Shichun Mu
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View article: Multiscale Failure Mechanisms of Ternary Oxide Cathode Materials for Lithium‐Ion Batteries
Multiscale Failure Mechanisms of Ternary Oxide Cathode Materials for Lithium‐Ion Batteries Open
Ternary oxide cathodes (LiNi x Co y Mn 1‐x‐y O 2 , NCM) have emerged as promising candidates for lithium‐ion batteries (LIBs) due to high energy densities and tunable electrochemical properties. However, their structural degradation during…
View article: Direct Regeneration of Degraded High‐Nickel Layered Cathode with a Grain‐Growth Inhibitor by Epitaxial Boundaries
Direct Regeneration of Degraded High‐Nickel Layered Cathode with a Grain‐Growth Inhibitor by Epitaxial Boundaries Open
The direct regeneration of degraded cathode materials for lithium‐ion batteries holds significant promise for closed‐loop recycling. However, fully recovering the structure and performance of degraded LiNi x Co y Mn z O 2 (NCM) cathodes re…
View article: Upcycling Spent Cathodes into Gradient Electrocatalysts for Seawater Electrolysis
Upcycling Spent Cathodes into Gradient Electrocatalysts for Seawater Electrolysis Open
The rapid growth of lithium-ion batteries (LIBs) is lighting a more sustainable transportation driven by electric vehicles. However, the end-of-life LIBs in the next decades will pose key challenges to the resource economy and environment …
View article: Ultrafast Carbothermal Shock Synthesis of Intermetallic Silicides with Anion‐Cation Double Active Sites for Efficient Hydrogen Evolution
Ultrafast Carbothermal Shock Synthesis of Intermetallic Silicides with Anion‐Cation Double Active Sites for Efficient Hydrogen Evolution Open
The exploration and elucidation of the active site of catalysts is crucial for advancing the comprehension of the catalytic mechanism and propelling the development of exceptional catalysts. Herein, it is unveiled that anionic Si and catio…
View article: Cu–N–C support confinement stabilizes active Co sites in oxygen reduction reaction
Cu–N–C support confinement stabilizes active Co sites in oxygen reduction reaction Open
View article: External field-assisted catalysis
External field-assisted catalysis Open
In recent years, substantial effort has been dedicated to improving the intrinsic catalytic activity of catalysts through structural modification, component regulation, and chemical state optimization. However, complexity in the design and…
View article: MOF-derived carbon-coated NiS/NiS2 yolk-shell spheres as a satisfactory positive electrode material for hybrid supercapacitors
MOF-derived carbon-coated NiS/NiS2 yolk-shell spheres as a satisfactory positive electrode material for hybrid supercapacitors Open
View article: Insights into multivariate zeolitic imidazolate frameworks
Insights into multivariate zeolitic imidazolate frameworks Open
With the explosive growth of research focused on building units and types of crystalline materials, disruptive changes in the physical and/or chemical properties of crystals have been discovered. As the most studied subclass of metal-organ…
View article: Solid-state stepwise temperature-programmable synthesis of bioinspired Fe-N-C oxygen reduction electrocatalyst featuring Fe-N <sub>5</sub> configuration
Solid-state stepwise temperature-programmable synthesis of bioinspired Fe-N-C oxygen reduction electrocatalyst featuring Fe-N <sub>5</sub> configuration Open
View article: Author Correction: Twin-distortion modulated ultra-low coordination PtRuNi-Ox catalyst for enhanced hydrogen production from chemical wastewater
Author Correction: Twin-distortion modulated ultra-low coordination PtRuNi-Ox catalyst for enhanced hydrogen production from chemical wastewater Open
View article: Strengthened d–p orbital hybridization and hydrogen diffusion in a hollow N-doped porous carbon/Ru cluster catalyst system for hydrogen evolution reactions
Strengthened d–p orbital hybridization and hydrogen diffusion in a hollow N-doped porous carbon/Ru cluster catalyst system for hydrogen evolution reactions Open
Hollow and N-doped porous carbon structures enhanced hydrogen diffusion and the d–p hybridization effect with Ru clusters, thereby boosting the HER performance.
