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View article: Photolytic activation of Ni(II)X2L explains how Ni-mediated cross coupling begins
Photolytic activation of Ni(II)X2L explains how Ni-mediated cross coupling begins Open
View article: Electrostatic Work Causes Unexpected Reactivity in Ionic Photoredox Catalysts in Low Dielectric Constant Solvents
Electrostatic Work Causes Unexpected Reactivity in Ionic Photoredox Catalysts in Low Dielectric Constant Solvents Open
We show that in low dielectric constant (εr) solvents, the prototypical cationic photoredox catalyst [Ir(III)(dFCF3ppy)2-(5,5'-dCF3bpy)]+ is capable of oxidizing its counterion …
View article: Supporting Data for "Photolytic Activation of Ni(II)X2L Explains How Ni-Mediated Cross Coupling Begins"
Supporting Data for "Photolytic Activation of Ni(II)X2L Explains How Ni-Mediated Cross Coupling Begins" Open
View article: Polymer nanoparticle photocatalysts realized in non-aqueous solvents
Polymer nanoparticle photocatalysts realized in non-aqueous solvents Open
Solvent transfer procedure for moving polymer nanoparticles from water into non-aqueous solvents preserves colloidal stability and charge generation, expanding opportunities for diverse redox photocatalysis.
View article: Free‐Charge Carrier Generation in Homojunction Non‐Polymeric Organic Semiconductor Films – The Role of the Optical Frequency Dielectric Constant
Free‐Charge Carrier Generation in Homojunction Non‐Polymeric Organic Semiconductor Films – The Role of the Optical Frequency Dielectric Constant Open
Engineering the dielectric constant ( ε ) to lower the exciton binding energy of the light‐absorbing semiconductor can improve organic photovoltaic (OPV) device performance. Here, a series of materials are reported with 2‐(3‐oxo‐2,3‐dihydr…
View article: Efficient Free Charge Generation at Low-carrier Concentration in Chemically-doped Single-walled Carbon Nanotubes
Efficient Free Charge Generation at Low-carrier Concentration in Chemically-doped Single-walled Carbon Nanotubes Open
Free carrier generation in doped organic semiconductors is poorly understood, since assumed tight electron-hole binding conflicts with observed high free carrier yields. We experimentally investigate the roles of enthalpy, entropy, and loc…
View article: Driving force controls charge separation distance in solid state organic donor/acceptors
Driving force controls charge separation distance in solid state organic donor/acceptors Open
In this work, charge pairs of varying separation distance are interpreted from photoinduced absorption detected magnetic resonance (PADMR) spectroscopy of organic, small molecule dilute donor/acceptor thin films. We report that a donor/acc…
View article: Reconceptualizing the Ir<sup>III</sup> Role in Metallaphotoredox Catalysis: From Strong Photooxidant to Potent Energy Donor
Reconceptualizing the Ir<sup>III</sup> Role in Metallaphotoredox Catalysis: From Strong Photooxidant to Potent Energy Donor Open
Dual IrIII/LnNiII metallaphotoredox catalyzed C(sp3)–C(sp2) cross-coupling reactions are widely assumed to proceed by photoinduced single electron transfer steps due to the highly oxid…
View article: Missing Excitons: How Energy Transfer Competes with Free Charge Generation in Dilute-Donor/Acceptor Systems
Missing Excitons: How Energy Transfer Competes with Free Charge Generation in Dilute-Donor/Acceptor Systems Open
Energy transfer across the donor-acceptor interface in organic photovoltaics is usually beneficial to device performance, as it assists energy transport to the site of free charge generation. Here, we present a case where the opposite is t…
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Permissions Request permissions Contents list Nanoscale, 2024, 16, 493 DOI: 10.1039/D4NR90006E This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications…
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This article is Open Access All publication charges for this article have been paid for by the Royal Society of Chemistry
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Permissions Request permissions Contents list Energy Environ. Sci., 2024, 17, 3 DOI: 10.1039/D4EE90003K This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other pub…
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Permissions Request permissions Back cover Chem. Soc. Rev., 2024, 53, 1693 DOI: 10.1039/D4CS90011A This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publicat…
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Permissions Request permissions Contents list CrystEngComm, 2024, 26, 571 DOI: 10.1039/D4CE90014F This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publicati…
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Permissions Request permissions Contents list Inorg. Chem. Front., 2024, 11, 651 DOI: 10.1039/D4QI90008A This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other pu…
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Permissions Request permissions Back cover Environ. Sci.: Adv., 2024, 3, 347 DOI: 10.1039/D4VA90006E This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other public…
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Permissions Request permissions Contents list Chem. Commun., 2024, 60, 357 DOI: 10.1039/D4CC90015D This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publicat…
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Permissions Request permissions Contents list CrystEngComm, 2024, 26, 115 DOI: 10.1039/D4CE90005G This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publicati…
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Permissions Request permissions Contents list Nanoscale Adv., 2024, 6, 737 DOI: 10.1039/D4NA90013H This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publicat…
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Permissions Request permissions Back cover Chem. Commun., 2024, 60, 1651 DOI: 10.1039/D4CC90049A This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publicatio…
View article: Using spatial confinement to decipher polymorphism in the organic semiconductor p-DTS(FBTTh<sub>2</sub>)<sub>2</sub>
Using spatial confinement to decipher polymorphism in the organic semiconductor p-DTS(FBTTh<sub>2</sub>)<sub>2</sub> Open
Spatial confinement at the nanoscale is exploited to achieve specific polymorphs in the organic semiconductor p-DTS(FBTTh 2 ) 2 . A new polymorph exhibiting higher charge-carrier mobility compared to previously reported crystal form is fou…
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Permissions Request permissions Contents list New J. Chem., 2024, 48, 2871 DOI: 10.1039/D4NJ90022G This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publicat…
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Permissions Request permissions Contents list RSC Med. Chem., 2024, 15, 3 DOI: 10.1039/D4MD90002B This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publicati…
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Permissions Request permissions Back cover J. Mater. Chem. B, 2024, 12, 1937 DOI: 10.1039/D4TB90038C This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other public…
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Permissions Request permissions Back cover Chem. Commun., 2024, 60, 1953 DOI: 10.1039/D4CC90056A This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publicatio…
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Permissions Request permissions Back cover Anal. Methods, 2024, 16, 787 DOI: 10.1039/D4AY90017K This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publication…
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This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement…
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Permissions Request permissions Contents list Catal. Sci. Technol., 2024, 14, 217 DOI: 10.1039/D4CY90006E This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other p…
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Permissions Request permissions Back cover Anal. Methods, 2024, 16, 141 DOI: 10.1039/D4AY90003K This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publication…
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Permissions Request permissions Contents list Environ. Sci.: Water Res. Technol., 2024, 10, 3 DOI: 10.1039/D4EW90003K This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this articl…