Charl X. Bezuidenhout
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View article: Direct Integration of Functionalized Bridges by One‐Step Superacid‐Catalyzed Reaction to Fabricate Porous Polymers for CO <sub>2</sub> Capture and Separation
Direct Integration of Functionalized Bridges by One‐Step Superacid‐Catalyzed Reaction to Fabricate Porous Polymers for CO <sub>2</sub> Capture and Separation Open
A novel class of ultra‐microporous functionalized porous organic polymers (POPs) was developed starting from glyoxylic acid as a cross‐linker and triflic acid as a catalyst on polyaromatic monomers, generating in situ methine bridges with …
View article: Direct Integration of Functionalized Bridges by One‐Step Superacid‐Catalyzed Reaction to Fabricate Porous Polymers for CO <sub>2</sub> Capture and Separation
Direct Integration of Functionalized Bridges by One‐Step Superacid‐Catalyzed Reaction to Fabricate Porous Polymers for CO <sub>2</sub> Capture and Separation Open
A novel class of ultra‐microporous functionalized porous organic polymers (POPs) was developed starting from glyoxylic acid as a cross‐linker and triflic acid as a catalyst on polyaromatic monomers, generating in situ methine bridges with …
View article: Development of a New Vaccine Adjuvant System Based on the Combination of the Synthetic TLR4 Agonist FP20 and a Synthetic QS-21 Variant
Development of a New Vaccine Adjuvant System Based on the Combination of the Synthetic TLR4 Agonist FP20 and a Synthetic QS-21 Variant Open
In this study, we formulated an alternative to AS01b by combining FP20, a synthetic TLR4 agonist, and QS21v, a minimal saponin adjuvant, aiming to improve the vaccine efficacy and stability. The phase transition temperature of FP20 was det…
View article: Reabsorption‐Free Scintillating Hetero‐Ligand MOF Crystals Activated by Ultrafast Energy Transfer
Reabsorption‐Free Scintillating Hetero‐Ligand MOF Crystals Activated by Ultrafast Energy Transfer Open
Fast photoluminescence and scintillation with a Stokes shift larger than 1 eV is achieved in hetero‐ligand metal–organic framework (MOF) crystals comprising inorganic linking nodes and fluorescent conjugated ligands. By finely engineering …
View article: Graphical Abstract: Angew. Chem. Int. Ed. 10/2024
Graphical Abstract: Angew. Chem. Int. Ed. 10/2024 Open
In their Research Article (e202314112), Andreas Dreuw
View article: Solid State Machinery of Multiple Dynamic Elements in a Metal–Organic Framework
Solid State Machinery of Multiple Dynamic Elements in a Metal–Organic Framework Open
Engineering coordinated rotational motion in porous architectures enables the fabrication of molecular machines in solids. A flexible two‐fold interpenetrated pillared Metal‐Organic Framework precisely organizes fast mobile elements such a…
View article: Novel CO<sub>2</sub>-philic porous organic polymers synthesized in water: a leap towards eco-sustainability
Novel CO<sub>2</sub>-philic porous organic polymers synthesized in water: a leap towards eco-sustainability Open
β-Keto-enamine POPs, synthesized in water at relatively low temperatures, without catalysts, and using common glassware, exhibit a competitive adsorption capacity and high selectivity for CO 2 over N 2 at 298 K (1 bar).
View article: Construction of a three-state responsive framework from a bistable photoswitch
Construction of a three-state responsive framework from a bistable photoswitch Open
View article: Efficient radioactive gas detection by scintillating porous metal–organic frameworks
Efficient radioactive gas detection by scintillating porous metal–organic frameworks Open
Natural and anthropogenic gas radionuclides such as radon, xenon, hydrogen and krypton isotopes must be monitored to be managed as pathogenic agents, radioactive diagnostic agents or nuclear activity indicators. State-of-the-art detectors …
View article: CCDC 2194588: Experimental Crystal Structure Determination
CCDC 2194588: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2194589: Experimental Crystal Structure Determination
CCDC 2194589: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2194591: Experimental Crystal Structure Determination
CCDC 2194591: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2194587: Experimental Crystal Structure Determination
CCDC 2194587: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2194592: Experimental Crystal Structure Determination
CCDC 2194592: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2194593: Experimental Crystal Structure Determination
CCDC 2194593: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2194590: Experimental Crystal Structure Determination
CCDC 2194590: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Efficient radioactive gas detection by porous metal-organic framework scintillating nanocrystals.
Efficient radioactive gas detection by porous metal-organic framework scintillating nanocrystals. Open
Natural radioactive gases and anthropogenic radionuclides such as radon, xenon, hydrogen and krypton isotopes, need to be carefully monitored to be properly managed as pathogenic agents, radioactive diagnostic agents or indicators of nucle…
View article: Benchmark Dynamics of Dipolar Molecular Rotors in Fluorinated Metal‐Organic Frameworks
Benchmark Dynamics of Dipolar Molecular Rotors in Fluorinated Metal‐Organic Frameworks Open
Fluorinated Metal‐Organic Frameworks (MOFs), comprising a wheel‐shaped ligand with geminal rotating fluorine atoms, produced benchmark mobility of correlated dipolar rotors at 2 K, with practically null activation energy ( E a =17 cal mol …
View article: CCDC 2131110: Experimental Crystal Structure Determination
CCDC 2131110: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Highly luminescent scintillating hetero-ligand MOF nanocrystals with engineered Stokes shift for photonic applications
Highly luminescent scintillating hetero-ligand MOF nanocrystals with engineered Stokes shift for photonic applications Open
Large Stokes shift fast emitters show a negligible reabsorption of their luminescence, a feature highly desirable for several applications such as fluorescence imaging, solar-light managing, and fabricating sensitive scintillating detector…
View article: CCDC 2000249: Experimental Crystal Structure Determination
CCDC 2000249: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Highly luminescent hetero-ligand MOF nanocrystals with engineered massive Stokes shift for photonic applications.
Highly luminescent hetero-ligand MOF nanocrystals with engineered massive Stokes shift for photonic applications. Open
A high efficiency emission with a massive Stokes shift is obtained by fluorescent conjugated acene building blocks arranged in nanocrystals. The two ligands of equal molecular length and connectivity, yet complementary electronic propertie…
View article: CCDC 2069997: Experimental Crystal Structure Determination
CCDC 2069997: Experimental Crystal Structure Determination Open
View article: CCDC 2069998: Experimental Crystal Structure Determination
CCDC 2069998: Experimental Crystal Structure Determination Open
View article: CCDC 2069996: Experimental Crystal Structure Determination
CCDC 2069996: Experimental Crystal Structure Determination Open
View article: CCDC 2070080: Experimental Crystal Structure Determination
CCDC 2070080: Experimental Crystal Structure Determination Open
View article: Cascade Dynamics of Multiple Molecular Rotors in a MOF: Benchmark Mobility at a Few Kelvins and Dynamics Control by CO<sub>2</sub>
Cascade Dynamics of Multiple Molecular Rotors in a MOF: Benchmark Mobility at a Few Kelvins and Dynamics Control by CO<sub>2</sub> Open
Achieving sophisticated juxtaposition of geared molecular rotors with negligible energy-requirements in solids enables fast yet controllable and correlated rotary motion to construct switches and motors. Our endeavor was to realize multipl…
View article: Composite fast scintillators based on high-Z fluorescent metal–organic framework nanocrystals
Composite fast scintillators based on high-Z fluorescent metal–organic framework nanocrystals Open
View article: Calixarene-based porous 3D polymers and copolymers with high capacity and binding energy for CO<sub>2</sub>, CH<sub>4</sub>and Xe capture
Calixarene-based porous 3D polymers and copolymers with high capacity and binding energy for CO<sub>2</sub>, CH<sub>4</sub>and Xe capture Open
Calixarene-based porous polymers and copolymers with surface area of 3000 m 2 g −1 selectively capture CO 2 and CH 4 (DH of 35 and 24 kJ mol −1 , respectively) in specific sites, as revealed by microcalorimetry, breakthrough experiments an…
View article: CCDC 1994504: Experimental Crystal Structure Determination
CCDC 1994504: Experimental Crystal Structure Determination Open