Chaobo Tang
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View article: Migration behavior of Pb and Bi impurities during industrial silicon smelting
Migration behavior of Pb and Bi impurities during industrial silicon smelting Open
Organosilicon are widely used in strategic emerging industries such as national defense, high-end equipment, and biomedicine due to their superior properties. Industrial silicon serves as the primary raw material for organosilicon producti…
View article: Oxidative volatilization mechanism and kinetics of stibnite at low temperature
Oxidative volatilization mechanism and kinetics of stibnite at low temperature Open
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View article: Electrochemical mechanism and kinetics of electrodissolution-coupled hafnium alkoxide synthesis in tetraethylammonium-chloride-based anhydrous system
Electrochemical mechanism and kinetics of electrodissolution-coupled hafnium alkoxide synthesis in tetraethylammonium-chloride-based anhydrous system Open
Electrodissolution-coupled hafnium alkoxide synthesis (EHS) is a promising pathway for efficient electro- synthesis. It employs simultaneous heterogeneous reactions of Hf dissolution and ethanol dehydrogenation, and spontaneous solution-ba…
View article: One-step electrolytic reduction desulfurization of Sb2S3 in different molten salts
One-step electrolytic reduction desulfurization of Sb2S3 in different molten salts Open
A comparative analysis of different molten salt systems was conducted, including NaCl−KCl, NaCl−CaCl2, NaCl−Na2CO3, NaCl−KCl−CaCl2, and NaCl−KCl−Na2CO3. The phase diagrams, thermal stability, and solubility of Sb2S3 in molten salt systems …
View article: Interfacial Adsorption Mechanism of Diethyldithiocarbamate in High-Sulfur Residue Flotation
Interfacial Adsorption Mechanism of Diethyldithiocarbamate in High-Sulfur Residue Flotation Open
Diethyldithiocarbamate (DDTC) is employed in the sulfide ore flotation process due to its excellent collection performance. Herein, we investigated the interfacial adsorption behavior of DDTC on the four main mineral phases of high-sulfur …
View article: Interfacial Adsorption Mechanism of Diethyldithiocarbamate in High-Sulfur Residue Flotation
Interfacial Adsorption Mechanism of Diethyldithiocarbamate in High-Sulfur Residue Flotation Open
Diethyldithiocarbamate (DDTC) has been employed in the sulfide ore flotation process, due to its excellent collection performance. Herein, we investigated the interfacial adsorption behavior of DDTC on four mineral phases of high-sulfur re…
View article: Anodic Behavior of Hafnium in Anhydrous Electrodissolution-Coupled Hafnium Alkoxide Synthesis
Anodic Behavior of Hafnium in Anhydrous Electrodissolution-Coupled Hafnium Alkoxide Synthesis Open
The electrodissolution-coupled hafnium alkoxide (Hf(OR)4, R is alkyl) synthesis (EHS) system, which has significant environmental and economic advantages over conventional thermal methods, serves as a promising system for green and efficie…
View article: Leaching kinetics of de-lithium residue from spent ternary lithium-ion battery cathodic materials with starch as reductant
Leaching kinetics of de-lithium residue from spent ternary lithium-ion battery cathodic materials with starch as reductant Open
Starch was employed as a reductant for the recovery of Ni, Co, and Mn from ternary lithium-ion batteries (LIBs) cathodic materials de-lithium residue, and the leaching kinetics and mechanism were studied. The effects of stirring speed, lea…
View article: Mechanism and Application of Seed-Induced Goethite Crystal Growth for Iron Removal from Rich-Zinc Solution
Mechanism and Application of Seed-Induced Goethite Crystal Growth for Iron Removal from Rich-Zinc Solution Open
View article: Hydrometallurgical process for extracting bismuth from by-product of lead smelting based on methanesulfonic acid system
Hydrometallurgical process for extracting bismuth from by-product of lead smelting based on methanesulfonic acid system Open
A new hydrometallurgical process based on the methanesulfonic acid system was proposed to extract the bismuth efficiently from by-products of lead smelting. The bismuth extraction process includedelectrorefining, oxidation leaching, and el…
View article: Clean antimony production from stibnite concentrate with goethite residue co-treatment for zinc, iron, sulfur conservation
Clean antimony production from stibnite concentrate with goethite residue co-treatment for zinc, iron, sulfur conservation Open
View article: PbSO4 Reduction Mechanism and Gas Composition at 600–1000°C
PbSO4 Reduction Mechanism and Gas Composition at 600–1000°C Open
View article: High-temperature thermodynamics of ZnO–NH4Cl–H2O system
High-temperature thermodynamics of ZnO–NH4Cl–H2O system Open
On the basis of the principles of simultaneous equilibrium, conservation of mass, and aqueous electronic charge neutrality and the correspondence principle of ion entropy, the high-temperature thermodynamics of the ZnO–NH4Cl–H2O system was…
View article: Effects of Polyoxyethylene Ether Addition on the Nucleation and Microtopography of Zinc Electrodeposited in a Neutral Electrolyte
Effects of Polyoxyethylene Ether Addition on the Nucleation and Microtopography of Zinc Electrodeposited in a Neutral Electrolyte Open
View article: Sustainable phase-conversion method for antimony extraction and sulfur conservation and waste treatment at low temperature
Sustainable phase-conversion method for antimony extraction and sulfur conservation and waste treatment at low temperature Open
View article: Leaching of hemimorphite in neutral solution at high temperature
Leaching of hemimorphite in neutral solution at high temperature Open
The leaching behavior of hemimorphite in neutral solution (NH4 +-Cl--H2O) was investigated at high temperature (T > 100?C) under a range of experimental conditions. Thermodynamic calculations indicate that the tendency of dehydration of si…
View article: Reaction Behaviors of Associated Minerals in Molten Salt Smelting of Stibnite and Kilogram-Class Trials
Reaction Behaviors of Associated Minerals in Molten Salt Smelting of Stibnite and Kilogram-Class Trials Open
The molten salt metallurgy of Sb, which involves the smelting of stibnite in a binary NaCl-Na2CO3 salt with sulfur-fixing and the addition of a reductant, has been proposed as a clean method for Sb extraction. However, the reacting behavio…
View article: Recycling of Spent Lead-Acid Battery for Lead Extraction with Sulfur Conservation
Recycling of Spent Lead-Acid Battery for Lead Extraction with Sulfur Conservation Open
View article: Cleaner Recycling of Spent Lead-Acid Battery Paste and Co-Treatment of Pyrite Cinder via a Reductive Sulfur-Fixing Method for Valuable Metal Recovery and Sulfur Conservation
Cleaner Recycling of Spent Lead-Acid Battery Paste and Co-Treatment of Pyrite Cinder via a Reductive Sulfur-Fixing Method for Valuable Metal Recovery and Sulfur Conservation Open
This study proposes a cleaner lead-acid battery (LAB) paste and pyrite cinder (PyC) recycling method without excessive generation of SO2. PyCs were employed as sulfur-fixing reagents to conserve sulfur as condensed sulfides, which prevente…
View article: Spent Lead-Acid Battery Recycling via Reductive Sulfur-Fixing Smelting and Its Reaction Mechanism in the PbSO4-Fe3O4-Na2CO3-C System
Spent Lead-Acid Battery Recycling via Reductive Sulfur-Fixing Smelting and Its Reaction Mechanism in the PbSO4-Fe3O4-Na2CO3-C System Open
View article: Cleaner Extraction of Lead from Complex Lead-Containing Wastes by Reductive Sulfur-Fixing Smelting with Low SO2 Emission
Cleaner Extraction of Lead from Complex Lead-Containing Wastes by Reductive Sulfur-Fixing Smelting with Low SO2 Emission Open
