Daniel Strand
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View article: Synthesis of Siphonazole B Through Domino Cycloisomerization‐Oxazolonium Ion Rearrangements
Synthesis of Siphonazole B Through Domino Cycloisomerization‐Oxazolonium Ion Rearrangements Open
4‐Alkenyl‐ and 4‐acyloxazoles represent important substructures across a diverse array of bioactive molecules. Practical methods to synthesize these motifs are, therefore, of considerable interest. Here, we develop a novel domino process w…
View article: An optimised Bcl‐3 inhibitor for melanoma treatment
An optimised Bcl‐3 inhibitor for melanoma treatment Open
Background and Purpose Malignant melanoma is the most lethal form of skin cancer, characterised by a poor survival rate. One of the key factors driving the aggressive growth of melanoma cells is the elevated expression of the proto‐oncogen…
View article: Collective Asymmetric Synthesis of Thiosilvatins
Collective Asymmetric Synthesis of Thiosilvatins Open
Thiosilvatins are a family of biologically active sulfenylated diketopiperazine natural products. The first members were reported over 40 years ago, but total synthesis of a thiosilvatin has remained elusive. Here, we describe the first, c…
View article: Collective Asymmetric Synthesis of Thiosilvatins
Collective Asymmetric Synthesis of Thiosilvatins Open
Thiosilvatins are a family of biologically active sulfenylated diketopiperazine natural products. The first members were reported over 40 years ago, but total synthesis of a thiosilvatin has remained elusive. Here, we describe the first, c…
View article: Correction to “Tailoring the Photophysical Properties of a Homoleptic Iron(II) Tetra <i>N</i>-Heterocyclic Carbene Complex by Attaching an Imidazolium Group to the (C<sup>∧</sup>N<sup>∧</sup>C) Pincer Ligand─A Comparative Study”
Correction to “Tailoring the Photophysical Properties of a Homoleptic Iron(II) Tetra <i>N</i>-Heterocyclic Carbene Complex by Attaching an Imidazolium Group to the (C<sup>∧</sup>N<sup>∧</sup>C) Pincer Ligand─A Comparative Study” Open
ADVERTISEMENT RETURN TO ARTICLES ASAPPREVAddition/CorrectionNEXTORIGINAL ARTICLEThis notice is a correctionCorrection to "Tailoring the Photophysical Properties of a Homoleptic Iron(II) Tetra N-Heterocyclic Carbene Complex by Attaching an …
View article: How Rigidity and Conjugation of Bidentate Ligands Affect the Geometry and Photophysics of Iron <i>N</i>-Heterocyclic Complexes: A Comparative Study
How Rigidity and Conjugation of Bidentate Ligands Affect the Geometry and Photophysics of Iron <i>N</i>-Heterocyclic Complexes: A Comparative Study Open
Two iron complexes featuring the bidentate, nonconjugated N-heterocyclic carbene (NHC) 1,1'-methylenebis(3-methylimidazol-2-ylidene) (mbmi) ligand, where the two NHC moieties are separated by a methylene bridge, have been synthesized to ex…
View article: Tailoring the Photophysical Properties of a Homoleptic Iron(II) Tetra <i>N</i>-Heterocyclic Carbene Complex by Attaching an Imidazolium Group to the (C<sup>∧</sup>N<sup>∧</sup>C) Pincer Ligand─A Comparative Study
Tailoring the Photophysical Properties of a Homoleptic Iron(II) Tetra <i>N</i>-Heterocyclic Carbene Complex by Attaching an Imidazolium Group to the (C<sup>∧</sup>N<sup>∧</sup>C) Pincer Ligand─A Comparative Study Open
We here report the synthesis of the homoleptic iron(II) N-heterocyclic carbene (NHC) complex [Fe(miHpbmi)2](PF6)4 (miHpbmi = 4-((3-methyl-1H-imidazolium-1-yl)pyridine-2,6-diyl)bis(3-methylimidazol-2-ylidene)) and its electrochemical and ph…
View article: 3D Model-Based Large-Volume Metrology Supporting Smart Manufacturing and Digital Twin Concepts
3D Model-Based Large-Volume Metrology Supporting Smart Manufacturing and Digital Twin Concepts Open
New automated laser radar measurement systems at the Saab Inc. West Lafayette, USA, facility will make airframe assembly of the aft body for the new eT7-A aircraft a quicker, more cost-efficient process. Digital twin concepts realized thro…
View article: CCDC 2046062: Experimental Crystal Structure Determination
CCDC 2046062: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2046060: Experimental Crystal Structure Determination
