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View article: An Ultramicroporous Physisorbent Sustained by a Trifecta of Directional Supramolecular Interactions
An Ultramicroporous Physisorbent Sustained by a Trifecta of Directional Supramolecular Interactions Open
2D and 3D porous coordination networks (PCNs) as exemplified by metal-organic frameworks, MOFs, have garnered interest for their potential utility as sorbents for molecular separations and storage. The inherent modularity of PCNs has enabl…
View article: Trailblazing Kr/Xe Separation: The Birth of the First Kr-Selective Material
Trailblazing Kr/Xe Separation: The Birth of the First Kr-Selective Material Open
Efficient separation of Kr from Kr/Xe mixtures is pivotal in nuclear waste management and dark matter research. Thus far, scientists have encountered a formidable challenge: the absence of a material with the ability to selectively adsorb …
View article: Turning Normal to Abnormal: Reversing CO<sub>2</sub>/C2‐Hydrocarbon Selectivity in HKUST‐1
Turning Normal to Abnormal: Reversing CO<sub>2</sub>/C2‐Hydrocarbon Selectivity in HKUST‐1 Open
Metal–organic frameworks (MOFs) can efficiently purify hydrocarbons from CO 2 , but their rapid saturation, driven by preferential hydrocarbon adsorption, requires energy‐intensive adsorption–desorption processes. To address these challeng…
View article: Crystal Engineering of Two Light and Pressure Responsive Physisorbents
Crystal Engineering of Two Light and Pressure Responsive Physisorbents Open
An emerging strategy in the design of efficient gas storage technologies is the development of stimuli‐responsive physisorbents which undergo transformations in response to a particular stimulus, such as pressure, heat or light. Herein, we…
View article: Crystal Engineering of Two Light and Pressure Responsive Physisorbents
Crystal Engineering of Two Light and Pressure Responsive Physisorbents Open
An emerging strategy in the design of efficient gas storage technologies is the development of stimuli‐responsive physisorbents which undergo transformations in response to a particular stimulus, such as pressure, heat or light. Herein, we…
View article: Reversible transformations between the non-porous phases of a flexible coordination network enabled by transient porosity
Reversible transformations between the non-porous phases of a flexible coordination network enabled by transient porosity Open
View article: Reversible transformations between the non-porous phases of a flexible coordination network enabled by transient porosity
Reversible transformations between the non-porous phases of a flexible coordination network enabled by transient porosity Open
Raw data archive for the manuscript titled "Reversible transformations between the non-porous phases of a flexible coordination network enabled by transient porosity"
View article: Reversible transformations between the non-porous phases of a flexible coordination network enabled by transient porosity
Reversible transformations between the non-porous phases of a flexible coordination network enabled by transient porosity Open
Raw data archive for the manuscript titled "Reversible transformations between the non-porous phases of a flexible coordination network enabled by transient porosity"
View article: Methane storage in flexible and dynamical metal–organic frameworks
Methane storage in flexible and dynamical metal–organic frameworks Open
Recently, there has been significant interest in methane as an abundant and cleaner burning alternative to fossil fuels. Consequently, the design of media capable of the storage of methane under practical conditions has become an area of s…
View article: Self‐Adjusting Metal–Organic Framework for Efficient Capture of Trace Xenon and Krypton
Self‐Adjusting Metal–Organic Framework for Efficient Capture of Trace Xenon and Krypton Open
The capture of the xenon and krypton from nuclear reprocessing off‐gas is essential to the treatment of radioactive waste. Although various porous materials have been employed to capture Xe and Kr, the development of high‐performance adsor…
View article: Metal–Organic Framework Based Hydrogen-Bonding Nanotrap for Efficient Acetylene Storage and Separation
Metal–Organic Framework Based Hydrogen-Bonding Nanotrap for Efficient Acetylene Storage and Separation Open
