Conor P. Cullen
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View article: Comprehensive benchmarking and user guide for the characterization of CVD-grown transition metal chalcogenides
Comprehensive benchmarking and user guide for the characterization of CVD-grown transition metal chalcogenides Open
Since the discovery of graphene in 2004, there has been rapid progress in research on two-dimensional (2D) material’s potential applications with significant impact. Efforts to bring 2D materials closer to industrial production, quality as…
View article: Identification of Ubiquitously Present Polymeric Adlayers on 2D Transition Metal Dichalcogenides
Identification of Ubiquitously Present Polymeric Adlayers on 2D Transition Metal Dichalcogenides Open
The interest in 2D materials continues to grow across numerous scientific disciplines as compounds with unique electrical, optical, chemical, and thermal characteristics are being discovered. All these properties are governed by an all-sur…
View article: Synthesis and thermal stability of TMD thin films: A comprehensive XPS and Raman study
Synthesis and thermal stability of TMD thin films: A comprehensive XPS and Raman study Open
Transition metal dichalcogenides (TMDs) have been a core constituent of 2D material research throughout the last decade. Over this time, research focus has progressively shifted from synthesis and fundamental investigations, to exploring t…
View article: Synthesis and thermal stability of TMD thin films: A comprehensive XPS\n and Raman study
Synthesis and thermal stability of TMD thin films: A comprehensive XPS\n and Raman study Open
Transition metal dichalcogenides (TMDs) have been a core constituent of 2D\nmaterial research throughout the last decade. Over this time, research focus\nhas progressively shifted from synthesis and fundamental investigations, to\nexplorin…
View article: Synthesis and characterisation of thin-film platinum disulfide and platinum sulfide
Synthesis and characterisation of thin-film platinum disulfide and platinum sulfide Open
Group-10 transition metal dichalcogenides (TMDs) are rising in prominence within the highly innovative field of 2D materials. While PtS2 has been investigated for potential electronic applications, due to its high charge-carrier mobility a…
View article: Synthesis and characterisation of thin-film platinum disulfide and\n platinum sulfide
Synthesis and characterisation of thin-film platinum disulfide and\n platinum sulfide Open
Group-10 transition metal dichalcogenides (TMDs) are rising in prominence\nwithin the highly innovative field of 2D materials. While PtS2 has been\ninvestigated for potential electronic applications, due to its high\ncharge-carrier mobilit…
View article: Highly Selective Non‐Covalent On‐Chip Functionalization of Layered Materials
Highly Selective Non‐Covalent On‐Chip Functionalization of Layered Materials Open
Non‐covalent functionalization of layered 2D materials is an essential tool to modify and fully harness their optical, electrical, and chemical properties. Herein, a facile method enabling the selective formation of self‐assembled monolaye…
View article: “Only a god can save us:” A Reconstruction and Defense of Durkheim’s Account of Religious Life, with Continual Reference to Heidegger and Kierkegaard
“Only a god can save us:” A Reconstruction and Defense of Durkheim’s Account of Religious Life, with Continual Reference to Heidegger and Kierkegaard Open
What do religions do and how do they do it? In The Elementary Forms of Religious Life, Émile Durkheim claims that religions are “grounded in and express the real” and center upon a set of ritualized practices that enact and embody in a dis…
View article: Large-area growth of MoS<sub>2</sub> at temperatures compatible with integrating back-end-of-line functionality
Large-area growth of MoS<sub>2</sub> at temperatures compatible with integrating back-end-of-line functionality Open
Direct growth of transition metal dichalcogenides over large areas within the back-end-of-line (BEOL) thermal budget limit of silicon integrated circuits is a significant challenge for 3D heterogeneous integration. In this work, we report …
View article: Effect of localized helium ion irradiation on the performance of synthetic monolayer MoS<sub>2</sub> field-effect transistors
Effect of localized helium ion irradiation on the performance of synthetic monolayer MoS<sub>2</sub> field-effect transistors Open
Helium ion irradiation is a known method of tuning the electrical conductivity and charge carrier mobility of novel two-dimensional semiconductors. Here, we report a systematic study of the electrical performance of chemically synthesized …
View article: Synthesis of WTe2 thin films and highly-crystalline nanobelts from pre-deposited reactants
Synthesis of WTe2 thin films and highly-crystalline nanobelts from pre-deposited reactants Open
Tungsten ditelluride is a layered transition metal dichalcogenide (TMD) that has attracted increasing research interest in recent years. WTe2 has demonstrated large non-saturating magnetoresistance, potential for spintronic applications an…
View article: Electronic and structural characterisation of polycrystalline platinum disulfide thin films
Electronic and structural characterisation of polycrystalline platinum disulfide thin films Open
Semiconducting thin-film polycrystalline PtS2 is characterised by atomically resolved scanning tunnelling microscopy and spectroscopy.
View article: Sub-millimeter size high mobility single crystal MoSe<sub>2</sub> monolayers synthesized by NaCl-assisted chemical vapor deposition
Sub-millimeter size high mobility single crystal MoSe<sub>2</sub> monolayers synthesized by NaCl-assisted chemical vapor deposition Open
Sub-millimeter single crystal MoSe2 monolayers with a mobility of 38 cm2 V−1 s−1 and responsivity of 42 mA W−1 were synthesized by NaCl-assisted chemical vapor deposition.
View article: Ontology-Guided Policy Information Extraction for Healthcare Fraud Detection
Ontology-Guided Policy Information Extraction for Healthcare Fraud Detection Open
Financial losses in Medicaid, from Fraud, Waste and Abuse (FWA), in the United States are estimated to be in the tens of billions of dollars each year. This results in escalating costs as well as limiting the funding available to worthy re…
View article: Investigation of growth-induced strain in monolayer MoS2 grown by chemical vapor deposition
Investigation of growth-induced strain in monolayer MoS2 grown by chemical vapor deposition Open
View article: Effects of Annealing Temperature and Ambient on Metal/PtSe<sub>2</sub> Contact Alloy Formation
Effects of Annealing Temperature and Ambient on Metal/PtSe<sub>2</sub> Contact Alloy Formation Open
Forming gas annealing is a common process step used to improve the performance of devices based on transition-metal dichalcogenides (TMDs). Here, the impact of forming gas anneal is investigated for PtSe2-based devices. A range …
View article: Quantum confinement-induced semimetal-to-semiconductor evolution in large-area ultra-thin PtSe2 films grown at 400 °C
Quantum confinement-induced semimetal-to-semiconductor evolution in large-area ultra-thin PtSe2 films grown at 400 °C Open
In this work, we present a comprehensive theoretical and experimental study of quantum confinement in layered platinum diselenide (PtSe 2 ) films as a function of film thickness. Our electrical measurements, in combination with density fun…
View article: PtSe <sub>2</sub> grown directly on polymer foil for use as a robust piezoresistive sensor
PtSe <sub>2</sub> grown directly on polymer foil for use as a robust piezoresistive sensor Open
Robust strain gauges are fabricated by growing PtSe2 layers directly on top of flexible polyimide foils. These PtSe2 layers are grown by low-temperature, thermally-assisted conversion of predeposited Pt layers. Under applied flexure the Pt…
View article: PtSe2 grown directly on polymer foil for use as a robust piezoresistive\n sensor
PtSe2 grown directly on polymer foil for use as a robust piezoresistive\n sensor Open
Robust strain gauges are fabricated by growing PtSe2 layers directly on top\nof flexible polyimide foils. These PtSe2 layers are grown by low-temperature,\nthermally-assisted conversion of predeposited Pt layers. Under applied flexure\nthe…
View article: PtSe2 grown directly on polymer foil for use as a robust piezoresistive sensor
PtSe2 grown directly on polymer foil for use as a robust piezoresistive sensor Open
Robust strain gauges are fabricated by growing PtSe2 layers directly on top of flexible polyimide foils. These PtSe2 layers are grown by low-temperature, thermally-assisted conversion of predeposited Pt layers. Under applied flexure the Pt…
View article: Photoresponsivity enhancement in monolayer MoS2 by rapid O2:Ar plasma treatment
Photoresponsivity enhancement in monolayer MoS2 by rapid O2:Ar plasma treatment Open
