Daniel J. Mindiola
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View article: CCDC 2492498: Experimental Crystal Structure Determination
CCDC 2492498: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Carbon Dioxide Capture and Functionalization from a Molecular Ti(III) Oxo Anion
Carbon Dioxide Capture and Functionalization from a Molecular Ti(III) Oxo Anion Open
Carbon dioxide capture and functionalization sequesters carbon dioxide in more robust products and offers a viable route to reducing greenhouse gas emissions. We present herein a unique molecular Ti III oxo anion that reversibly binds CO 2…
View article: Carbon Dioxide Capture and Functionalization from a Molecular Ti(III) Oxo Anion
Carbon Dioxide Capture and Functionalization from a Molecular Ti(III) Oxo Anion Open
Carbon dioxide capture and functionalization sequesters carbon dioxide in more robust products and offers a viable route to reducing greenhouse gas emissions. We present herein a unique molecular Ti III oxo anion that reversibly binds CO 2…
View article: A titanium redox-switch enables reversible C–C bond forming and splitting reactions
A titanium redox-switch enables reversible C–C bond forming and splitting reactions Open
A dinuclear titanium complex remains in a trivalent valence state, during redox-driven formation and breakage of a C–C σ-bond.
View article: Electronic Structure of <i>trans‐</i>[V<sup>II</sup>Cl<sub>2</sub>(E(CH<sub>3</sub>)<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>E(CH<sub>3</sub>)<sub>2</sub>)<sub>2</sub>], E=N, P
Electronic Structure of <i>trans‐</i>[V<sup>II</sup>Cl<sub>2</sub>(E(CH<sub>3</sub>)<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>E(CH<sub>3</sub>)<sub>2</sub>)<sub>2</sub>], E=N, P Open
Coordination complexes of general formula trans ‐[MX 2 (R 2 ECH 2 CH 2 ER 2 ) 2 ] (M II =Ti, V, Cr, Mn; E=N or P; R=alkyl or aryl) are a cornerstone of coordination and organometallic chemistry. We investigate the electronic properties of …
View article: Divalent Titanium <i>via</i> Reductive N−C Coupling of a Ti<sup>IV</sup> Nitrido with <i>π</i>‐Acids
Divalent Titanium <i>via</i> Reductive N−C Coupling of a Ti<sup>IV</sup> Nitrido with <i>π</i>‐Acids Open
The nitrido‐ate complex [(PN) 2 Ti(N){μ 2 ‐K(OEt 2 )}] 2 ( 1 ) (PN − =(N‐(2‐P i Pr 2 ‐4‐methylphenyl)‐2,4,6‐Me 3 C 6 H 2 ) reductively couples CO and isocyanides in the presence of DME or cryptand (Kryptofix222), to form rare, five‐coordin…
View article: Divalent Titanium <i>via</i> Reductive N−C Coupling of a Ti<sup>IV</sup> Nitrido with <i>π</i>‐Acids
Divalent Titanium <i>via</i> Reductive N−C Coupling of a Ti<sup>IV</sup> Nitrido with <i>π</i>‐Acids Open
The nitrido‐ate complex [(PN) 2 Ti(N){μ 2 ‐K(OEt 2 )}] 2 ( 1 ) (PN − =(N‐(2‐P i Pr 2 ‐4‐methylphenyl)‐2,4,6‐Me 3 C 6 H 2 ) reductively couples CO and isocyanides in the presence of DME or cryptand (Kryptofix222), to form rare, five‐coordin…
View article: Ynamide and Azaalleneyl. Acid‐Base Promoted Chelotropic and Spin‐State Rearrangements in a Versatile Heterocumulene [(Ad)NCC(<sup><i>t</i></sup>Bu)]<sup>−</sup>
Ynamide and Azaalleneyl. Acid‐Base Promoted Chelotropic and Spin‐State Rearrangements in a Versatile Heterocumulene [(Ad)NCC(<sup><i>t</i></sup>Bu)]<sup>−</sup> Open
We introduce the heterocumulene ligand [(Ad)NCC( t Bu)] − (Ad=1‐adamantyl (C 10 H 15 ), t Bu= tert ‐butyl, (C 4 H 9 )), which can adopt two forms, the azaalleneyl and ynamide. This ligand platform can undergo a reversible chelotropic shift…
View article: Ynamide and Azaalleneyl. Acid‐Base Promoted Chelotropic and Spin‐State Rearrangements in a Versatile Heterocumulene [(Ad)NCC(<sup><i>t</i></sup>Bu)]<sup>−</sup>
Ynamide and Azaalleneyl. Acid‐Base Promoted Chelotropic and Spin‐State Rearrangements in a Versatile Heterocumulene [(Ad)NCC(<sup><i>t</i></sup>Bu)]<sup>−</sup> Open
We introduce the heterocumulene ligand [(Ad)NCC( t Bu)] − (Ad=1‐adamantyl (C 10 H 15 ), t Bu= tert ‐butyl, (C 4 H 9 )), which can adopt two forms, the azaalleneyl and ynamide. This ligand platform can undergo a reversible chelotropic shift…