The removal of carbon dioxide (CO2) from acetylene (C2H2) is a critical industrial process for manufacturing high-purity C2H2. However, it remains challenging to address the tradeoff b…
View article: One-step ethylene production from a four-component gas mixture by a single physisorbent
One-step ethylene production from a four-component gas mixture by a single physisorbent Open
View article: Efficient propyne/propadiene separation by microporous crystalline physiadsorbents
Efficient propyne/propadiene separation by microporous crystalline physiadsorbents Open
View article: Breaking the trade-off between selectivity and adsorption capacity for gas separation
Breaking the trade-off between selectivity and adsorption capacity for gas separation Open
View article: Toward an Understanding of the Propensity for Crystalline Hydrate Formation by Molecular Compounds. Part 2
Toward an Understanding of the Propensity for Crystalline Hydrate Formation by Molecular Compounds. Part 2 Open
The propensity of molecular organic compounds to form stoichiometric or nonstoichiometric crystalline hydrates remains a challenging aspect of crystal engineering and is of practical relevance to fields such as pharmaceutical science. In t…
View article: Benchmark Acetylene Binding Affinity and Separation through Induced Fit in a Flexible Hybrid Ultramicroporous Material
Benchmark Acetylene Binding Affinity and Separation through Induced Fit in a Flexible Hybrid Ultramicroporous Material Open
Structural changes at the active site of an enzyme induced by binding to a substrate molecule can result in enhanced activity in biological systems. Herein, we report that the new hybrid ultramicroporous material sql‐SIFSIX‐bpe‐Zn exhibits…
View article: Amino‐Functionalised Hybrid Ultramicroporous Materials that Enable Single‐Step Ethylene Purification from a Ternary Mixture
Amino‐Functionalised Hybrid Ultramicroporous Materials that Enable Single‐Step Ethylene Purification from a Ternary Mixture Open
Pyrazine‐linked hybrid ultramicroporous (pore size 99.95 % for SIFSIX‐17‐Ni ) from a ternary equimolar mixture of ethylene, acetylene and CO 2 thanks to coadsorption of the latter two gases. We attribute this performance to the very differ…
View article: Amino‐Functionalised Hybrid Ultramicroporous Materials that Enable Single‐Step Ethylene Purification from a Ternary Mixture
Amino‐Functionalised Hybrid Ultramicroporous Materials that Enable Single‐Step Ethylene Purification from a Ternary Mixture Open
Pyrazine‐linked hybrid ultramicroporous (pore size 99.95 % for SIFSIX‐17‐Ni ) from a ternary equimolar mixture of ethylene, acetylene and CO 2 thanks to coadsorption of the latter two gases. We attribute this performance to the very differ…
View article: Immobilization of a Polar Sulfone Moiety onto the Pore Surface of a Humid-Stable MOF for Highly Efficient CO<sub>2</sub> Separation under Dry and Wet Environments through Direct CO<sub>2</sub>–Sulfone Interactions
Immobilization of a Polar Sulfone Moiety onto the Pore Surface of a Humid-Stable MOF for Highly Efficient CO<sub>2</sub> Separation under Dry and Wet Environments through Direct CO<sub>2</sub>–Sulfone Interactions Open
The stability of microporous metal-organic frameworks (MOFs) in moist environments must be taken into consideration for their practical implementations, which has been largely ignored thus far. Herein, we synthesized a new moisture-stable …
View article: Innentitelbild: Ultramicropore Engineering by Dehydration to Enable Molecular Sieving of H<sub>2</sub> by Calcium Trimesate (Angew. Chem. 37/2020)
Innentitelbild: Ultramicropore Engineering by Dehydration to Enable Molecular Sieving of H<sub>2</sub> by Calcium Trimesate (Angew. Chem. 37/2020) Open
Physikalische Trennungen können chemischen Trennungen überlegen sein, das gilt insbesondere für Siebverfahren schwierig zu trennender Gasgemische. Ein ideales Sieben von industriellen Gasen erfordert jedoch eine sehr präzise, ultramikropor…
View article: Radiation-resistant metal-organic framework enables efficient separation of krypton fission gas from spent nuclear fuel
Radiation-resistant metal-organic framework enables efficient separation of krypton fission gas from spent nuclear fuel Open
View article: Ultramicropore Engineering by Dehydration to Enable Molecular Sieving of H<sub>2</sub> by Calcium Trimesate
Ultramicropore Engineering by Dehydration to Enable Molecular Sieving of H<sub>2</sub> by Calcium Trimesate Open
The high energy footprint of commodity gas purification and increasing demand for gases require new approaches to gas separation. Kinetic separation of gas mixtures through molecular sieving can enable separation by molecular size or shape…
View article: Cover Feature: Halogen–C<sub>2</sub>H<sub>2</sub> Binding in Ultramicroporous Metal–Organic Frameworks (MOFs) for Benchmark C<sub>2</sub>H<sub>2</sub>/CO<sub>2</sub> Separation Selectivity (Chem. Eur. J. 22/2020)
Cover Feature: Halogen–C<sub>2</sub>H<sub>2</sub> Binding in Ultramicroporous Metal–Organic Frameworks (MOFs) for Benchmark C<sub>2</sub>H<sub>2</sub>/CO<sub>2</sub> Separation Selectivity (Chem. Eur. J. 22/2020) Open
Breaking up is hard to do, especially for acetylene and carbon dioxide, but benchmark separation with selectivity for these gases has been accomplished in a crystal engineered family of ultramicroporous metal-organic frameworks (MOFs) than…
View article: Halogen–C<sub>2</sub>H<sub>2</sub> Binding in Ultramicroporous Metal–Organic Frameworks (MOFs) for Benchmark C<sub>2</sub>H<sub>2</sub>/CO<sub>2</sub> Separation Selectivity
Halogen–C<sub>2</sub>H<sub>2</sub> Binding in Ultramicroporous Metal–Organic Frameworks (MOFs) for Benchmark C<sub>2</sub>H<sub>2</sub>/CO<sub>2</sub> Separation Selectivity Open
Acetylene (C 2 H 2 ) capture is a step in a number of industrial processes, but it comes with a high‐energy footprint. Although physisorbents have the potential to reduce this energy footprint, they are handicapped by generally poor select…
View article: Trace CO <sub>2</sub> capture by an ultramicroporous physisorbent with low water affinity
Trace CO <sub>2</sub> capture by an ultramicroporous physisorbent with low water affinity Open
The first sorbent with high CO 2 selectivity and poor water affinity addresses need for trace CO 2 remediation in confined spaces.
View article: Enhanced Gas Uptake in a Microporous Metal–Organic Framework <i>via</i> a Sorbate Induced-Fit Mechanism
Enhanced Gas Uptake in a Microporous Metal–Organic Framework <i>via</i> a Sorbate Induced-Fit Mechanism Open
Physical adsorption of gas molecules in microporous materials is an exothermic process, with desorption entropy driving a decrease in uptake with temperature. Enhanced gas sorption with increasing temperature is rare in porous materials an…
View article: MPMC and MCMD: Free High‐Performance Simulation Software for Atomistic Systems
MPMC and MCMD: Free High‐Performance Simulation Software for Atomistic Systems Open
Advancements in parallel computing and hardware have allowed computational exploration of chemical systems of interest with unprecendented accuracy and efficiency. The typical development of molecular simulation software is initially inspi…
View article: Innenrücktitelbild: A Metal–Organic Framework Based Methane Nano‐trap for the Capture of Coal‐Mine Methane (Angew. Chem. 30/2019)
Innenrücktitelbild: A Metal–Organic Framework Based Methane Nano‐trap for the Capture of Coal‐Mine Methane (Angew. Chem. 30/2019) Open
Eine Methan-Nanofalle auf Basis eines Alkyl-MOF mit gegenüberliegenden offenen Metallzentren und dichten Alkylgruppen wird von S. Ma, Z. Niu et al. in ihrer Zuschrift auf S. 10244 vorgestellt. Die Methan-Nanofalle zeigt eine Rekord-Methana…
View article: Inside Back Cover: A Metal–Organic Framework Based Methane Nano‐trap for the Capture of Coal‐Mine Methane (Angew. Chem. Int. Ed. 30/2019)
Inside Back Cover: A Metal–Organic Framework Based Methane Nano‐trap for the Capture of Coal‐Mine Methane (Angew. Chem. Int. Ed. 30/2019) Open
A methane nanotrap based on an alkyl metal–organic framework (MOF) and featuring oppositely adjacent open metal sites and dense alkyl groups is reported by S. Ma, Z. Niu, and co-workers in their Communication on page 10138 ff. The methane …
View article: Molecular Sieving and Direct Visualization of CO<sub>2</sub> in Binding Pockets of an Ultramicroporous Lanthanide Metal–Organic Framework Platform
Molecular Sieving and Direct Visualization of CO<sub>2</sub> in Binding Pockets of an Ultramicroporous Lanthanide Metal–Organic Framework Platform Open
Inspired by the structure of carbonic anhydrase, we developed a robust ultramicroporous lanthanide metal-organic framework (MOF) platform (NKMOF-3-Ln), which possesses a porous pocket to selectively bind with CO2 at ambient cond…