Harry C. Dorn
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Fullertubes: A 30-Year Story of Prediction, Experimental Validation, and Applications for a Long-Missing Family of Soluble Carbon Molecules Open
ConspectusDuring the last 30 years, theoretical scientists imagined segmental families of monolayer carbon tubules with fullerene-based end-caps. These fullertube molecules would possess structural features of both fullerenes (hemispherica…
View article: CCDC 2184521: Experimental Crystal Structure Determination
CCDC 2184521: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
Water-soluble endohedral metallofullerenes: new horizons for biomedical applications Open
This feature article provides a brief overview of the relevant chemistry used to take advantage of the unique metal-hosting capabilities of endohedral metallofullerenes (EMFs), followed by the development and application of EMF derivatives…
View article: Amine Functionalized Trimetallic Nitride Endohedral Fullerenes: A Class of Nanoparticle to Tackle Low Back/Leg Pain
Amine Functionalized Trimetallic Nitride Endohedral Fullerenes: A Class of Nanoparticle to Tackle Low Back/Leg Pain Open
Low back pain is the most common health problem with a prevalence of over 80% worldwide and an estimated annual cost of $100 billion in the United States. Intervertebral disc degeneration accounts for a major cause of low back pain. Howeve…
Metamagnetic transition and a loss of magnetic hysteresis caused by electron trapping in monolayers of single-molecule magnet Tb<sub>2</sub>@C<sub>79</sub>N Open
Whereas bulk Tb 2 @C 79 N is a single-molecule magnet with broad hysteresis, its monolayers on different substrates show the prevalence of a non-magnetic ground state near zero magnetic field and a metamagnetic transition with the field in…
Cover Feature: Isolation and Crystallographic Characterization of Two, Nonisolated Pentagon Endohedral Fullerenes: Ho<sub>3</sub>N@<i>C</i><sub>2</sub>(22010)‐C<sub>78</sub> and Tb<sub>3</sub>N@<i>C</i><sub>2</sub>(22010)‐C<sub>78</sub> (Chem. Eur. J. 54/2019) Open
The molecular structure of Ho3N@C2(22010)-C78 is shown in the cover artwork, along with the two molecules of nickel octaethylporphyrin (Ni(OEP) that surround it in the co-crystal, Ho3N@C2(22010)-C78⋅2 Ni(OEP)⋅2 toluene. Ho3N@C2(22010)-C78 …
High Blocking Temperature of Magnetization and Giant Coercivity in the Azafullerene Tb<sub>2</sub>@C<sub>79</sub>N with a Single‐Electron Terbium–Terbium Bond Open
The azafullerene Tb 2 @C 79 N is found to be a single‐molecule magnet with a high 100‐s blocking temperature of magnetization of 24 K and large coercivity. Tb magnetic moments with an easy‐axis single‐ion magnetic anisotropy are strongly c…
Giant exchange coupling and field-induced slow relaxation of magnetization in Gd<sub>2</sub>@C<sub>79</sub>N with a single-electron Gd–Gd bond Open
Single-electron Gd–Gd bond in Gd2@C79N results in giant ferromagnetic coupling between local 4f magnetic moments and unpaired electron spin.
Trimetallic Nitride Endohedral Fullerenes Carboxyl-Gd<sub>3</sub>N@C<sub>80</sub>: A New Theranostic Agent for Combating Oxidative Stress and Resolving Inflammation Open
Antioxidative and anti-inflammatory effects of trimetallic nitride endohedral fullerenes carboxyl-Gd(3)N@C(80), a newly developed magnetic resonance imaging (MRI) contrast agent, were investigated. All hydrochalarone and carboxyl-functiona…
Detecting Chronic Post-Traumatic Osteomyelitis of Mouse Tibia via an IL-13Rα2 Targeted Metallofullerene Magnetic Resonance Imaging Probe Open
Differential diagnosis of chronic post-traumatic osteomyelitis (CPO) from aseptic inflammation remains challenging, since both pathological processes share similar clinical symptoms. Here we utilized a novel targeted metallofullerene nanop…
CCDC 1541111: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 1541110: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …