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View article: The role of ligand design affecting the thermal and light-induced spin transition in mononuclear iron(II) complexes
The role of ligand design affecting the thermal and light-induced spin transition in mononuclear iron(II) complexes Open
Molecules are increasingly considered for information processing and sensing applications. Therefore, much research has focused on the improvement of such property changes, especially the ability to observe the switching at room temperatur…
View article: Switchable Heteroleptic Mononuclear Iron(II) Complexes as Versatile Molecular Building Block
Switchable Heteroleptic Mononuclear Iron(II) Complexes as Versatile Molecular Building Block Open
A series of photoswitchable precursors based on [Fe(NCX) 2 L(L′) 2 ], where X = S or Se, L is a bidentate ligand (phenanthroline or bipyrimidine), and L′ a monodentate ligand such as a pyridine or picoline derivative, were synthesized and …
View article: Seven-coordinated iron(<scp>ii</scp>) spin-crossover molecules: some learning from iron substitution in [Fe<sub>x</sub>Mn<sub>1−x</sub>(L<sub>222</sub>N<sub>3</sub>O<sub>2</sub>)(CN)<sub>2</sub>]·H<sub>2</sub>O solid solutions
Seven-coordinated iron(<span>ii</span>) spin-crossover molecules: some learning from iron substitution in [Fe<sub>x</sub>Mn<sub>1−x</sub>(L<sub>222</sub>N<sub>3</sub>O<sub>2</sub>)(CN)<sub>2</sub>]·H<sub>2</sub>O solid solutions Open
Temperature dependence of (χMT)Fe for [FexMn1−x(L222N3O2)(CN)2]·H2O of the T(TIESST) experiment with x = 1 (in violet ), 0.949 (in blue ), 0.93 (in red ), 0.912 (in green ), 0.892 (in olive ) and 0.853 (in black ■).
View article: On the Effect of the Internal Pressure on the Photoinduced Spin‐Crossover Behavior of [Fe<i><sub>x</sub></i>M<sub>1–<i>x</i></sub>(1,10‐phenanthroline)<sub>2</sub>(NCS)<sub>2</sub>] Solid Solutions (M = Ni<sup>II</sup>, Zn<sup>II</sup>, and Cd<sup>II</sup>)
On the Effect of the Internal Pressure on the Photoinduced Spin‐Crossover Behavior of [Fe<i><sub>x</sub></i>M<sub>1–<i>x</i></sub>(1,10‐phenanthroline)<sub>2</sub>(NCS)<sub>2</sub>] Solid Solutions (M = Ni<sup>II</sup>, Zn<sup>II</sup>, and Cd<sup>II</sup>) Open
The thermal and light‐induced magnetic properties of a family of metal‐diluted spin‐crossover complexes, [Fe x M 1– x (phen) 2 (NCS) 2 ] (phen = 1,10‐phenantholine and M = Ni II , Cd II ), are reported and compared to previous results obta…