We report up to ten-fold enhancement of the photoresponsivity of monolayer molybdenum disulfide (MoS2) by treatment with O2:Ar (1:3) plasma. We characterize the surface of plasma-exposed MoS2 by TEM, Raman, and PL mapping and discuss the r…
View article: Growth of 1T′ MoTe<sub>2</sub> by Thermally Assisted Conversion of Electrodeposited Tellurium Films
Growth of 1T′ MoTe<sub>2</sub> by Thermally Assisted Conversion of Electrodeposited Tellurium Films Open
Molybdenum ditelluride (MoTe2) is a transition metal dichalcogenide (TMD) which has two phases stable under ambient conditions, a semiconducting (2H) and semimetallic (1T′) phase. Despite a host of interesting properties and potential appl…
View article: Neuromorphic MoS2 memtransistors fabricated by localised helium ion beam irradiation
Neuromorphic MoS2 memtransistors fabricated by localised helium ion beam irradiation Open
Two-dimensional layered semiconductors have recently emerged as attractive building blocks for next-generation low-power non-volatile memories. However, challenges remain in the controllable sub-micron fabrication of bipolar resistively sw…
View article: Defect sizing, separation, and substrate effects in ion-irradiated monolayer two-dimensional materials
Defect sizing, separation, and substrate effects in ion-irradiated monolayer two-dimensional materials Open
Precise and scalable defect engineering of 2D nanomaterials is acutely sought-after in contemporary materials science. Here we present defect engineering in monolayer graphene and molybdenum disulfide (MoS$_2$) by irradiation with noble ga…
View article: In Situ Formed Protective Barrier Enabled by Sulfur@Titanium Carbide (MXene) Ink for Achieving High‐Capacity, Long Lifetime Li‐S Batteries
In Situ Formed Protective Barrier Enabled by Sulfur@Titanium Carbide (MXene) Ink for Achieving High‐Capacity, Long Lifetime Li‐S Batteries Open
Sulfur (S) is an attractive cathode material with advantages including high theoretical capacity and low cost. However, issues such as the lithium polysulfide shuttle effect and its insulating properties greatly limit the future applicatio…
View article: Oxide-mediated recovery of field-effect mobility in plasma-treated MoS <sub>2</sub>
Oxide-mediated recovery of field-effect mobility in plasma-treated MoS <sub>2</sub> Open
Time-controlled plasma treatment of MoS 2 FETs improves carrier transport due to the presence of a two-dimensional oxide phase.
View article: Rhenium-doped MoS2 films
Rhenium-doped MoS2 films Open
Tailoring the electrical properties of transition metal dichalcogenides by doping is one of the biggest challenges for the application of 2D materials in future electronic devices. Here, we report on a straightforward approach to the n-typ…
View article: Controlling Defect and Dopant Concentrations in Graphene by Remote Plasma Treatments
Controlling Defect and Dopant Concentrations in Graphene by Remote Plasma Treatments Open
This report details the controllable doping of graphene through post‐growth plasma treatments. Defects are controllably introduced into the lattice using argon plasma, following this sample are exposed to ammonia/hydrogen plasma. During th…
View article: High-Performance Hybrid Electronic Devices from Layered PtSe<sub>2</sub>Films Grown at Low Temperature
High-Performance Hybrid Electronic Devices from Layered PtSe<sub>2</sub>Films Grown at Low Temperature Open
Layered two-dimensional (2D) materials display great potential for a range of applications, particularly in electronics. We report the large-scale synthesis of thin films of platinum diselenide (PtSe2), a thus far scarcely inves…