View article: CCDC 2249030: Experimental Crystal Structure Determination
CCDC 2249030: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2249032: Experimental Crystal Structure Determination
CCDC 2249032: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2249031: Experimental Crystal Structure Determination
CCDC 2249031: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: C<sub>sp<sup>2</sup></sub>–H/F bond activation and borylation with iron
C<sub>sp<sup>2</sup></sub>–H/F bond activation and borylation with iron Open
[{K(18-C-6)} 2 ( t Bu pyrr 2 pyr)Fe(N 2 )] splits the C sp 2 –H and C sp 2 –F bond of benzene and fluorobenzene to form [{K(18-C-6)}( t Bu pyrr 2 pyr)Fe(C 6 H 5 )] and reaction with ClBcat yields [K(18-C-6)(thf) 2 ][( t Bu pyrr 2 pyr)FeCl]…
View article: Pnictogen-based vanadacyclobutadiene complexes
Pnictogen-based vanadacyclobutadiene complexes Open
The reactivity of a [V V ] alkylidyne with unsaturated substrates such as NCR (R = Ad or Ph) and PCAd leads to the formation of rare transition metal complexes featuring an α-aza-vanadacyclobutadiene and a β-phospha-vanadacyclobutadiene …
View article: CCDC 2262082: Experimental Crystal Structure Determination
CCDC 2262082: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2262083: Experimental Crystal Structure Determination
CCDC 2262083: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2262073: Experimental Crystal Structure Determination
CCDC 2262073: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2262084: Experimental Crystal Structure Determination
CCDC 2262084: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2262081: Experimental Crystal Structure Determination
CCDC 2262081: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2262074: Experimental Crystal Structure Determination
CCDC 2262074: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2262085: Experimental Crystal Structure Determination
CCDC 2262085: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2262075: Experimental Crystal Structure Determination
CCDC 2262075: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Vanadium Alkylidyne Initiated Cyclic Polymer Synthesis: The importance of a Deprotiovanadacyclobutadiene Moiety.
Vanadium Alkylidyne Initiated Cyclic Polymer Synthesis: The importance of a Deprotiovanadacyclobutadiene Moiety. Open
Reported is the catalytic cyclic polymer synthesis by a 3d transition metal complex: a [VV] alkylidyne, [(dBDI)V≡CtBu(OEt2)] (1−OEt2), supported by the deprotonated β-diketiminate dBDI2− (dBDI2− = ArNC(CH3)CHC(CH2)NAr). Complex 1−OEt2 is a…
View article: CCDC 2262095: Experimental Crystal Structure Determination
CCDC 2262095: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2262094: Experimental Crystal Structure Determination
CCDC 2262094: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2262098: Experimental Crystal Structure Determination
CCDC 2262098: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Iron‐Catalyzed Intermolecular C−H Amination Assisted by an Isolated Iron‐Imido Radical Intermediate
Iron‐Catalyzed Intermolecular C−H Amination Assisted by an Isolated Iron‐Imido Radical Intermediate Open
Here we report the use of a base metal complex [( t Bu pyrpyrr 2 )Fe(OEt 2 )] ( 1 ‐OEt 2 ) ( t Bu pyrpyrr 2 2− =3,5‐ t Bu 2 ‐bis(pyrrolyl)pyridine) as a catalyst for intermolecular amination of C sp3 −H bonds of 9,10‐dihydroanthracene ( 2 …
View article: Iron‐Catalyzed Intermolecular C−H Amination Assisted by an Isolated Iron‐Imido Radical Intermediate
Iron‐Catalyzed Intermolecular C−H Amination Assisted by an Isolated Iron‐Imido Radical Intermediate Open
Here we report the use of a base metal complex [( t Bu pyrpyrr 2 )Fe(OEt 2 )] ( 1 ‐OEt 2 ) ( t Bu pyrpyrr 2 2− =3,5‐ t Bu 2 ‐bis(pyrrolyl)pyridine) as a catalyst for intermolecular amination of C sp3 −H bonds of 9,10‐dihydroanthracene ( 2 …
View article: CCDC 2249020: Experimental Crystal Structure Determination
CCDC 2249020: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2249024: Experimental Crystal Structure Determination
CCDC 2249024: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …