Daniel Carter Martos
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View article: Diazomethyl-λ <sup>3</sup> -iodane meets aryne: dipolar cycloaddition and C-to-N iodane shift leading to indazolyl-λ <sup>3</sup> -iodanes
Diazomethyl-λ <sup>3</sup> -iodane meets aryne: dipolar cycloaddition and C-to-N iodane shift leading to indazolyl-λ <sup>3</sup> -iodanes Open
Diazomethyl-λ 3 -iodanes act as iodane-bound 1,3-dipoles in reactions with arynes, forming indazolyl-λ 3 -iodanes via [3 + 2] cycloaddition and a 1,3-iodane shift. The resulting indazolyl-λ 3 -iodanes serve as novel oxidative indazole-tran…
View article: Diazomethyl-λ3-iodane Meets Aryne: Dipolar Cycloaddition and C-to-N Iodane Shift Leading to Indazolyl-λ3-iodanes
Diazomethyl-λ3-iodane Meets Aryne: Dipolar Cycloaddition and C-to-N Iodane Shift Leading to Indazolyl-λ3-iodanes Open
Diazomethyl-λ3-iodanes have recently emerged as carbyne equivalents in organic synthesis, enabling the construction of multi-substituted carbon centers through strategic sequential activation of the diazo and iodane functional groups. Dist…
View article: Easy access to polyhalogenated biaryls: regioselective (di)halogenation of hypervalent bromines and chlorines
Easy access to polyhalogenated biaryls: regioselective (di)halogenation of hypervalent bromines and chlorines Open
Polyhalogenated biaryls are unique motifs offering untapped potential as versatile building blocks for the expedient synthesis of complex biaryl compounds.
View article: Stereospecific Conversion of Boronic Esters into Enones using Methoxyallene: Application in the Total Synthesis of 10‐Deoxymethynolide
Stereospecific Conversion of Boronic Esters into Enones using Methoxyallene: Application in the Total Synthesis of 10‐Deoxymethynolide Open
Enones are widely utilized linchpin functional groups in chemical synthesis and molecular biology. We herein report the direct conversion of boronic esters into enones using commercially available methoxyallene as a three‐carbon building b…
View article: Stereospecific Conversion of Boronic Esters into Enones using Methoxyallene: Application in the Total Synthesis of 10‐Deoxymethynolide
Stereospecific Conversion of Boronic Esters into Enones using Methoxyallene: Application in the Total Synthesis of 10‐Deoxymethynolide Open
Enones are widely utilized linchpin functional groups in chemical synthesis and molecular biology. We herein report the direct conversion of boronic esters into enones using commercially available methoxyallene as a three‐carbon building b…