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View article: B‐Site‐Metal‐Mediated Coke‐Resistant CO <sub>2</sub> Electrolysis on Perovskite Surfaces
B‐Site‐Metal‐Mediated Coke‐Resistant CO <sub>2</sub> Electrolysis on Perovskite Surfaces Open
High‐temperature CO 2 reduction to CO using perovskite‐oxide‐based solid oxide electrochemical cells holds promise for carbon‐neutral chemical production, yet currently faces the challenge of coke formation that leads to device failure. A …
View article: Rigid and stable nitroxide spin label for high-resolution distance measurements on proteins by DEER experiments
Rigid and stable nitroxide spin label for high-resolution distance measurements on proteins by DEER experiments Open
The distance distributions between two site-specifically anchored spin labels in a protein, measured by pulsed electron-electron double resonance (PELDOR or DEER), provide rich sources of structural and conformational restraints on the pro…
View article: Precision labeling of proteins in live cells illustrated by in-cell 19F-NMR spectroscopy
Precision labeling of proteins in live cells illustrated by in-cell 19F-NMR spectroscopy Open
Deciphering protein activity in living cells, especially at atomic resolution, remains a challenge. Nuclear magnetic resonance (NMR) spectroscopy is a unique tool to provide atomic-resolution information of proteins in live cells, but most…
View article: Enhanced Carbon‐Carbon Coupling at Interfaces with Abrupt Coordination Number Changes
Enhanced Carbon‐Carbon Coupling at Interfaces with Abrupt Coordination Number Changes Open
Cu‐catalyzed electrochemical CO 2 reduction reaction (CO 2 RR) produces multi‐carbon (C 2+ ) chemicals with considerable selectivities and activities, yet required high overpotentials impede its practical application. Here, we design inter…
View article: In-situ spectroscopic probe of the intrinsic structure feature of single-atom center in electrochemical CO/CO2 reduction to methanol
In-situ spectroscopic probe of the intrinsic structure feature of single-atom center in electrochemical CO/CO2 reduction to methanol Open
While exploring the process of CO/CO 2 electroreduction (CO x RR) is of great significance to achieve carbon recycling, deciphering reaction mechanisms so as to further design catalytic systems able to overcome sluggish kinetics remains ch…
View article: Perovskite‐Derived Bismuth with I<sup>−</sup> and Cs<sup>+</sup> Dual Modification for High‐Efficiency CO<sub>2</sub>‐to‐Formate Electrosynthesis and Al‐CO<sub>2</sub> Batteries
Perovskite‐Derived Bismuth with I<sup>−</sup> and Cs<sup>+</sup> Dual Modification for High‐Efficiency CO<sub>2</sub>‐to‐Formate Electrosynthesis and Al‐CO<sub>2</sub> Batteries Open
Bi‐based materials are one of the most promising candidates for electrochemical CO 2 reduction reaction (CO 2 RR) to formate; however, the majority of them still suffer from low current density and stability that essentially constrain thei…
View article: In-Situ Spectroscopic Probe of the Intrinsic Structure Feature of Single-Atom Center in Electrochemical CO/CO2 Reduction to Methanol
In-Situ Spectroscopic Probe of the Intrinsic Structure Feature of Single-Atom Center in Electrochemical CO/CO2 Reduction to Methanol Open
Single-Co-Atom catalysts for Electrochemical CO/CO2 Reduction to Methanol
View article: Highly Dispersed Indium Oxide Nanoparticles Supported on Carbon Nanorods Enabling Efficient Electrochemical CO<sub>2</sub> Reduction
Highly Dispersed Indium Oxide Nanoparticles Supported on Carbon Nanorods Enabling Efficient Electrochemical CO<sub>2</sub> Reduction Open
Indium‐based materials can selectively reduce CO 2 to formate, but their activities still fall short of expectations to be considered for practical applications. Structural engineering at the nanoscale offers a promising solution. However,…
View article: Toward Highly Selective Electrochemical CO<sub>2</sub> Reduction using Metal‐Free Heteroatom‐Doped Carbon
Toward Highly Selective Electrochemical CO<sub>2</sub> Reduction using Metal‐Free Heteroatom‐Doped Carbon Open
There are growing interests in metal‐free heteroatom‐doped carbons for electrochemical CO 2 reduction. Previous studies extensively focus on the effect of N‐doping, and their products severely suffer from low current density (mostly <2 mA …
View article: In-Cell Trityl–Trityl Distance Measurements on Proteins
In-Cell Trityl–Trityl Distance Measurements on Proteins Open
Double-electron electron resonance (DEER) can be used to track the structural dynamics of proteins in their native environment, the cell. This method provides the distance distribution between two spin labels attached at specific, well-def…
View article: Third BIR domain of XIAP binds to both Cu(II) and Cu(I) in multiple sites and with diverse affinities characterized at atomic resolution
Third BIR domain of XIAP binds to both Cu(II) and Cu(I) in multiple sites and with diverse affinities characterized at atomic resolution Open
The X-chromosome linked inhibitor of apoptosis, XIAP, is mainly known as the inhibitor of caspases by direct interaction with caspases with its baculoviral IAP repeat (BIR) domains. XIAP has three BIR domains and each BIR domain contains a…