David Pugh
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View article: A Higher-Yielding Route for the Synthesis of Molecular Precursors to Thin Films of Gold by Atomic Layer Deposition
A Higher-Yielding Route for the Synthesis of Molecular Precursors to Thin Films of Gold by Atomic Layer Deposition Open
A synthetically straightforward and high-yielding route to the series of complexes [AuMe2(dtc)] (dtc = dithiocarbamate) has been developed using dialkyl-, cyclic-dialkyl-, and diaryldithiocarbamate ligands. These compounds were screened by…
Addition of the Vulcanisation Accelerator Di(pentamethylene) thiuram Tetrasulfide (PMTT) to Low and High Valent Molybdenum Centres Open
The reactivity of di(pentamethylene) thiuram tetrasulfide (PMTT) towards both low and high valent molybdenum centres has been investigated to compare with the well‐studied reactivity of thiuram disulfides (TDS) and to generate potential ne…
Graph neural networks with configuration cross-attention for tensor compilers Open
With the recent popularity of neural networks comes the need for efficient serving of inference workloads. A neural network inference workload can be represented as a computational graph with nodes as operators transforming multidimensiona…
A revised understanding of the speciation of gold(<span>iii</span>) dithiocarbamate complexes in solution Open
Contrary to the established orthodoxy, “pure” Au( iii ) dithiocarbamates actually exist as a solution-phase equilibrium with an ion pair.
Addressing misconceptions in dithiocarbamate chemistry Open
Dithiocarbamates are monoanionic chelating ligands that find widespread use in agriculture, medicine, materials science and coordination chemistry. In this perspective we address some common misconceptions that have crept into the literatu…
Fineweb-Edu-Ar: Machine-translated Corpus to Support Arabic Small Language Models Open
As large language models (LLMs) grow and develop, so do their data demands. This is especially true for multilingual LLMs, where the scarcity of high-quality and readily available data online has led to a multitude of synthetic dataset gen…
Graph neural networks with configuration cross-attention for tensor compilers Open
With the recent popularity of neural networks comes the need for efficient serving of inference workloads. A neural network inference workload can be represented as a computational graph with nodes as operators transforming multidimensiona…
A chemically induced, room temperature, single source precursor to CuS (covellite) nanomaterials: synthesis and reactivity of [Cu(S<sub>2</sub>CNHBz)]<sub><i>n</i></sub> Open
In situ generated [Cu(S 2 CNHBz) 2 ] undergoes rapid intramolecular electron-transfer to afford the Cu( i ) complex [Cu(S 2 CNHBz)] n which undergoes base-induced room temperature decomposition to afford CuS (covellite) nanomaterials.
View article: Evolving better solvate electrolytes for lithium secondary batteries
Evolving better solvate electrolytes for lithium secondary batteries Open
Electrolytes are a key component of lithium batteries with significant potential for improvement. Here we present strategies to navigate the large chemical space of electrolytes by combining the strengths of theoretical and experimental ap…
View article: CCDC 2175905: Experimental Crystal Structure Determination
CCDC 2175905: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2175902: Experimental Crystal Structure Determination
CCDC 2175902: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2175904: Experimental Crystal Structure Determination
CCDC 2175904: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2175906: Experimental Crystal Structure Determination
CCDC 2175906: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2175903: Experimental Crystal Structure Determination
CCDC 2175903: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2247759: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2247758: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2247762: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2247757: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2247811: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2247813: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2247760: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2247763: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2247812: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2247756: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2247764: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2247766: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2247810: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2247765: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2247809: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2247808: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …