Christian Serre
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View article: Dual-photon–driven hydrogen evolution in copper-based photocatalysts under near-infrared and visible light
Dual-photon–driven hydrogen evolution in copper-based photocatalysts under near-infrared and visible light Open
While the dynamic restructuring of Cu-metalated metal-organic frameworks for photocatalysis has recently been explored, its effect on electronic excitation remains under-investigated. For better mechanistic understanding, we study the ligh…
View article: Photoaccumulation of Long‐Lived Reactive Electrons in a Microporous Ti(IV) Oxocluster‐Based Metal–Organic Framework for Light and Dark Photocatalysis
Photoaccumulation of Long‐Lived Reactive Electrons in a Microporous Ti(IV) Oxocluster‐Based Metal–Organic Framework for Light and Dark Photocatalysis Open
The microporous Ti 12 oxocluster‐based metal–organic framework (MOF) MIP‐177(Ti)‐LT exhibits excellent stability and photoactivity, making it highly promising for photocatalysis. Using transient and photoinduced absorption spectroscopies, …
View article: Unlocking the scale-up of the benchmark MOFs MIL-53(Al)’s
Unlocking the scale-up of the benchmark MOFs MIL-53(Al)’s Open
Environment-friendly synthesis of metal-organic frameworks (MOFs) is crucial to meet growing industrial demand. Here, we present a generalized and scalable route for the production of the prototypical Al-OH chain-based microporous and flex…
View article: Photoaccumulation of Long-lived Reactive Electrons in the Microporous Ti(IV) Oxocluster Based Metal-organic Framework for Light and Dark Photocatalysis
Photoaccumulation of Long-lived Reactive Electrons in the Microporous Ti(IV) Oxocluster Based Metal-organic Framework for Light and Dark Photocatalysis Open
The microporous Ti12 oxocluster based metal-organic framework MIP-177(Ti)-LT exhibits excellent stability and photoactivity, making it highly promising for photocatalytic applications (LT stands for low temperature synthesis). This study e…
View article: In-situ Diffraction Crystallization Study of a porous Ti(IV) oxo-cluster carboxylate MOF and its Water-Induced Ti(III) Formate
In-situ Diffraction Crystallization Study of a porous Ti(IV) oxo-cluster carboxylate MOF and its Water-Induced Ti(III) Formate Open
The in-situ crystallization kinetics of the highly porous Ti(IV)12 oxo-cluster based metal-organic framework (MOF) MIP-177(Ti)-LT (MIP: Materials from Institute of porous solids of Paris, LT: Low Temperature) were studied by synchrotron ti…
View article: Evaluating the Performance of a Microporous Ti Bisphosphonate MOF for Postcombustion Carbon Capture by Vacuum Pressure Swing Adsorption
Evaluating the Performance of a Microporous Ti Bisphosphonate MOF for Postcombustion Carbon Capture by Vacuum Pressure Swing Adsorption Open
A multiscale study was carried out to evaluate the microporous -Ti-bisphosphonate MIL-91-(Ti) sorbent for postcombustion CO2 capture in industrially relevant conditions. The process performance of the MOF was first assessed by using molecu…
View article: A Microporous Bimetallic Aluminum-Copper-Carboxylate-Pyrazolate MOF for CO2 Capture
A Microporous Bimetallic Aluminum-Copper-Carboxylate-Pyrazolate MOF for CO2 Capture Open
Herein, we present a novel bimetallic hetero-functional ultra-microporous MOF, labelled MIP-212(Al/Cu) (MIP stands for Materials from Institute of Porous Materials of Paris), designed based on Hard and Soft Acids and Bases (HSAB) principle…
View article: Calcium Alginate Aerogel-MIL160 Nanocomposites for CO <sub>2</sub> Removal
Calcium Alginate Aerogel-MIL160 Nanocomposites for CO <sub>2</sub> Removal Open
Using MOFs in powder form leads to mass transfer limitations and large pressure drops in packed bed adsorbers. Use of MOF/aerogel composites (called MOFACs) in bead form could overcome these challenges without compromising the MOF's adsorp…
View article: Metal–Organic Frameworks: Unlocking New Frontiers in Cardiovascular Diagnosis and Therapy
Metal–Organic Frameworks: Unlocking New Frontiers in Cardiovascular Diagnosis and Therapy Open
Cardiovascular disease (CVD) is one of the most critical diseases which is the predominant cause of death in the world. Early screening and diagnosis of the disease and effective treatment after diagnosis play an important role in the pati…
View article: A Novel Ti <sub>12</sub> ‐Based Metal‐Organic Framework for Photocatalytic Hydrogen Evolution
A Novel Ti <sub>12</sub> ‐Based Metal‐Organic Framework for Photocatalytic Hydrogen Evolution Open
A new microporous titanium‐based metal‐organic framework (Ti‐MOF), labeled as MIP‐209(Ti) (MIP: Materials from Institute of Porous Materials of Paris), features nitro terephthalate ligands and Ti 12 O 15 oxo‐clusters, as revealed by contin…
View article: Metal‐Organic Frameworks for the Therapy of Inflammatory Diseases
Metal‐Organic Frameworks for the Therapy of Inflammatory Diseases Open
Inflammation is a natural immune response triggered by harmful external or internal stimuli. However, when inflammation fails to resolve and restore basal homeostasis, it can lead to various inflammatory diseases such as rheumatoid arthrit…
View article: MOF and related composites as selective functional separators and interlayers for Li-S batteries
MOF and related composites as selective functional separators and interlayers for Li-S batteries Open
Lithium-sulfur (Li-S) batteries are one of the most promising technologies compared to lithium-ion-based ones, mainly due to their outstanding high energy density (2,567 Wh/kg). Nonetheless, Li-S batteries still face important drawbacks, n…
