T. Daniel P. Stack
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View article: Experiences of Autistic Students in Postsecondary Education: A Review of Reviews
Experiences of Autistic Students in Postsecondary Education: A Review of Reviews Open
We summarize key findings from the current literature and make relevant recommendations to move the research on autism in postsecondary forward.
View article: Imidazolate‐Stabilized Cu(III): Dioxygen to Oxides at Type 3 Copper Sites
Imidazolate‐Stabilized Cu(III): Dioxygen to Oxides at Type 3 Copper Sites Open
Imidazole ligation of metals through histidine is extensive among metalloproteins, yet the role of the imidazol ate conjugate base is often neglected, despite its potential accessibility when bonded to an oxidized metal center. Using synth…
View article: Exclusive imidazole ligation to CuIII2O<sub>2</sub> and Cu<sup>III</sup>CuII2O<sub>2</sub> cores
Exclusive imidazole ligation to CuIII2O<sub>2</sub> and Cu<sup>III</sup>CuII2O<sub>2</sub> cores Open
Direct oxygenation of imidazole-ligated Cu(i) generates dinuclear and trinuclear Cu(iii) species with exclusive imidazole ligation.
View article: CCDC 1563639: Experimental Crystal Structure Determination
CCDC 1563639: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Simplest Monodentate Imidazole Stabilization of the oxy‐Tyrosinase Cu<sub>2</sub>O<sub>2</sub> Core: Phenolate Hydroxylation through a Cu<sup>III</sup> Intermediate
Simplest Monodentate Imidazole Stabilization of the oxy‐Tyrosinase Cu<sub>2</sub>O<sub>2</sub> Core: Phenolate Hydroxylation through a Cu<sup>III</sup> Intermediate Open
Tyrosinases are ubiquitous binuclear copper enzymes that oxygenate to Cu II 2 O 2 cores bonded by three histidine Nτ‐imidazoles per Cu center. Synthetic monodentate imidazole‐bonded Cu II 2 O 2 species self‐assemble in a near quantitative …
View article: Simplest Monodentate Imidazole Stabilization of the oxy‐Tyrosinase Cu<sub>2</sub>O<sub>2</sub> Core: Phenolate Hydroxylation through a Cu<sup>III</sup> Intermediate
Simplest Monodentate Imidazole Stabilization of the oxy‐Tyrosinase Cu<sub>2</sub>O<sub>2</sub> Core: Phenolate Hydroxylation through a Cu<sup>III</sup> Intermediate Open
Tyrosinases are ubiquitous binuclear copper enzymes that oxygenate to Cu II 2 O 2 cores bonded by three histidine Nτ‐imidazoles per Cu center. Synthetic monodentate imidazole‐bonded Cu II 2 O 2 species self‐assemble in a near quantitative …