A novel and cleaner process for lead and silver recycling from multiple lead-containing wastes, e.g., lead ash, lead sludge, lead slag, and ferric sludge, by reductive sulfur-fixing smelting was proposed. In this process, coke and iron-con…
View article: Novel recycling process for lead-acid battery paste without SO2 generation - Reaction mechanism and industrial pilot campaign
Novel recycling process for lead-acid battery paste without SO2 generation - Reaction mechanism and industrial pilot campaign Open
View article: Phase and Morphology Transformations in Sulfur-Fixing and Reduction Roasting of Antimony Sulfide
Phase and Morphology Transformations in Sulfur-Fixing and Reduction Roasting of Antimony Sulfide Open
Metallurgical extraction of antimony (Sb) currently has the limitations of high energy consumption and adverse environmental impact. In this study, we proposed a cleaning process to extract Sb by metallurgy and beneficiation based on S-fix…
View article: Hydrometallurgical Process for Zinc Recovery from C.Z.O. Generated by the Steelmaking Industry with Ammonia–Ammonium Chloride Solution
Hydrometallurgical Process for Zinc Recovery from C.Z.O. Generated by the Steelmaking Industry with Ammonia–Ammonium Chloride Solution Open
In this research, some experimental steps were investigated to recover zinc contained in crude zinc oxide (C.Z.O.). In the first stage, the C.Z.O. was treated in NH3–NH4Cl–H2O solution to dissolve the metals. The optimized leaching conditi…
View article: Thermodynamic and kinetics analysis of the sulfur-fixed roasting of antimony sulfide using ZnO as sulfur-fixing agent
Thermodynamic and kinetics analysis of the sulfur-fixed roasting of antimony sulfide using ZnO as sulfur-fixing agent Open
Currently, the commercial antimony metallurgy is mainly based on pyrometallurgical processes and oxidative volatilization of Sb2S3 is an essential step. This step includes the problems of high energy consumption and low concentration of SO…
View article: A New Pyrometallurgical Recycling Technique for Lead Battery Paste Without SO2 Generation—A Thermodynamic and Experimental Investigation
A New Pyrometallurgical Recycling Technique for Lead Battery Paste Without SO2 Generation—A Thermodynamic and Experimental Investigation Open
View article: Reductive-sulfurizing smelting treatment of smelter slag for copper and cobalt recovery
Reductive-sulfurizing smelting treatment of smelter slag for copper and cobalt recovery Open
Recovery of copper and cobalt from smelter slag using reductive-sulfurizing smelting method was performed in this study. The effects of reductive agent (coke), sulfurizing agent (pyrite), slag modifier (CaO) and smelting temperature and du…
View article: Leaching Kinetics of Hemimorphite in Ammonium Chloride Solution
Leaching Kinetics of Hemimorphite in Ammonium Chloride Solution Open
The leaching kinetics of hemimorphite (Zn4Si2O7(OH)2·H2O) in ammonium chloride solution was presented in detail. Effects of stirring speed (150–350 rpm), leaching temperature (75–108 °C), particle size of hemimorphite (45–150 μm), and the …
View article: Electrochemical Behaviour of Hafnium in Anhydrous n-butanol Containing Tetraethylammonium Bromide
Electrochemical Behaviour of Hafnium in Anhydrous n-butanol Containing Tetraethylammonium Bromide Open
View article: One-Step Extraction of Antimony in Low Temperature from Stibnite Concentrate Using Iron Oxide as Sulfur-Fixing Agent
One-Step Extraction of Antimony in Low Temperature from Stibnite Concentrate Using Iron Oxide as Sulfur-Fixing Agent Open
A new process for one-step extraction of antimony in low temperature from stibnite concentrate by reductive sulfur-fixation smelting in sodium molten salt, using iron oxide as sulfur-fixing agent, was presented. The influences of molten sa…