Claude P. Gros
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View article: Electrocatalytic CO<sub>2</sub> to CO and Methanol Conversion Using a Molecular Cobalt Corrole Complex
Electrocatalytic CO<sub>2</sub> to CO and Methanol Conversion Using a Molecular Cobalt Corrole Complex Open
International audience
View article: CoCorrole‐Functionalized PCN‐222 for Carbon Monoxide Selective Adsorption
CoCorrole‐Functionalized PCN‐222 for Carbon Monoxide Selective Adsorption Open
The high risk of CO poisoning justifies the need for indoor air quality control and warning systems based on the detection of low concentrations (ppm‐ppb) of CO. Cobalt corrole complexes selectively bind CO vs . O 2 , CO 2 , N 2 , opening …
View article: Synthesis and characterization of new acid-functionalized porphyrins displaying antimicrobial activity against gram positive bacteria, yeasts and filamentous fungi with or without ultra-high irradiance
Synthesis and characterization of new acid-functionalized porphyrins displaying antimicrobial activity against gram positive bacteria, yeasts and filamentous fungi with or without ultra-high irradiance Open
The antimicrobial activity of new acid-functionalized porphyrins, with or without ultra-high irradiance, was investigated. Antibacterial efficacy was evaluated against Staphylococcus aureus (methicillin-resistant or methicillin-sensitive s…
View article: Inverse Hypercorroles
Inverse Hypercorroles Open
Ground-state and time-dependent density functional theory (TDDFT) calculations with the long-range-corrected, Coulomb-attenuating CAMY-B3LYP exchange-correlation functional and large, all-electron STO-TZ2P basis sets have been used to exam…
View article: Inverse Hypercorroles
Inverse Hypercorroles Open
Ground-state and time-dependent density functional theory (TDDFT) calculations with the long-range-corrected, Coulomb-attenuating CAMY-B3LYP exchange-correlation functional and large, all-electron STO-TZ2P basis sets have been used to exam…
View article: Perylenes, Porphyrins, and Other Large Dye Molecules for Molecular Layer Deposition
Perylenes, Porphyrins, and Other Large Dye Molecules for Molecular Layer Deposition Open
Molecular layer deposition (MLD) is an incredibly powerful and flexible tool for designing completely new materials with novel and unique properties. The low temperature layer‐by‐layer approach and the use of highly reactive reactants allo…
View article: Cobalt tris(4-vinylphenyl)corrole: out of the frying pan into the polymer
Cobalt tris(4-vinylphenyl)corrole: out of the frying pan into the polymer Open
A novel cobalt corrole bearing 4-vinylphenyl groups at the 5,10,15- meso -positions of the macrocycle has been synthesized from tris(4-bromophenyl)corrole using a Suzuki coupling reaction.
View article: Identifying G-Quadruplex-DNA-Disrupting Small Molecules
Identifying G-Quadruplex-DNA-Disrupting Small Molecules Open
The quest for small molecules that strongly bind to G-quadruplex-DNA (G4), so-called G4 ligands, has invigorated the G4 research field from its very inception. Massive efforts have been invested to discover or rationally design G4 ligands,…
View article: Here’s looking at the reduction of noninnocent copper corroles via anion induced electron transfer
Here’s looking at the reduction of noninnocent copper corroles via anion induced electron transfer Open
The synthesis, electrochemical and spectroscopic characterization of five copper triarylcorroles bearing one, two or three meso -nitroaryl substituents is reported. Redox potentials and spectroscopic properties of the neutral Cu(II) corrol…
View article: SAW based CO2 sensor: influence of functionalizing MOF crystal size on the sensor's selectivity
SAW based CO2 sensor: influence of functionalizing MOF crystal size on the sensor's selectivity Open
International audience
View article: Correction to “Multimodal Theranostic Cyanine-Conjugated Gadolinium(III) Complex for <i>In Vivo</i> Imaging of Amyloid-β in Alzheimer’s Disease Mouse Model”
Correction to “Multimodal Theranostic Cyanine-Conjugated Gadolinium(III) Complex for <i>In Vivo</i> Imaging of Amyloid-β in Alzheimer’s Disease Mouse Model” Open
ADVERTISEMENT RETURN TO ISSUEPREVAddition/CorrectionNEXTORIGINAL ARTICLEThis notice is a correctionCorrection to "Multimodal Theranostic Cyanine-Conjugated Gadolinium(III) Complex for In Vivo Imaging of Amyloid-β in Alzheimer's Disease Mou…
View article: Disclosing the actual efficiency of G-quadruplex-DNA–disrupting small molecules
Disclosing the actual efficiency of G-quadruplex-DNA–disrupting small molecules Open
The quest for small molecules that avidly bind to G-quadruplex-DNA (G4-DNA, or G4), so called G4-ligands, has invigorated the G4 research field from its very inception. Massive efforts have been invested to i - screen or design G4-ligands,…
View article: Solvent and Anion Effects on the Electrochemistry of Manganese Dipyrrin-Bisphenols
Solvent and Anion Effects on the Electrochemistry of Manganese Dipyrrin-Bisphenols Open
A series of "N2O2-type" manganese dipyrrin-bisphenols (DPP), formulated as (Ar)DPPMn, where Ar = pentafluorophenyl (F5Ph), phenyl (Ph), or mesityl (Mes), were electrochemically and spectroscopically characterized in nonaqueous media with a…
View article: Old Dog, New Tricks: Innocent, Five-coordinate Cyanocobalt Corroles
Old Dog, New Tricks: Innocent, Five-coordinate Cyanocobalt Corroles Open
Three mono-CN ligated anionic cobalt A3-triarylcorroles were synthesized and investigated as to their spectroscopic and electrochemical properties in CH2Cl2, pyridine (Py), and dimethyl sulfoxide (DMSO). The newly synthesized corroles prov…
View article: A<sub>3</sub>- and A<sub>2</sub>B-nitrocorroles: synthesis and antiviral activity evaluation against human cytomegalovirus infection
A<sub>3</sub>- and A<sub>2</sub>B-nitrocorroles: synthesis and antiviral activity evaluation against human cytomegalovirus infection Open
We report the 2nd generation of seventeen A2B- and A3-substituted fluoronitrocorroles and the discovery of optimized compounds with a selectivity index of >200 against hCMV.
View article: Gold dipyrrin-bisphenolates: a combined experimental and DFT study of metal–ligand interactions
Gold dipyrrin-bisphenolates: a combined experimental and DFT study of metal–ligand interactions Open
The first gold dipyrrin-bisphenolates have been synthesized. Like their corrole analogues, they exhibit AuIII–L3− ground states, providing rare innocent paradigms for a class of complexes that commonly occur as metalloradicals.
View article: Porous materials applied to biomarker sensing in exhaled breath for monitoring and detecting non-invasive pathologies
Porous materials applied to biomarker sensing in exhaled breath for monitoring and detecting non-invasive pathologies Open
Overview of the use of porous materials for gas sensing to analyze the exhaled breath of patients for disease identification.
View article: Carbazole-based green and blue-BODIPY dyads and triads as donors for bulk heterojunction organic solar cells
Carbazole-based green and blue-BODIPY dyads and triads as donors for bulk heterojunction organic solar cells Open
Two BODIPY derivatives with one (B2) and two (B3) carbazole moieties were synthesized and applied as electron-donor materials in organic photovoltaic cells (OPV), showing an overall PCE of 6.41% and 7.47%, respectively.
View article: A<sub>3</sub>- and A<sub>2</sub>B-fluorocorroles: synthesis, X-ray characterization and antiviral activity evaluation against human cytomegalovirus infection
A<sub>3</sub>- and A<sub>2</sub>B-fluorocorroles: synthesis, X-ray characterization and antiviral activity evaluation against human cytomegalovirus infection Open
New generation of anti hCMV molecules: 29 fluorinated corroles were studied for their antiviral activity evaluation against human cytomegalovirus infection and maximum activity is achieved for A2B-corroles with SI above 400.
View article: CCDC 1554869: Experimental Crystal Structure Determination
CCDC 1554869: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …