Daniel Grande
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View article: Clinical Status of Exosomes: A Review
Clinical Status of Exosomes: A Review Open
Nano-sized extracellular vesicles enclosed by a lipid bilayer and secreted by various cell types including mesenchymal stem cells, exosomes act as natural transporters, carrying bioactive molecules such as proteins, lipids, and nucleic aci…
View article: Newly Developed Multicomponent Polycondensation Involving Sulfur for the Successful Synthesis of Biobased Polythioureas
Newly Developed Multicomponent Polycondensation Involving Sulfur for the Successful Synthesis of Biobased Polythioureas Open
International audience
View article: Molecular design of cyanate ester resin using amino-POSS and C60 to create high-performance thermostable polycyanurate nanocomposites
Molecular design of cyanate ester resin using amino-POSS and C60 to create high-performance thermostable polycyanurate nanocomposites Open
The kinetics of polycyclotrimerization of cyanate ester resin (CER), viz. dicyanate ester of bisphenol E (DCBE), was studied by DSC method during its molecular design at ultra-low content (0.1 wt%) of two types of nanofillers: reactive ami…
View article: Transition from Steric to Electrostatic Stabilization in Shell-Degradable Waterborne Particles Obtained by Photopolymerization-Induced Self-Assembly
Transition from Steric to Electrostatic Stabilization in Shell-Degradable Waterborne Particles Obtained by Photopolymerization-Induced Self-Assembly Open
International audience
View article: Synthesis and Characterization of Thermosetting Polymers: An Electrospinning Approach
Synthesis and Characterization of Thermosetting Polymers: An Electrospinning Approach Open
This chapter is devoted to the description of the main recent approaches and technical solutions for the creation of polymer micro- and nanofibers engineered by electrospinning precursors of thermosetting polymers. Structure-property relat…
View article: Toward the Development of Graphene/Chitosan Biocomposite Aerogels with Enhanced Mechanical and Thermal Insulation Performance
Toward the Development of Graphene/Chitosan Biocomposite Aerogels with Enhanced Mechanical and Thermal Insulation Performance Open
International audience
View article: Coarsening effects on the liquid permeability in foam-filled porous media
Coarsening effects on the liquid permeability in foam-filled porous media Open
International audience
View article: ACCELERATING EFFECT OF 3-AMINOPROPYLOLIGOMERIC SILSESQUIOXANE ON FORMATION KINETICS OF THERMOSTABLE HYBRID NANOCOMPOSITES BASED ON POLYCYANURATE NETWORK.
ACCELERATING EFFECT OF 3-AMINOPROPYLOLIGOMERIC SILSESQUIOXANE ON FORMATION KINETICS OF THERMOSTABLE HYBRID NANOCOMPOSITES BASED ON POLYCYANURATE NETWORK. Open
In this work, reactive 3-aminopropyloligomeric silsesquioxane (AP-OSS) was synthesized and studied, and the effect of AP-OSS depending on its content (0.1–1.0 wt.%) on the kinetics of polycyclotrimerization of dicyanate ester of bispheno…
View article: Catalytic effect of N-phenylaminopropyl polyheadral oligomeric silsesquioxane in the synthesis of hybrid nanocomposites based on polycyanurate
Catalytic effect of N-phenylaminopropyl polyheadral oligomeric silsesquioxane in the synthesis of hybrid nanocomposites based on polycyanurate Open
Organic-inorganic nanocomposites based on heat-resistant crosslinked polycyanurate (PCN) and N-phenylaminopropyl polyhedral oligomeric silsesquioxane (NPAP-POSS), containing eight reactive secondary amino groups, were synthesized using the…
View article: Thioxanthone-Based Siloxane Photosensitizer for Cationic/Radical Photopolymerization and Photoinduced Sol–Gel Reactions
Thioxanthone-Based Siloxane Photosensitizer for Cationic/Radical Photopolymerization and Photoinduced Sol–Gel Reactions Open
In this investigation, a multifunctional visible-light TX-based photosensitizer containing a siloxane moiety (TXS) was designed with a good overall yield of 54%. The addition of a siloxane moiety enabled the incorporation of a TX photosens…
View article: Antibiotic-loaded gelatin fibers fighting bacteria resistant to antibiotics: a case of spectinomycin-resistant <i>Escherichia coli</i>
Antibiotic-loaded gelatin fibers fighting bacteria resistant to antibiotics: a case of spectinomycin-resistant <i>Escherichia coli</i> Open
We designed gelatin based fibers useable as an antimicrobial material in the prevention and treatment of wound infections, particularly those resistant to antibiotic therapy.
