Brian L. Scott
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View article: In vitro toxicity assessment of uranium particulates on different human lung epithelial cell models
In vitro toxicity assessment of uranium particulates on different human lung epithelial cell models Open
Inhalation of uranium aerosols produced via human activities such as mining can pose a threat to human respiratory systems. Uranium oxide particulates emit short-range alpha particles that elicit DNA and direct damage, beyond associated ph…
View article: The limiting effects of banking regulations on emission permit markets: An experimental analysis.
The limiting effects of banking regulations on emission permit markets: An experimental analysis. Open
The limiting effects of banking regulations on emission permit markets: An experimental analysis.
View article: Digging into the Intrinsic Negative Thermal Expansion of Uranium Tetrafluoride
Digging into the Intrinsic Negative Thermal Expansion of Uranium Tetrafluoride Open
The intrinsic negative thermal expansion of UF4 below room temperature was examined. A redetermination of the structure of UF4 by single-crystal X-ray diffraction at 100, 200, and 300 K accompanied by an evaluation of…
View article: Development of Material Studies at the LANL UCN Facility Focusing on Actinide Hydriding and Fission Damage
Development of Material Studies at the LANL UCN Facility Focusing on Actinide Hydriding and Fission Damage Open
The aging of as-built actinide surfaces in static and dynamic environments is a complex problem of high importance to LANL’s core mission. Many standard material science tools used to study this problem are ideal for highly controlled, lab…
View article: N-Heterocyclic Carbene to Actinide d-Based π-bonding Correlates with Observed Metal–Carbene Bond Length Shortening Versus Lanthanide Congeners
N-Heterocyclic Carbene to Actinide d-Based π-bonding Correlates with Observed Metal–Carbene Bond Length Shortening Versus Lanthanide Congeners Open
Comparison of bonding and electronic structural features between trivalent lanthanide (Ln) and actinide (An) complexes across homologous series' of molecules can provide insights into subtle and overt periodic trends. Of keen interest and …
View article: Selectivity in the Synthesis of 1-Substituted and 1,8 –Disubstituted Fluroenones by Directed Metalation and Conversion to Spiral Cyclopropenes.
Selectivity in the Synthesis of 1-Substituted and 1,8 –Disubstituted Fluroenones by Directed Metalation and Conversion to Spiral Cyclopropenes. Open
View article: Electronic Structure and Bonding of Minor Actinide Sulfur-Donor Extractants
Electronic Structure and Bonding of Minor Actinide Sulfur-Donor Extractants Open
View article: Nickel hydride complexes of an aliphatic PNP Pincer ligand: insertion and catalytic hydrogenation reactions
Nickel hydride complexes of an aliphatic PNP Pincer ligand: insertion and catalytic hydrogenation reactions Open
View article: Probing the luminescence spectroscopy of uranyl and neptunyl heteropolyoxotungstate complexes
Probing the luminescence spectroscopy of uranyl and neptunyl heteropolyoxotungstate complexes Open
View article: Environmental chemistry of actinide species at contaminated sites
Environmental chemistry of actinide species at contaminated sites Open
View article: Molecular transuranic coordination chemistry
Molecular transuranic coordination chemistry Open
View article: Exploring the chemistry of the actinides in ionic liquids
Exploring the chemistry of the actinides in ionic liquids Open
View article: Solution route to high quality epitaxial actinide films: from oxides to carbides
Solution route to high quality epitaxial actinide films: from oxides to carbides Open
View article: Actinide speciation and chemical behavior at contaminated sites
Actinide speciation and chemical behavior at contaminated sites Open
View article: Coordination behavior and electrochemical studies of actinide and transition metal complexes in room temperature ionic liquids
Coordination behavior and electrochemical studies of actinide and transition metal complexes in room temperature ionic liquids Open
Our current research efforts are centered around the behavior of actinide and transition metal complexes in room temperature ionic liquids (RTIL's). The RTIL's typically employed in our studies are based upon either cyclic or acyclic quate…
View article: Plutonium (III) and uranium (III) nitrile complexes