View article: Gasotransmitters in Modern Medicine: Promises and Challenges in the Use of Porous Crystalline Carriers
Gasotransmitters in Modern Medicine: Promises and Challenges in the Use of Porous Crystalline Carriers Open
Gas therapy using gasotransmitters is of exponential interest due to the growing recognition of gas signaling molecules that can be involved in multiple therapeutic actions. Finding suitable methods for delivering these molecules is crucia…
View article: Evaluating the performance and suitability of MIL-91(Ti) MOF for post-combustion carbon capture by vacuum pressure swing adsorption (VPSA)
Evaluating the performance and suitability of MIL-91(Ti) MOF for post-combustion carbon capture by vacuum pressure swing adsorption (VPSA) Open
A multiscale study was carried out to evaluate MIL-91 (Ti) sorbent for post-combustion CO2 capture in industrially relevant conditions. Initially, the process performance of the MOF was assessed using molecular simulated adsorption isother…
View article: Excited State Transient Phenomena in Two Different Phases of the Photoactive MOF MIP‐177(Ti)
Excited State Transient Phenomena in Two Different Phases of the Photoactive MOF MIP‐177(Ti) Open
The metal organic framework (MOF) MIP‐177(Ti) is under the spotlight for its robust photo‐response and stability. This MOF can be synthesized in forms: MIP‐177(Ti)‐LT (LT: low temperature) and MIP‐177(Ti)‐HT (HT: high temperature). The MIP…
View article: Cost Estimation of the Production of MIL-100(Fe) at Industrial Scale from Two Upscaled Sustainable Synthesis Routes
Cost Estimation of the Production of MIL-100(Fe) at Industrial Scale from Two Upscaled Sustainable Synthesis Routes Open
Understanding the impact of MOF synthesis conditions on the production cost is vital in order to have a competitive product with a view toward industrial applications. Here, considering the benchmark mesoporous iron(III) trimesate MIL-100(…
View article: Synthetic Aspects and Characterization Needs in MOF Chemistry – from Discovery to Applications
Synthetic Aspects and Characterization Needs in MOF Chemistry – from Discovery to Applications Open
Even if MOFs are recently developed for large‐scale applications, the road to applications of MOFs is long and rocky. This requires to overcome challenges associated with phase discovery, synthesis optimization, basic and advanced characte…
View article: A spin-state switchable MOF-based film for visual DMSO vapor sensing
A spin-state switchable MOF-based film for visual DMSO vapor sensing Open
The encapsulation of an Fe( iii ) spin crossover complex in a Zr( iv )-based metal–organic framework film led to a switchable compound that can be used for colorimetric sensing of dimethyl sulfoxide.
View article: Angle-dependent spin crossover properties in polymorphic iron(<scp>ii</scp>) complexes based on pyridine–triazole derivatives
Angle-dependent spin crossover properties in polymorphic iron(<span>ii</span>) complexes based on pyridine–triazole derivatives Open
Highlighting the impact of the Fe–NCS bond angle on the spin crossover behaviour with novel Fe( ii ) complexes.
View article: Photocatalytic water splitting reaction: The pathway from semiconductors to MOFs
Photocatalytic water splitting reaction: The pathway from semiconductors to MOFs Open
International audience
View article: Metal-organic frameworks based on pyrazolates for the selective and efficient capture of formaldehyde
Metal-organic frameworks based on pyrazolates for the selective and efficient capture of formaldehyde Open
Indoor air pollution is one of the major threads in developed countries, notably due to high concentrations of formaldehyde, a harmful molecule difficult to eliminate. Addressing this purification challenge while adhering to the principles…
View article: MOF‐Enhanced Phototherapeutic Wound Dressings Against Drug‐Resistant Bacteria
MOF‐Enhanced Phototherapeutic Wound Dressings Against Drug‐Resistant Bacteria Open
Phototherapy is a low‐risk alternative to traditional antibiotics against drug‐resistant bacterial infections. However, optimizing phototherapy agents, refining treatment conditions, and addressing misuse of agents, remain a formidable cha…
View article: Iron‐MOFs for Biomedical Applications
Iron‐MOFs for Biomedical Applications Open
Over the past two decades, iron‐based metal–organic frameworks (Fe‐MOFs) have attracted significant research interest in biomedicine due to their low toxicity, tunable degradability, substantial drug loading capacity, versatile structures,…
View article: Ultra‐Microporous Fe‐MOF with Prolonged NO Delivery in Biological Media for Therapeutic Application
Ultra‐Microporous Fe‐MOF with Prolonged NO Delivery in Biological Media for Therapeutic Application Open
Nitric oxide (NO), a key element in the regulation of essential biological mechanisms, presents huge potential as therapeutic agent in the treatment and prevention of chronic diseases. Metal‐organic frameworks (MOFs) with open metal sites …
View article: A Novel Ti12-based Metal-Organic Framework for Photocatalytic Hydrogen Evolution
A Novel Ti12-based Metal-Organic Framework for Photocatalytic Hydrogen Evolution Open
Constructing titanium-based metal-organic frameworks (Ti-MOFs) is an effective way towards upgrading TiOx and the enhancement of their photocatalytic performance throughout higher accessibility to active sites and better tunability of phot…