View article: Hybrid aerogels for sustainable construction : Elaboration, characterization and modelling
Hybrid aerogels for sustainable construction : Elaboration, characterization and modelling Open
Afin d'apporter une solution pérenne pour les efforts d'économie d'énergie dans les bâtiments, notamment en ce qui concerne l'isolation thermique et l'impact environnemental limité, les aérogels à base de silice suscitent aujourd'hui un in…
View article: Effect of Amino-Functionalized Polyhedral Oligomeric Silsesquioxanes on Structure-Property Relationships of Thermostable Hybrid Cyanate Ester Resin Based Nanocomposites
Effect of Amino-Functionalized Polyhedral Oligomeric Silsesquioxanes on Structure-Property Relationships of Thermostable Hybrid Cyanate Ester Resin Based Nanocomposites Open
Nanocomposites of cyanate ester resin (CER) filled with three different reactive amino-functionalized polyhedral oligomeric silsesquioxane (POSS) were synthesized and characterized. The addition of a small quantity (0.1 wt.%) of amino-POSS…
View article: Effect of Amino-Functionalized POSS on Structure-Property Relationships of Thermostable Hybrid Cyanate Ester Resin Based Nanocomposites
Effect of Amino-Functionalized POSS on Structure-Property Relationships of Thermostable Hybrid Cyanate Ester Resin Based Nanocomposites Open
Nanocomposites of cyanate ester resin (CER) filled with three different reactive amino-functionalized polyhedral oligomeric silsesquioxane (POSS) were synthesized and characterized. The addition of a small quantity (0.1 wt.%) of amino-POSS…
View article: Diblock and Triblock Copolymers as Nanostructured Precursors to Functional Nanoporous Materials: From Design to Application
Diblock and Triblock Copolymers as Nanostructured Precursors to Functional Nanoporous Materials: From Design to Application Open
Block copolymers have gained tremendous interest from the scientific community in the last two decades. These macromolecular architectures indeed constitute ideal nanostructured precursors for the generation of nanoporous materials meant f…
View article: Fibrochondrogenic Differentiation Potential of Human Adipose-derived Mesenchymal Stem Cells in a Type I Collagen-based Meniscus Scaffold with Activated Platelet-rich Plasma Stimulation in vitro
Fibrochondrogenic Differentiation Potential of Human Adipose-derived Mesenchymal Stem Cells in a Type I Collagen-based Meniscus Scaffold with Activated Platelet-rich Plasma Stimulation in vitro Open
Introduction Despite efforts to use scaffolds to treat meniscus tears, minimal progress has been made in facilitating meniscus regeneration and return of function. Our research objective was to develop a meniscus repair and regeneration im…
View article: SYNTACTIC FOAMS AS COMPOSITE MATERIALS FOR HIGH-TECH INDUSTRIES
SYNTACTIC FOAMS AS COMPOSITE MATERIALS FOR HIGH-TECH INDUSTRIES Open
The present review introduces the analysis and gathering modern ideas about the novel polymer composites, namely polymer syntactic foams, known as extremely widely used multifunctional materials with unique properties that meet the require…
View article: Synthesis of Thioureas, Thioamides, and Aza-Heterocycles via Dimethyl-Sulfoxide-Promoted Oxidative Condensation of Sulfur, Malonic Acids, and Amines
Synthesis of Thioureas, Thioamides, and Aza-Heterocycles via Dimethyl-Sulfoxide-Promoted Oxidative Condensation of Sulfur, Malonic Acids, and Amines Open
Malonic acid and derivatives have been well-known to undergo monodecarboxylation under relatively mild conditions and have been exclusively used as a C2 synthon. We report herein their new application as a C1 synthon via double decarboxyla…
View article: Evaluation of strategies to incorporate silver nanoparticles into electrospun microfibers for the preparation of wound dressings and their antimicrobial activity
Evaluation of strategies to incorporate silver nanoparticles into electrospun microfibers for the preparation of wound dressings and their antimicrobial activity Open
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View article: Liquid relative permeability through foam-filled porous media: Experiments
Liquid relative permeability through foam-filled porous media: Experiments Open
International audience
View article: Thermostable Nanoporous Polycyanurates
Thermostable Nanoporous Polycyanurates Open
The monograph is devoted to the synthesis, analysis of the structure and morphology, porosity parameters and physicochemical properties of heat-resistant nanoporous polycyanurates, as well as the possibility of their application for gas se…
View article: 5-Aminolevulinic Acid Tumor Paint and Photodynamic Therapy for Chordoma: An In Vitro Study
5-Aminolevulinic Acid Tumor Paint and Photodynamic Therapy for Chordoma: An In Vitro Study Open
Wide resections of chordoma tumors are challenging for many reasons, primarily due to a lack of intraoperative visualization, leading to unacceptably high recurrence rates. Known techniques using five-aminolevulinic acid (5-ALA) for tumor …