Christopher Deldaele
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View article: A general synthesis of azetidines by copper-catalysed photoinduced anti-Baldwin radical cyclization of ynamides
A general synthesis of azetidines by copper-catalysed photoinduced anti-Baldwin radical cyclization of ynamides Open
View article: [(DPEPhos)(bcp)Cu]PF<sub>6</sub>: A General and Broadly Applicable Copper-Based Photoredox Catalyst
[(DPEPhos)(bcp)Cu]PF<sub>6</sub>: A General and Broadly Applicable Copper-Based Photoredox Catalyst Open
Our group recently reported the use of [(DPEPhos)(bcp)Cu]PF6 as a general copper-based photoredox catalyst which proved efficient to promote the activation of a broad variety of organic halides, including unactivated ones. These can then p…
View article: Copper-Mediated N-Arylations of Hydantoins
Copper-Mediated N-Arylations of Hydantoins Open
A set of two broadly applicable procedures for the N-arylation of hydantoins is reported. The first one relies on the use of stoichiometric copper(I) oxide under ligand- and base-free conditions and enables a clean regioselective arylation…
View article: A General Copper-based Photoredox Catalyst for Organic Synthesis: Scope, Application in Natural Product Synthesis and Mechanistic Insights
A General Copper-based Photoredox Catalyst for Organic Synthesis: Scope, Application in Natural Product Synthesis and Mechanistic Insights Open
Organic transformations can broadly be classified into four categories including cationic, anionic, pericyclic and radical reactions. While the last category has been known for decades to provide remarkably efficient synthetic pathways, it…
View article: Copper-Catalyzed Photoinduced Radical Domino Cyclization of Ynamides and Cyanamides: A Unified Entry to Rosettacin, Luotonin A, and Deoxyvasicinone
Copper-Catalyzed Photoinduced Radical Domino Cyclization of Ynamides and Cyanamides: A Unified Entry to Rosettacin, Luotonin A, and Deoxyvasicinone Open
A general and efficient procedure for the copper-catalyzed photoinduced radical domino cyclization of ynamides and cyanamides providing an efficient access to complex tri-, tetra- and pentacyclic nitrogen heterocycles is reported. Upon vis…