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View article: Boron Radical Promoted Metal-Free Transformation of Nitroazobenzene into Benzotriazole
Boron Radical Promoted Metal-Free Transformation of Nitroazobenzene into Benzotriazole Open
Although the triazole skeleton is significant in biochemistry as a click reaction candidate, as well as in material chemistry due to its excellent absorption of UV light, the preparation of these compounds relies on multinitrogen reagents …
View article: Gut microbiota dynamics in SAMP8 mice: insights from machine learning and longitudinal analysis
Gut microbiota dynamics in SAMP8 mice: insights from machine learning and longitudinal analysis Open
The gut microbiota plays a crucial role in maintaining host health, and its composition is significantly influenced by aging. The SAMP8 mouse model, known for its accelerated aging process, is widely used to study age-related changes. Howe…
View article: Red Phosphorescence at Elevated Temperatures Enabled by Dexter Energy Transfer in Polyaromatic Hydrocarbon‐Xanthone Systems
Red Phosphorescence at Elevated Temperatures Enabled by Dexter Energy Transfer in Polyaromatic Hydrocarbon‐Xanthone Systems Open
Organic materials with red persistent phosphorescence hold immense promise for biotechnology due to their excellent tissue permeability and high signal‐to‐background ratios. However, inefficient spin‐orbit coupling, high triplet susceptibi…
View article: A Scoping Review of Research on the Current Status of Graduate Students' English Academic Thesis Writing
A Scoping Review of Research on the Current Status of Graduate Students' English Academic Thesis Writing Open
In recent years, English academic writing has received wide attention in the field of English teaching in recent years. It is found that the English academic writing ability of Chinese university students is generally low. More than 80% of…
View article: Integrative multiomics analysis reveals association of gut microbiota and its metabolites with susceptibility to keloids
Integrative multiomics analysis reveals association of gut microbiota and its metabolites with susceptibility to keloids Open
Keloid scarring is a fibroproliferative disease of the skin, which can significantly impact one’s quality of life through cosmetic concerns, physical discomfort (itchy; painful), restricted movement, and psychological distress. Owing to th…
View article: Unveiling superior phenol detoxification and degradation ability in Candida tropicalis SHC-03: a comparative study with Saccharomyces cerevisiae BY4742
Unveiling superior phenol detoxification and degradation ability in Candida tropicalis SHC-03: a comparative study with Saccharomyces cerevisiae BY4742 Open
This study examined the phenol degradation capabilities and oxidative stress responses of Candida tropicalis SHC-03, demonstrating its metabolic superiority and resilience compared to Saccharomyces cerevisiae BY4742 in a culture medium wit…
View article: Efficient intersystem crossing and tunable ultralong organic room-temperature phosphorescence via doping polyvinylpyrrolidone with polyaromatic hydrocarbons
Efficient intersystem crossing and tunable ultralong organic room-temperature phosphorescence via doping polyvinylpyrrolidone with polyaromatic hydrocarbons Open
Polymer-based pure organic room-temperature phosphorescent materials have tremendous advantages in applications owing to their low cost, vast resources, and easy processability. However, designing polymer-based room-temperature phosphoresc…
View article: Clinical manifestations and long-term symptoms associated with SARS-CoV-2 omicron infection in children aged 0–17 years in Beijing: a single-center study
Clinical manifestations and long-term symptoms associated with SARS-CoV-2 omicron infection in children aged 0–17 years in Beijing: a single-center study Open
Objective The study aims to analyze the clinical characteristics of acute phase of SARS-CoV-2 infection in children aged 0–17 years with the Omicron variant, and summarize the persistent symptoms or new-onset clinical manifestations from 4…
View article: Anion‐Counterion Strategy toward Organic Cocrystal Engineering for Near‐Infrared Photothermal Conversion and Solar‐Driven Water Evaporation
Anion‐Counterion Strategy toward Organic Cocrystal Engineering for Near‐Infrared Photothermal Conversion and Solar‐Driven Water Evaporation Open
An anion‐counterion strategy is proposed to construct organic mono‐radical charge‐transfer cocrystals for near‐infrared photothermal conversion and solar‐driven water evaporation. Ionic compounds with halogen anions as the counterions serv…
View article: Anion‐Counterion Strategy toward Organic Cocrystal Engineering for Near‐Infrared Photothermal Conversion and Solar‐Driven Water Evaporation
Anion‐Counterion Strategy toward Organic Cocrystal Engineering for Near‐Infrared Photothermal Conversion and Solar‐Driven Water Evaporation Open
An anion‐counterion strategy is proposed to construct organic mono‐radical charge‐transfer cocrystals for near‐infrared photothermal conversion and solar‐driven water evaporation. Ionic compounds with halogen anions as the counterions serv…
View article: Dual-rotor strategy for organic cocrystals with enhanced near-infrared photothermal conversion
Dual-rotor strategy for organic cocrystals with enhanced near-infrared photothermal conversion Open
A single-/double-bond dual-rotor strategy is proposed to construct D–A cocrystals with enhanced NIR photothermal conversion, which can be attributed to the nonradiative decays of excited states induced by the free rotation of dual-rotors.
View article: Response mechanisms of Candida tropicalis incubated with a dilute acid hydrolysate from corn stover
Response mechanisms of Candida tropicalis incubated with a dilute acid hydrolysate from corn stover Open
Understanding the cellular response mechanisms of Candida tropicalis is crucial to biofuel production from corn stover, and targeted genetic modification of a C. tropicalis fermentation strain can improve the biofuel yield. In this report,…
View article: CCDC 2217682: Experimental Crystal Structure Determination
CCDC 2217682: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2217681: Experimental Crystal Structure Determination
CCDC 2217681: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Pediatric population (aged 3-11 years) received primary inactivated SARS-CoV-2 vaccination prior to infection exhibiting robust humoral immune response following infected with Omicron variant: a study conducted in Beijing
Pediatric population (aged 3-11 years) received primary inactivated SARS-CoV-2 vaccination prior to infection exhibiting robust humoral immune response following infected with Omicron variant: a study conducted in Beijing Open
Objective Analysis of SARS-CoV-2 IgG antibody and neutralizing antibody levels following SARS-CoV-2 infection in children aged 3-11 years, comparing those who had received the inactivated SARS-CoV-2 vaccine to those who were unvaccinated p…
View article: CCDC 2213522: Experimental Crystal Structure Determination
CCDC 2213522: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Icosidodecahedral Coordination‐Saturated Cuprofullerene
Icosidodecahedral Coordination‐Saturated Cuprofullerene Open
The first coordination‐saturated buckyball with a C 60 molecule totally encased in an icosidodecahedral Cu 30 in a (μ 30 ‐(η 2 ) 30 )‐fashion, namely C 60 @Cu 30 @Cl 36 N 12 , has been successfully realized by a C 60 ‐templated assembly. T…
View article: Remote Selective C−H Halogenation of Arylphosphine Oxides with Ferric Halides
Remote Selective C−H Halogenation of Arylphosphine Oxides with Ferric Halides Open
We developed the remote selective C−H bromination for the synthesis of C4′‐brominated biarylphosphine oxides using FeBr 3 as a brominating reagent. C3′‐Brominated products were obtained in reactions with substrates bearing a 2,4,6‐triisopr…
View article: CCDC 2191950: Experimental Crystal Structure Determination
CCDC 2191950: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Mechanochemistry toward Organic “Salt” via Integer‐Charge‐Transfer Cocrystal Strategy for Rapid, Efficient, and Scalable Near‐Infrared Photothermal Conversion
Mechanochemistry toward Organic “Salt” via Integer‐Charge‐Transfer Cocrystal Strategy for Rapid, Efficient, and Scalable Near‐Infrared Photothermal Conversion Open
Invited for this month′s cover is the group of Shun‐Li Chen and Ming‐De Li at the Shantou University. The image shows that one electron can be transferred easily from donor to acceptor unit to obtain integer‐charge‐transfer cocrystals for …
View article: Front Cover: Mechanochemistry toward Organic “Salt” via Integer‐Charge‐Transfer Cocrystal Strategy for Rapid, Efficient, and Scalable Near‐Infrared Photothermal Conversion (ChemSusChem 14/2023)
Front Cover: Mechanochemistry toward Organic “Salt” via Integer‐Charge‐Transfer Cocrystal Strategy for Rapid, Efficient, and Scalable Near‐Infrared Photothermal Conversion (ChemSusChem 14/2023) Open
The Front Cover shows integer-charge-transfer cocrystals are self-assembled via multiple intermolecular hydrogen bonds with one electron transferred from donor to acceptor unit for high-efficiency (∼87 %) NIR photothermal conversion. “D-A …
View article: Symmetry‐Driven Assembly of a Penta‐Shell Keplerate Cuprofullerene for Metallofullerene Frameworks
Symmetry‐Driven Assembly of a Penta‐Shell Keplerate Cuprofullerene for Metallofullerene Frameworks Open
Two metallofullerene frameworks (MFFs) constructed from a penta‐shell Keplerate cuprofullerene chloride, C 60 @Cu 24 @Cl 44 @Cu 12 @Cl 12 , have been successfully prepared via a C 60 ‐templated symmetry‐driven strategy. The icosahedral cup…
View article: 16S rRNA gene sequencing reveals the correlation between the gut microbiota and the susceptibility to pathological scars
16S rRNA gene sequencing reveals the correlation between the gut microbiota and the susceptibility to pathological scars Open
The gut microbiome profile in patients with pathological scars remains rarely known, especially those patients who are susceptible to pathological scars. Previous studies demonstrated that gut microbial dysbiosis can promote the developmen…
View article: Boosting Ultrafast <i>Trans‐Cis</i> Photoisomerization and Intersystem Crossing in Nanocrystals of Double‐Bond Photoswitching Molecules
Boosting Ultrafast <i>Trans‐Cis</i> Photoisomerization and Intersystem Crossing in Nanocrystals of Double‐Bond Photoswitching Molecules Open
Double‐bond photoswitching molecules typically can undergo trans → cis photoisomerization, but their photoisomerization mechanisms in the solid state have been rarely reported. Herein, the excited‐state evolutions of trans‐ azobenzene (AB)…
View article: Back Cover: Chiral Iron Porphyrins Catalyze Enantioselective Intramolecular C(sp<sup>3</sup>)−H Bond Amination Upon Visible‐Light Irradiation (Angew. Chem. Int. Ed. 19/2023)
Back Cover: Chiral Iron Porphyrins Catalyze Enantioselective Intramolecular C(sp<sup>3</sup>)−H Bond Amination Upon Visible‐Light Irradiation (Angew. Chem. Int. Ed. 19/2023) Open
An efficient method has been developed for the asymmetric intramolecular C(sp3)−H amination of aryl and arylsulfonyl azides to give chiral indolines and benzofused cyclic sulfonamides in high product yields and with excellent enantioselect…
View article: Chiral Iron Porphyrins Catalyze Enantioselective Intramolecular C(sp<sup>3</sup>)−H Bond Amination Upon Visible‐Light Irradiation
Chiral Iron Porphyrins Catalyze Enantioselective Intramolecular C(sp<sup>3</sup>)−H Bond Amination Upon Visible‐Light Irradiation Open
Iron‐catalyzed asymmetric amination of C(sp 3 )−H bonds is appealing for synthetic applications due to the biocompatibility and high earth abundance of iron, but examples of such reactions are sparse. Herein we describe chiral iron complex…
View article: Study on Unloading-wet Swelling Mechanism of Upper Arch Deformation of Mudstone Subgrade in a High-speed Railway
Study on Unloading-wet Swelling Mechanism of Upper Arch Deformation of Mudstone Subgrade in a High-speed Railway Open
Mudstone subgrade may exhibit rather complicated deformation behavior under the coupling effect of unloading and wet swelling caused by subgrade excavation. To study the deformation mechanism of mudstone subgrade, mudstones were sampled fr…