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View article: Photodegradable Hydrogels for On-Demand Modeling of Age-Related Spatiotemporal ECM Deformation
Photodegradable Hydrogels for On-Demand Modeling of Age-Related Spatiotemporal ECM Deformation Open
The extracellular matrix (ECM) plays a crucial role in regulating tissue behavior through a dynamic interplay of spatial and temporal cues. Dynamic materials capable of modulating these cues at relevant scales are essential for tackling cu…
View article: Synergizing bioprinting and 3D cell culture to enhance tissue formation in printed synthetic constructs
Synergizing bioprinting and 3D cell culture to enhance tissue formation in printed synthetic constructs Open
Bioprinting is currently the most promising method to biofabricate complex tissues in vitro with the potential to transform the future of organ transplantation and drug discovery. Efforts to create such tissues are, however, almost exclusi…
View article: Ethylene Polymerization‐Induced Self‐Assembly (PISA) of Poly(ethylene oxide)‐<i>block</i>‐polyethylene Copolymers via RAFT
Ethylene Polymerization‐Induced Self‐Assembly (PISA) of Poly(ethylene oxide)‐<i>block</i>‐polyethylene Copolymers via RAFT Open
Poly(ethylene oxide) (PEO) with dithiocarbamate chain ends (PEO–SC(=S)−N(CH 3 )Ph and PEO–SC(=S)−NPh 2 , named PEO‐1 and PEO‐2 , respectively) were used as macromolecular chain‐transfer agents (macro‐CTAs) to mediate the reversible additio…
View article: Aromatic Xanthates and Dithiocarbamates for the Polymerization of Ethylene through Reversible Addition–Fragmentation Chain Transfer (RAFT)
Aromatic Xanthates and Dithiocarbamates for the Polymerization of Ethylene through Reversible Addition–Fragmentation Chain Transfer (RAFT) Open
Aromatic xanthates and dithiocarbamates were used as chain‐transfer agents (CTAs) in reversible addition–fragmentation chain‐transfer (RAFT) polymerizations of ethylene under milder conditions (≤80 °C, ≤200 bar). While detrimental side fra…
View article: Synthesis of PMMA-based block copolymers by consecutive irreversible and reversible addition–fragmentation chain transfer polymerizations
Synthesis of PMMA-based block copolymers by consecutive irreversible and reversible addition–fragmentation chain transfer polymerizations Open
Xanthate and dithiocarbamate functionalized PMMAs obtained by free radical polymerization in the presence of xanthogen and dithiuram disulfide were used for chain extension with less activated monomers such as vinyl acetate and ethylene.