Christopher E. Anson
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View article: Stability and Ultrafast Dynamics of Luminescent Biquinoxen-Bis-σH-Adducts
Stability and Ultrafast Dynamics of Luminescent Biquinoxen-Bis-σH-Adducts Open
We report the synthesis of two new biquinoxen-σH-adducts (3,3′-diisopropoxy-4,4′-dimethyl-3,3′,4,4′-tetrahydro-2,2′-biquinoxaline (Mbqn-(OiPr)2) (1) and 3,3′-bis(isopropylthio)-4,4′-dimethyl-3,3′,4,4′-tetrahydro-2,2′-biquinoxaline (Mbqn-(S…
View article: Finding lanthanide magnetic anisotropy axes in 3d-4f butterfly single-molecule magnets using inelastic neutron scattering
Finding lanthanide magnetic anisotropy axes in 3d-4f butterfly single-molecule magnets using inelastic neutron scattering Open
View article: Giant Molecular Toroidal Moment Amenable to Direct Observation in a Fe$_{10}$Dy$_{10}$ Ring
Giant Molecular Toroidal Moment Amenable to Direct Observation in a Fe$_{10}$Dy$_{10}$ Ring Open
In single molecule toroics (SMTs) atomic spins and orbital currents generate magnetic vortices known as toroidal moments $\boldsymbolτ$, endowed with both magnetic and electric dipole symmetries, which can enable spin control via magnetoel…
View article: Adding Time-Domain 161Dy Mössbauer to the Mix: a Multitechnique Investigation of Magnetic Transitions in a {CoIII3DyIII3} Cluster with a Toroidal Moment
Adding Time-Domain 161Dy Mössbauer to the Mix: a Multitechnique Investigation of Magnetic Transitions in a {CoIII3DyIII3} Cluster with a Toroidal Moment Open
The coordination cluster [CoIII3DyIII3(µ3-OH)4(O2C-C6H4-p-Me)6(pmide)3(H2O)3]Cl2∙10Me…
View article: The Interplay of Single Ion Anisotropy and Magnetic 3 <i>d</i>‐4 <i>f</i> Interactions in V<sup>III</sup><sub>2</sub>Ln<sup>III</sup><sub>2</sub> Butterfly Complexes
The Interplay of Single Ion Anisotropy and Magnetic 3 <i>d</i>‐4 <i>f</i> Interactions in V<sup>III</sup><sub>2</sub>Ln<sup>III</sup><sub>2</sub> Butterfly Complexes Open
Within the framework of 3 d –4 f molecular magnets, the most thoroughly investigated architecture is that of butterfly‐shaped coordination clusters as it provides an ideal testbed to study fundamental magnetic interactions. Here, we report…
View article: Transferability of Ligand Field Parameters in a Family of 3d-4f M<sub>2</sub>Ln<sub>2</sub> Butterfly Single-Molecule Magnets
Transferability of Ligand Field Parameters in a Family of 3d-4f M<sub>2</sub>Ln<sub>2</sub> Butterfly Single-Molecule Magnets Open
Lanthanide-based single-molecule magnets are attractive candidates for applications in quantum information processing or data storage. The low symmetry ligand field environment often encountered in these complexes, combined with a sparsity…
View article: Unexpected stability of the iron(II) complex by an asymmetrical Schiff base from Fe(III): structure, magnetic and Mössbauer investigations
Unexpected stability of the iron(II) complex by an asymmetrical Schiff base from Fe(III): structure, magnetic and Mössbauer investigations Open
The asymmetric Schiff base prepared in situ from ethylenediamine and pyridine-2-carboxaldehyde reacts with Fe(ClO 4 ) 3 ·6H 2 O to form the Fe(II) complex [FeL 2 ](ClO 4 ) 2 with L = N , N -diethyl- N ′-(pyridin-2-yl)methylene)ethane-1,2-d…
View article: Dinuclear Dysprosium Compounds: The Importance of Rigid Bridges
Dinuclear Dysprosium Compounds: The Importance of Rigid Bridges Open
We report the synthesis, structures and magnetic behaviour of two isostructural dinuclear Dy 3+ complexes where the metal ions of a previously reported monomeric building block are connected by a peroxide (O 2 2− ) or a pair of fluoride (2…
View article: Self‐Assembly of four Ni<sub>16</sub> Molecular Wheels with Capsule and Tubular Supramolecular Architectures
Self‐Assembly of four Ni<sub>16</sub> Molecular Wheels with Capsule and Tubular Supramolecular Architectures Open
Four new Ni 16 molecular wheels with the general formula [ L 4 Ni 16 (RCOO) 16 (H 2 O) x (MeOH) 12‐x ] (where H 4 L =1,4‐bis(( E )‐((2’‐hydroxybenzyl)imino)methyl)‐2,3‐naphthalenediol, and R=H or Me) have been isolated and structurally cha…
View article: Mononuclear Fe(III) Schiff Base Complex with Trans-FeO4N2 Chromophore of o-Aminophenol Origin: Synthesis, Characterisation, Crystal Structure, and Spin State Investigation
Mononuclear Fe(III) Schiff Base Complex with Trans-FeO4N2 Chromophore of o-Aminophenol Origin: Synthesis, Characterisation, Crystal Structure, and Spin State Investigation Open
A new iron(III) complex (Et3NH)2[Fe(L)2](ClO4)·MeOH (1) where H2L = 2-{(E)-[2-hydroxyphenyl)imino]methyl}phenol has been synthesised and characterised by single crystal XRD, elemental analysis and DC magnetic susceptibility measurements. T…
View article: CCDC 2306455: Experimental Crystal Structure Determination
CCDC 2306455: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: An Effectively Uncoupled Gd8 Cluster Formed through Fixation of Atmospheric CO2 Showing Excellent Magnetocaloric Properties
An Effectively Uncoupled Gd8 Cluster Formed through Fixation of Atmospheric CO2 Showing Excellent Magnetocaloric Properties Open
The [Gd8(opch)8(CO3)4(H2O)8]·4H2O·10MeCN coordination cluster (1) crystallises in P1¯. The Gd8 core is held together by four bridging carbonates derived from atmospheric CO2 as well as the carboxyhydrazonyl oxygens of the 2-hydroxy-3-metho…
View article: A nested spin structure and single molecule magnet behaviour in an Fe<sub>8</sub>Dy<sub>12</sub> heterometallic cyclic coordination cluster
A nested spin structure and single molecule magnet behaviour in an Fe<sub>8</sub>Dy<sub>12</sub> heterometallic cyclic coordination cluster Open
The evaluation of the magnetic hysteresis of a saddle-shaped Fe 8 Dy 12 cyclic coordination cluster (CCC) using MAGELLAN reveals three sets of Dy III anisotropy axes.
View article: CCDC 2278369: Experimental Crystal Structure Determination
CCDC 2278369: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2285993: Experimental Crystal Structure Determination
CCDC 2285993: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: A nickel(II) complex with an unsymmetrical tetradentate chelating ligand derived from pyridine-2,6-dicarbaldehyde and 2-aminothiophenol
A nickel(II) complex with an unsymmetrical tetradentate chelating ligand derived from pyridine-2,6-dicarbaldehyde and 2-aminothiophenol Open
[(2-{[6-(1,3-Benzothiazol-2-yl)pyridin-2-yl]carbonylazanidyl}phenyl)sulfanido]nickel(II), [Ni(C 19 H 11 N 3 OS 2 )], crystallizes in the centrosymmetric monoclinic space group P 2 1 / n with one molecule in the asymmetric unit. The expecte…
View article: CCDC 2217868: Experimental Crystal Structure Determination
CCDC 2217868: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2217869: Experimental Crystal Structure Determination
CCDC 2217869: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 969280: Experimental Crystal Structure Determination
CCDC 969280: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 969276: Experimental Crystal Structure Determination
CCDC 969276: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2157252: Experimental Crystal Structure Determination
CCDC 2157252: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2157728: Experimental Crystal Structure Determination
CCDC 2157728: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2157725: Experimental Crystal Structure Determination
CCDC 2157725: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2157726: Experimental Crystal Structure Determination
CCDC 2157726: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2157727: Experimental Crystal Structure Determination
CCDC 2157727: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: An Inorganic Pac‐Man: Synthesis, structure and electrochemical studies of a heterometallic {YCo<sup>II</sup><sub>3</sub>W} cluster sandwiched by two germanotungstates
An Inorganic Pac‐Man: Synthesis, structure and electrochemical studies of a heterometallic {YCo<sup>II</sup><sub>3</sub>W} cluster sandwiched by two germanotungstates Open
A new heterometallic sandwich‐type Keggin polyoxometalate, [(GeW 9 O 34 ) 2 {YCo(W=O)(μ 3 ‐O)(μ 3 ‐OH)(μ 2 ‐O)(μ 2 ‐OH 2 )(OH 2 )(C 2 H 3 O 2 )}] 13− has been synthesized by a simple reaction method. The isolated compound has been structur…
View article: Keeping dysprosium in line: Trinuclear heterometallic M<sup>II</sup><sub>2</sub>Dy<sup>III</sup> complexes with M=Cd, Co and Cu
Keeping dysprosium in line: Trinuclear heterometallic M<sup>II</sup><sub>2</sub>Dy<sup>III</sup> complexes with M=Cd, Co and Cu Open
Four new heterometallic trinuclear essentially linear (“in‐line”) M II 2 Dy III complexes (M=Cd II ( 1 ), Co II ( 2 ), Cu II ( 3 , 4 ) were synthesised using the ligand 3,5‐di‐ tert ‐butylbenzoic acid (dtbbaH) in a MeCN : i PrOH ( 1–3 ) or…
View article: CCDC 2155664: Experimental Crystal Structure Determination
CCDC 2155664: Experimental Crystal Structure Determination Open
View article: CCDC 2155663: Experimental Crystal Structure Determination
CCDC 2155663: Experimental Crystal Structure Determination Open
View article: CCDC 2155665: Experimental Crystal Structure Determination
CCDC 2155665: Experimental Crystal Structure Determination Open