Plutonium (III) and uranium (III) nitrile complexes Open
Iodine oxidation of uranium and plutonium metals in tetrahydrofuran and pyridine form AnI{sub 3}(THF){sub 4} and AnI{sub 3}(py){sub 4} (An = Pu, U). These compounds represent convenient entries Into solution An(III) chemistry in organic so…
View article: Selenate and tellurate complexes of pentavalent uranium
Selenate and tellurate complexes of pentavalent uranium Open
View article: What a difference a 5f element makes: trivalent and tetravalent uranium halide complexes supported by one and two PNP ligands
What a difference a 5f element makes: trivalent and tetravalent uranium halide complexes supported by one and two PNP ligands Open
View article: Thorium and uranium redox-active ligand complexes; reversible intramolecular electron transfer in U(dpp-BIAN)2/ U(dpp-BIAN)2(THE)
Thorium and uranium redox-active ligand complexes; reversible intramolecular electron transfer in U(dpp-BIAN)2/ U(dpp-BIAN)2(THE) Open
Actinide complexes of the redox-active ligand dpp-BIAN{sup 2-} (dpp-BIAN = bis(2,6-diisopropylphenyl)acenaphthylene), An(dpp-BIAN){sub 2}(THF){sub n} (An = Th, n = 1; An = U, n = 0, 1) have been prepared. Solid-state magnetic and single-cr…
View article: Carbene Complexes of Plutonium: Structure, Bonding, and Divergent Reactivity to Lanthanide Analogs
Carbene Complexes of Plutonium: Structure, Bonding, and Divergent Reactivity to Lanthanide Analogs Open
Organoplutonium chemistry was established in 1965, yet structurally authenticated plutonium-carbon bonds remain rare being limited to π-bonded carbocycle and σ-bonded isonitrile and hydrocarbyl derivatives. Thus, plutonium-carbenes, includ…
View article: Aerobic oxidation of polyalcohols by vanadium (V) complexes: experimental evidence for reduction to vanadium (III)
Aerobic oxidation of polyalcohols by vanadium (V) complexes: experimental evidence for reduction to vanadium (III) Open
View article: Challenging the metallocene dominance in actinide chemistry with a soft PNP pincer ligand: new uranium structures reactivity patterns
Challenging the metallocene dominance in actinide chemistry with a soft PNP pincer ligand: new uranium structures reactivity patterns Open
View article: Aeolian Dust Deposition as a Driver of Cyanobacterial Community Structure in Biological Soil Crusts
Aeolian Dust Deposition as a Driver of Cyanobacterial Community Structure in Biological Soil Crusts Open
View article: Gas permeable hydrophobic material
Gas permeable hydrophobic material Open
Hydrophobic filter materials, methods of making them, and their use in various industrial applications are presented. In an example, thermally stable, gas permeable hydrophobic filters which maintain their integrity upon exposure to elevat…
View article: CCDC 2231572: Experimental Crystal Structure Determination
CCDC 2231572: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2231573: Experimental Crystal Structure Determination
CCDC 2231573: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Impact of Pendent Ammonium Groups on Solubility and Cycling Charge Carrier Performance in Nonaqueous Redox Flow Batteries
Impact of Pendent Ammonium Groups on Solubility and Cycling Charge Carrier Performance in Nonaqueous Redox Flow Batteries Open
The synthesis, characterization, electrochemical performance, and theoretical modeling of two base-metal charge carrier complexes incorporating a pendent quaternary ammonium group, [Ni(bppn-Me3)][BF4], 3', and …
View article: <i>In situ</i> synthesis of PuCl<sub>3</sub> and corresponding Raman and density functional theory vibrational modes
<i>In situ</i> synthesis of PuCl<sub>3</sub> and corresponding Raman and density functional theory vibrational modes Open
The experimental and calculated Raman spectrum of PuCl 3 has been reported for the first time. PuCl 3 is a primary species found in plutonium metal refinement, specifically in pyrochemical salt processes including multicycle direct oxide r…
View article: In-situ Synthesis of PuCl<sub>3</sub> and Corresponding Raman and Density Functional Theory Vibrational Modes
In-situ Synthesis of PuCl<sub>3</sub> and Corresponding Raman and Density Functional Theory Vibrational Modes Open
The experimental and calculated Raman spectrum of PuCl3 has been reported for the first time. PuCl3 is a primary species found in plutonium metal refinement, specifically in pyrochemical salt processes including multi…