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View article: Unveiling the Reactivity of Li<sub>1+<i>x</i></sub>Al<sub><i>x</i></sub>Ti<sub>2–<i>x</i></sub>(PO<sub>4</sub>)<sub>3</sub> with Lithium Salts to Reduce Its Sintering Temperature
Unveiling the Reactivity of Li<sub>1+<i>x</i></sub>Al<sub><i>x</i></sub>Ti<sub>2–<i>x</i></sub>(PO<sub>4</sub>)<sub>3</sub> with Lithium Salts to Reduce Its Sintering Temperature Open
International audience
View article: Transforming Nanocrystals into Superhard Boron Carbide Nanostructures
Transforming Nanocrystals into Superhard Boron Carbide Nanostructures Open
Boron carbide (B4+δC) possesses a large potential as a structural material owing to its lightness, refractory character, and outstanding mechanical properties. However, its large-scale industrialization is set back by its tenden…
View article: Greener solvents for the processing of preceramic polycarbosilane: application in the preparation of B <sub>4</sub> C/SiC composites
Greener solvents for the processing of preceramic polycarbosilane: application in the preparation of B <sub>4</sub> C/SiC composites Open
Greener solvents for ceramic precursors leading to hybrid materials for high-performance applications.
View article: CSD 2073127: Experimental Crystal Structure Determination
CSD 2073127: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: Molten Salts‐Driven Discovery of a Polar Mixed‐Anion 3D Framework at the Nanoscale: Zn<sub>4</sub>Si<sub>2</sub>O<sub>7</sub>Cl<sub>2</sub>, Charge Transport and Photoelectrocatalytic Water Splitting
Molten Salts‐Driven Discovery of a Polar Mixed‐Anion 3D Framework at the Nanoscale: Zn<sub>4</sub>Si<sub>2</sub>O<sub>7</sub>Cl<sub>2</sub>, Charge Transport and Photoelectrocatalytic Water Splitting Open
Mixed‐anion compounds widen the chemical space of attainable materials compared to single anionic compounds, but the exploration of their structural diversity is limited by common synthetic paths. Especially, oxychlorides rely mainly on la…
View article: Molten Salts‐Driven Discovery of a Polar Mixed‐Anion 3D Framework at the Nanoscale: Zn<sub>4</sub>Si<sub>2</sub>O<sub>7</sub>Cl<sub>2</sub>, Charge Transport and Photoelectrocatalytic Water Splitting
Molten Salts‐Driven Discovery of a Polar Mixed‐Anion 3D Framework at the Nanoscale: Zn<sub>4</sub>Si<sub>2</sub>O<sub>7</sub>Cl<sub>2</sub>, Charge Transport and Photoelectrocatalytic Water Splitting Open
Mixed‐anion compounds widen the chemical space of attainable materials compared to single anionic compounds, but the exploration of their structural diversity is limited by common synthetic paths. Especially, oxychlorides rely mainly on la…
View article: Formation of ZrC–SiC Composites from the Molecular Scale through the Synthesis of Multielement Polymers
Formation of ZrC–SiC Composites from the Molecular Scale through the Synthesis of Multielement Polymers Open
In the field of non-oxide ceramic composites, and by using the polymer-derived ceramic route, understanding the relationship between the thermal behaviour of the preceramic polymers and their structure, leading to the mechanisms involved, …
View article: Mechanisms of Structural Reordering During Thermal Transformation of Aluminogermanate Imogolite Nanotubes
Mechanisms of Structural Reordering During Thermal Transformation of Aluminogermanate Imogolite Nanotubes Open
International audience
View article: A straightforward approach to high purity sodium silicide Na<sub>4</sub>Si<sub>4</sub>
A straightforward approach to high purity sodium silicide Na<sub>4</sub>Si<sub>4</sub> Open
The high reactivity of silicon nanoparticles provides a low temperature pathway to sodium silicide, an important inorganic precursor to silicon-based materials, including clathrates.
View article: Topological connection between vesicles and nanotubes in single-component lipid membranes driven by head-tail interactions
Topological connection between vesicles and nanotubes in single-component lipid membranes driven by head-tail interactions Open
View article: Role of initial precursors on the liquid-crystalline phase behavior of synthetic aluminogermanate imogolite nanotubes
Role of initial precursors on the liquid-crystalline phase behavior of synthetic aluminogermanate imogolite nanotubes Open
View article: Enhanced sieving from exfoliated MoS2 membranes via covalent functionalization
Enhanced sieving from exfoliated MoS2 membranes via covalent functionalization Open
View article: Synthesis of Bulk BC8 Silicon Allotrope by Direct Transformation and Reduced-Pressure Chemical Pathways
Synthesis of Bulk BC8 Silicon Allotrope by Direct Transformation and Reduced-Pressure Chemical Pathways Open
Phase-pure samples of a metastable allotrope of silicon, Si-III or BC8, were synthesized by direct elemental transformation at 14 GPa and ∼900 K and also at significantly reduced pressure in the Na-Si system at 9.5 GPa by quenching from hi…
View article: Efficiency of Polyoxometalate-Based Mesoporous Hybrids as Covalently Anchored Catalysts
Efficiency of Polyoxometalate-Based Mesoporous Hybrids as Covalently Anchored Catalysts Open
Polyoxometalate (POM) hybrids have been covalently immobilized through the formation of amide bonds on several types of mesoporous silica. This work allows the comparison of three POM-based mesoporous systems, obtained with three different…