View article: Ultra-Rapid Hydrogen Evolution Reaction Kinetics Over Ceo2@Ptcu Coaxial Nanocables
Ultra-Rapid Hydrogen Evolution Reaction Kinetics Over Ceo2@Ptcu Coaxial Nanocables Open
View article: Twin-distortion modulated ultra-low coordination PtRuNi-Ox catalyst for enhanced hydrogen production from chemical wastewater
Twin-distortion modulated ultra-low coordination PtRuNi-Ox catalyst for enhanced hydrogen production from chemical wastewater Open
View article: Valorization of spent lithium-ion battery cathode materials for energy conversion reactions
Valorization of spent lithium-ion battery cathode materials for energy conversion reactions Open
With large-scale commercial applications of lithium-ion batteries (LIBs), lots of spent LIBs will be produced and cause huge waste of resources and greatly increased environmental problems. Thus, recycling spent LIB materials is inevitable…
View article: Fe-S dually modulated adsorbate evolution and lattice oxygen compatible mechanism for water oxidation
Fe-S dually modulated adsorbate evolution and lattice oxygen compatible mechanism for water oxidation Open
Simultaneously activating metal and lattice oxygen sites to construct a compatible multi-mechanism catalysis is expected for the oxygen evolution reaction (OER) by providing highly available active sites and mediate catalytic activity/stab…
View article: Entropy-increased LiMn2O4-based positive electrodes for fast-charging lithium metal batteries
Entropy-increased LiMn2O4-based positive electrodes for fast-charging lithium metal batteries Open
View article: Bicontinuous RuO2 nanoreactors for acidic water oxidation
Bicontinuous RuO2 nanoreactors for acidic water oxidation Open
View article: Sharply expanding single-atomically dispersed Fe–N active sites through bidirectional coordination for oxygen reduction
Sharply expanding single-atomically dispersed Fe–N active sites through bidirectional coordination for oxygen reduction Open
Triphenylphosphine not only restricts Fe growth with 2-methylimidazole in bidirectional confinement to obtain high-density Fe–N sites, but also prevents the irregular aggregation of Fe on the carbon surface to generate positive Fe 2 P nano…
View article: Solid-State Stepwise Temperature-Programmable Synthesis of Bioinspired Fe-N-C Oxygen Reduction Electrocatalyst Featuring Fe-N5 Configuration
Solid-State Stepwise Temperature-Programmable Synthesis of Bioinspired Fe-N-C Oxygen Reduction Electrocatalyst Featuring Fe-N5 Configuration Open
View article: Oxygen Octahedral Void-Confined Iodine Single-Site Ruo2 Catalysts for Water Reduction
Oxygen Octahedral Void-Confined Iodine Single-Site Ruo2 Catalysts for Water Reduction Open
View article: Correlating Single‐Atomic Ruthenium Interdistance with Long‐Range Interaction Boosts Hydrogen Evolution Reaction Kinetics (Adv. Mater. 2/2024)
Correlating Single‐Atomic Ruthenium Interdistance with Long‐Range Interaction Boosts Hydrogen Evolution Reaction Kinetics (Adv. Mater. 2/2024) Open
View article: Dual active site-mediated Ir single-atom-doped RuO <sub>2</sub> catalysts for highly efficient and stable water splitting
Dual active site-mediated Ir single-atom-doped RuO <sub>2</sub> catalysts for highly efficient and stable water splitting Open
Ru and Ir sites on Ir single-atom-doped RuO 2 with the lowest rate-determining step reaction energy barriers towards the HER and OER, respectively.
View article: Revitalizing osmium-based catalysts for energy conversion
Revitalizing osmium-based catalysts for energy conversion Open
Designing high cost-effective catalysts has been one of the core topics in energy conversion and storage. Due to unique electronic structure and excellent comprehensive properties, Pt-group metal (PGM) based-materials occupy the top region…
View article: Ru Cluster Incorporated NiMoO(P)<sub>4</sub> Nanosheet Arrays as High‐Efficient Bifunctional Catalyst for Wind/Solar‐To‐Hydrogen Generation Systems
Ru Cluster Incorporated NiMoO(P)<sub>4</sub> Nanosheet Arrays as High‐Efficient Bifunctional Catalyst for Wind/Solar‐To‐Hydrogen Generation Systems Open
Developing cost‐efficient bifunctional water splitting catalysts is crucial for sustainable hydrogen energy applications. Herein, ruthenium (Ru)‐incorporated and phosphorus (P)‐doped nickel molybdate (Ru‐NiMoO(P) 4 ) nanosheet array cataly…
View article: Tuning Active Metal Atomic Spacing by Filling of Light Atoms and Resulting Reversed Hydrogen Adsorption-Distance Relationship for Efficient Catalysis
Tuning Active Metal Atomic Spacing by Filling of Light Atoms and Resulting Reversed Hydrogen Adsorption-Distance Relationship for Efficient Catalysis Open
View article: Monomicelle‐Directed Engineering of Strained Carbon Nanoribbons as Oxygen Reduction Catalyst
Monomicelle‐Directed Engineering of Strained Carbon Nanoribbons as Oxygen Reduction Catalyst Open
To date, precisely tailoring local active sites of well‐defined earth‐abundant metal‐free carbon‐based electrocatalysts for attractive electrocatalytic oxygen reduction reaction (ORR), remains challenging. Herein, the authors successfully …
View article: Flower‐Like Amorphous MoO<sub>3−</sub><i><sub>x</sub></i> Stabilized Ru Single Atoms for Efficient Overall Water/Seawater Splitting
Flower‐Like Amorphous MoO<sub>3−</sub><i><sub>x</sub></i> Stabilized Ru Single Atoms for Efficient Overall Water/Seawater Splitting Open
Benefitting from the maximum atom utilization efficiency, special size quantum effects and tailored active sites, single‐atom catalysts (SACs) have been promising candidates for bifunctional catalysts toward water splitting. Besides, due t…
View article: Ultra‐Fast In Situ Reconstructed Nickel (Oxy)Hydroxide Nanoparticle Crosslinked Structure for Super‐Efficient Alkaline Water Electrolysis by Sacrificing Template Strategy
Ultra‐Fast In Situ Reconstructed Nickel (Oxy)Hydroxide Nanoparticle Crosslinked Structure for Super‐Efficient Alkaline Water Electrolysis by Sacrificing Template Strategy Open
The rapid construction of water electrolysis catalysts by a sacrificing template in an electrochemical environment is rarely a concern. Herein, using a fluorine‐rich (F‐rich) nickel fluoride (NiF 2 ) grown on nickel foam (NF) as a sacrific…
View article: Alkaline Hydrogen Oxidation Reaction Catalysts: Insight into Catalytic Mechanisms, Classification, Activity Regulation and Challenges
Alkaline Hydrogen Oxidation Reaction Catalysts: Insight into Catalytic Mechanisms, Classification, Activity Regulation and Challenges Open
Hydrogen oxidation reaction (HOR) is an important semi‐cell reaction in the renewable energy conversion technology such as fuel cells. However, due to the slow reaction rate, the development of highly active catalysts remains a major chall…
View article: Acidic oxygen evolution reaction: Mechanism, catalyst classification, and enhancement strategies
Acidic oxygen evolution reaction: Mechanism, catalyst classification, and enhancement strategies Open
As the most desirable hydrogen production device, the highly efficient acidic proton exchange membrane water electrolyzers (PEMWE) are severely limited by the sluggish kinetics of oxygen evolution reaction (OER) at the anode. Rutile IrO 2 …