Clayton J. Curtis
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View article: Gold Tripyrrindione: Redox Chemistry and Reactivity with Dichloromethane
Gold Tripyrrindione: Redox Chemistry and Reactivity with Dichloromethane Open
The identification of ligands that stabilize Au(III) centers has led to the isolation of complexes for applications in catalysis, gold-based therapeutics, and functional materials. Herein, we report the coordination of gold by tripyrrin-1,…
View article: CCDC 2182028: Experimental Crystal Structure Determination
CCDC 2182028: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2182027: Experimental Crystal Structure Determination
CCDC 2182027: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2182029: Experimental Crystal Structure Determination
CCDC 2182029: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2182030: Experimental Crystal Structure Determination
CCDC 2182030: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Multicenter interactions and ligand field effects in platinum(II) tripyrrindione radicals
Multicenter interactions and ligand field effects in platinum(II) tripyrrindione radicals Open
The tripyrrin-1,14-dione biopyrrin, which shares the scaffold of several naturally occurring heme metabolites, is a redox-active platform for metal coordination. We report the synthesis of square planar platinum(II) tripyrrindiones, in whi…
View article: Ligand-Centered Triplet Diradical Supported by a Binuclear Palladium(II) Dipyrrindione
Ligand-Centered Triplet Diradical Supported by a Binuclear Palladium(II) Dipyrrindione Open
Oligopyrroles form a versatile class of redox-active ligands and electron reservoirs. Although the stabilization of radicals within oligopyrrolic π systems is more common for macrocyclic ligands, bidentate dipyrrindiones are emerging as co…
View article: Stabilization of a Triplet Diradical on a Binuclear palladium(II) Dipyrrindione
Stabilization of a Triplet Diradical on a Binuclear palladium(II) Dipyrrindione Open
Porphyrins and other macrocyclic oligopyrroles form a versatile class of redox-active ligands and electron reservoirs. The stabilization of unpaired electrons within oligopyrrolic π systems adds to the available reactivity pathways and spi…
View article: Stabilization of a Triplet Diradical on a Binuclear palladium(II) Dipyrrindione
Stabilization of a Triplet Diradical on a Binuclear palladium(II) Dipyrrindione Open
Porphyrins and other macrocyclic oligopyrroles form a versatile class of redox-active ligands and electron reservoirs. The stabilization of unpaired electrons within oligopyrrolic π systems adds to the available reactivity pathways and spi…