Damien M. Murphy
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View article: Highly efficient benzyl alcohol valorisation <i>via</i> the <i>in situ</i> synthesis of H<sub>2</sub>O<sub>2</sub> and associated reactive oxygen species
Highly efficient benzyl alcohol valorisation <i>via</i> the <i>in situ</i> synthesis of H<sub>2</sub>O<sub>2</sub> and associated reactive oxygen species Open
The selective oxidation of alcohol to the corresponding aldehydes via in situ H 2 O 2 (and associated ROS) production offers an exciting, environmentally friendly alternative to the use of stoichiometric oxidants.
View article: Uncovering the truth about M101, NGC 3938, and their significant others through radiative transfer
Uncovering the truth about M101, NGC 3938, and their significant others through radiative transfer Open
Solving the inverse problem in spiral galaxies, that allows the derivation of the spatial distribution of dust, gas, and stars, together with their associated physical properties, directly from panchromatic imaging observations, is one of …
View article: Benzyl Alcohol Valorization via the In Situ Production of Reactive Oxygen Species
Benzyl Alcohol Valorization via the In Situ Production of Reactive Oxygen Species Open
In this contribution, we outline the efficacy of Pd-based bimetallic catalysts toward the oxidative upgrading of benzyl alcohol via the in situ synthesis of H2O2 (and related reaction intermediates) from the elements. In particular, the fo…
View article: A Continuous-Wave EPR Investigation into the Photochemical Transformations of the Chromium(I) Carbonyl Complex [Cr(CO)4bis(diphenylphosphino)]+ and Reactivity with 1-hexene
A Continuous-Wave EPR Investigation into the Photochemical Transformations of the Chromium(I) Carbonyl Complex [Cr(CO)4bis(diphenylphosphino)]+ and Reactivity with 1-hexene Open
Chromium complexes containing a bis(diphenylphosphino) ligand have attracted significant interest over many years due to their potential as active catalysts for ethylene oligomerisation when combined with suitable co-catalysts such as trie…
View article: Utilizing EPR spectroscopy to investigate the liquid adsorption properties of bimetallic MIL-53(Al/Cr) MOF
Utilizing EPR spectroscopy to investigate the liquid adsorption properties of bimetallic MIL-53(Al/Cr) MOF Open
The flexibility of the MIL-53(M) metal–organic framework (MOF) has been elucidated through EPR spectroscopy, in liquid adsorption processes.
View article: EPR and SQUID interrogations of Cr(III) trimer complexes in the MIL-101(Cr) and bimetallic MIL-100(Al/Cr) MOFs
EPR and SQUID interrogations of Cr(III) trimer complexes in the MIL-101(Cr) and bimetallic MIL-100(Al/Cr) MOFs Open
Description of the dataset: Data type: Experimental spectroscopic measurements, computer simulation and analysis Files are with filename extensions: DSC, DAT, m
View article: Unveiling the atomistic and electronic structure of NiII–NO adduct in a MOF-based catalyst by EPR spectroscopy and quantum chemical modelling
Unveiling the atomistic and electronic structure of NiII–NO adduct in a MOF-based catalyst by EPR spectroscopy and quantum chemical modelling Open
Description of the dataset: Data type: Experimental spectroscopic measurements, computer simulation and analysis Files are with filename extensions: DSC, DAT, m
View article: Unveiling the atomistic and electronic structure of NiII–NO adduct in a MOF-based catalyst by EPR spectroscopy and quantum chemical modelling
Unveiling the atomistic and electronic structure of NiII–NO adduct in a MOF-based catalyst by EPR spectroscopy and quantum chemical modelling Open
Description of the dataset: Data type: Experimental spectroscopic measurements, computer simulation and analysis Files are with filename extensions: DSC, DAT, m
View article: EPR and SQUID interrogations of Cr(III) trimer complexes in the MIL-101(Cr) and bimetallic MIL-100(Al/Cr) MOFs
EPR and SQUID interrogations of Cr(III) trimer complexes in the MIL-101(Cr) and bimetallic MIL-100(Al/Cr) MOFs Open
Description of the dataset: Data type: Experimental spectroscopic measurements, computer simulation and analysis Files are with filename extensions: DSC, DAT, m
View article: EPR and SQUID interrogations of Cr(III) trimer complexes in the MIL-101(Cr) and bimetallic MIL-100(Al/Cr) MOFs
EPR and SQUID interrogations of Cr(III) trimer complexes in the MIL-101(Cr) and bimetallic MIL-100(Al/Cr) MOFs Open
Herein, electron paramagnetic resonance (EPR) spectroscopy at X- (9.4 GHz), Q- (34 GHz) and W-band (95 GHz), and superconducting quantum interference device (SQUID) measurements on antiferromagnetically coupled metal trimers in MIL-101(Cr)…
View article: Magnetic coupling of divalent metal centers in postsynthetic metal exchanged bimetallic DUT-49 MOFs by EPR spectroscopy
Magnetic coupling of divalent metal centers in postsynthetic metal exchanged bimetallic DUT-49 MOFs by EPR spectroscopy Open
Data type: Experimental spectroscopic measurements, computer simulation and analysis Files are with filename extensions: DSC, DAT, m, txt Information on <…
View article: Magnetic coupling of divalent metal centers in postsynthetic metal exchanged bimetallic DUT-49 MOFs by EPR spectroscopy
Magnetic coupling of divalent metal centers in postsynthetic metal exchanged bimetallic DUT-49 MOFs by EPR spectroscopy Open
Data type: Experimental spectroscopic measurements, computer simulation and analysis Files are with filename extensions: DSC, DAT, m, txt Information on <…
View article: Report on scipost_202208_00001v1
Report on scipost_202208_00001v1 Open
Herein, electron paramagnetic resonance (EPR) spectroscopy at X-(9.4 GHz), Q-(34 GHz) and W-band (95 GHz), and superconducting quantum interference device (SQUID) measurements on antiferromagnetically coupled metal trimers in MIL-101(Cr) a…
View article: Magnetic coupling of divalent metal centers in postsynthetic metal exchanged bimetallic DUT-49 MOFs by EPR spectroscopy
Magnetic coupling of divalent metal centers in postsynthetic metal exchanged bimetallic DUT-49 MOFs by EPR spectroscopy Open
EPR measurements at X- (9.5 GHz), Q- (34 GHz) and W-band (94 GHz) on paddlewheel (PW) type post-synthetic metal exchanged DUT-49(M,M): M- Zn, Mn, Cu MOFs are here reported (DUT–Dresden University of Technology). Temperature-dependent X-ban…
View article: Unveiling the atomistic and electronic structure of Ni<sup>II</sup>–NO adduct in a MOF-based catalyst by EPR spectroscopy and quantum chemical modelling
Unveiling the atomistic and electronic structure of Ni<sup>II</sup>–NO adduct in a MOF-based catalyst by EPR spectroscopy and quantum chemical modelling Open
The nature of the chemical bonding between NO and open-shell Ni II ions docked in a metal–organic framework is fully characterized by EPR spectroscopy and computational methods.
View article: An in situ study of the thermal decomposition of 2,2′-azobis(2-methylpropionitrile) radical chemistry using a dual-mode EPR resonator
An in situ study of the thermal decomposition of 2,2′-azobis(2-methylpropionitrile) radical chemistry using a dual-mode EPR resonator Open
A custom-built dual-mode EPR resonator was used to study the radical chemistry of AIBN thermal decomposition. This resonator enables both simultaneous in situ heating using microwaves and EPR measurements to be performed. The thermal decom…
View article: An in-situ study of the thermal decomposition of AIBN radical chemistry using a dual mode EPR resonator
An in-situ study of the thermal decomposition of AIBN radical chemistry using a dual mode EPR resonator Open
A custom-built dual mode EPR resonator was used to study the radical chemistry of AIBN thermal decomposition. This resonator enables both simultaneous in situ heating using microwaves and EPR measurements to be performed. The thermal decom…
View article: Monitoring the Substrate‐Induced Spin‐State Distribution in a Cobalt(II)‐Salen Complex by EPR and DFT
Monitoring the Substrate‐Induced Spin‐State Distribution in a Cobalt(II)‐Salen Complex by EPR and DFT Open
Ground state changes of (R,R ’ )‐N,N ’ ‐bis(3,5‐di‐tert‐butylsalicylidene)‐1,2‐cyclohexane‐diamino Co(II), following coordination of various pyridyl substrate has been examined by CW EPR, pulsed relaxation measurements and DFT. The solutio…
View article: Design Considerations of a Dual Mode X-Band EPR Resonator for Rapid In-Situ Microwave Heating
Design Considerations of a Dual Mode X-Band EPR Resonator for Rapid In-Situ Microwave Heating Open
This paper describes the design considerations for a dual mode X-band continuous wave (CW) Electron Paramagnetic Resonance (EPR) cavity, for simultaneous EPR measurement and microwave heating of the same sample. An elliptical cavity geomet…
View article: CCDC 2083188: Experimental Crystal Structure Determination
CCDC 2083188: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2083185: Experimental Crystal Structure Determination
CCDC 2083185: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2083189: Experimental Crystal Structure Determination
CCDC 2083189: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2083186: Experimental Crystal Structure Determination
CCDC 2083186: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2083187: Experimental Crystal Structure Determination
CCDC 2083187: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: The influence of solvent composition on the coordination environment of the Co/Mn/Br based <i>para</i>-xylene oxidation catalyst as revealed by EPR and ESEEM spectroscopy
The influence of solvent composition on the coordination environment of the Co/Mn/Br based <i>para</i>-xylene oxidation catalyst as revealed by EPR and ESEEM spectroscopy Open
The industrially important para -xylene oxidation reaction, based on a Co/Mn/Br catalyst, operates in a water/acetic acid (H 2 O/AcOH) solvent system.
View article: Front Cover Picture: <i>peri</i>‐Xanthenoxanthene (PXX): a Versatile Organic Photocatalyst in Organic Synthesis (Adv. Synth. Catal. 20/2021)
Front Cover Picture: <i>peri</i>‐Xanthenoxanthene (PXX): a Versatile Organic Photocatalyst in Organic Synthesis (Adv. Synth. Catal. 20/2021) Open
The front cover picture illustrates the photophysical and practical properties of PXX (peri-xanthenoxanthene) as novel photocatalyst. A synthetic experiment is portrayed as a video game where you need to choose the right components to star…
View article: <i>peri</i>‐Xanthenoxanthene (PXX): a Versatile Organic Photocatalyst in Organic Synthesis
<i>peri</i>‐Xanthenoxanthene (PXX): a Versatile Organic Photocatalyst in Organic Synthesis Open
Recent years have witnessed a continuous development of photocatalysts to satisfy the growing demand of photophysical and redox properties in photoredox catalysis, with complex structures or alternative strategies devised to access highly …
View article: Enhanced Selective Oxidation of Benzyl Alcohol via <i>In Situ</i> H<sub>2</sub>O<sub>2</sub> Production over Supported Pd-Based Catalysts
Enhanced Selective Oxidation of Benzyl Alcohol via <i>In Situ</i> H<sub>2</sub>O<sub>2</sub> Production over Supported Pd-Based Catalysts Open
Bimetallic Pd-Fe catalysts supported on TiO2 are shown to be highly effective toward the selective oxidation of benzyl alcohol to benzaldehyde via the in situ production of H2O2 from molecular H2 and O2, under conditions where no reaction …
View article: An EPR investigation of defect structure and electron transfer mechanism in mixed-conductive LiBO<sub>2</sub>–V<sub>2</sub>O<sub>5</sub>glasses
An EPR investigation of defect structure and electron transfer mechanism in mixed-conductive LiBO<sub>2</sub>–V<sub>2</sub>O<sub>5</sub>glasses Open
A series of LiBO2–V2O5glasses of varying contents were investigated using Electron Paramagnetic Resonance (EPR) spectroscopy. This approach provides a convenient method to rationalise the defect structure a…
View article: Ambient base-free glycerol oxidation over bimetallic PdFe/SiO2 by in situ generated active oxygen species
Ambient base-free glycerol oxidation over bimetallic PdFe/SiO2 by in situ generated active oxygen species Open
Low temperature oxidation of alcohols over heterogeneous catalysts is exceptionally challenging, particularly under neutral conditions. Herein, we report on an efficient, base-free method to oxidise glycerol over a 0.5%Pd-0.5%Fe/SiO 2 cata…