CCDC 2046060: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2046061: Experimental Crystal Structure Determination
CCDC 2046061: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Photophysical Integrity of the Iron(III) Scorpionate Framework in Iron(III)–NHC Complexes with Long-Lived <sup>2</sup>LMCT Excited States
Photophysical Integrity of the Iron(III) Scorpionate Framework in Iron(III)–NHC Complexes with Long-Lived <sup>2</sup>LMCT Excited States Open
Fe(III) complexes with N-heterocyclic carbene (NHC) ligands belong to the rare examples of Earth-abundant transition metal complexes with long-lived luminescent charge-transfer excited states that enable applications as photosensitizers fo…
View article: Trypanocidal and cell swelling activity of 20-deoxysalinomycin
Trypanocidal and cell swelling activity of 20-deoxysalinomycin Open
The naturally occurring polyether ionophore salinomycin was previously found to display promising anti-proliferative activity against bloodstream forms of Trypanosoma brucei. Here, we report the evaluation of 20-deoxysalinomycin, a natural…
View article: Copper(I) Catalyzed Decarboxylative Synthesis of Diareno[<i>a</i>,<i>e</i>]cyclooctatetraenes
Copper(I) Catalyzed Decarboxylative Synthesis of Diareno[<i>a</i>,<i>e</i>]cyclooctatetraenes Open
Diareno[a,e]cyclooctatetraenes find widespread applications as building blocks, ligands, and responsive cores in topologically switchable materials. However, current synthetic methods to these structures suffer from low yields or operation…
View article: CCDC 2145274: Experimental Crystal Structure Determination
CCDC 2145274: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: A C–H Activation Approach to the Tricyclic Core of Glionitrin A and B
A C–H Activation Approach to the Tricyclic Core of Glionitrin A and B Open
Synthesis of diketopiperazines has been of long-standing interest in both natural product synthesis and medicinal chemistry. Here, we present an operationally convenient and efficient approach to the fused indoline-diketopiperazine tricycl…
View article: Flow behavior of thermo-thickening associative polymers in porous media: effects of associative content, salinity, time, velocity, and temperature
Flow behavior of thermo-thickening associative polymers in porous media: effects of associative content, salinity, time, velocity, and temperature Open
Above a critical temperature, thermo-thickening associative polymers (TAPs) have a superior ability to decrease the mobility of the water phase, compared to traditional polymers for enhanced oil recovery. The ability to decrease the mobili…
View article: Electro-mechanically switchable hydrocarbons based on [8]annulenes
Electro-mechanically switchable hydrocarbons based on [8]annulenes Open
Pure hydrocarbons with shape and conjugation properties that can be switched by external stimuli is an intriguing prospect in the design of new responsive materials and single-molecule electronics. Here, we develop an oligomeric [8]annulen…
View article: The long-awaited synthesis and self-assembly of a small rigid <i>C</i><sub>3</sub>-symmetric trilactam
The long-awaited synthesis and self-assembly of a small rigid <i>C</i><sub>3</sub>-symmetric trilactam Open
A C 3 symmetric building block for self-assembly.
View article: Total Synthesis of (−)-Glionitrin A and B Enabled by an Asymmetric Oxidative Sulfenylation of Triketopiperazines
Total Synthesis of (−)-Glionitrin A and B Enabled by an Asymmetric Oxidative Sulfenylation of Triketopiperazines Open
Asymmetric construction of dithiodiketopiperazines on otherwise achiral scaffolds remains a pivotal synthetic challenge encountered in many biologically significant natural products. Herein, we report the first total syntheses of (-)-glion…
View article: Stability of supported aerosol-generated nanoparticles in liquid media
Stability of supported aerosol-generated nanoparticles in liquid media Open
The stability of nanoparticles and their supports are critical, but poorly understood, parameters for applications of such systems in liquid environments. Here we develop an approach to systematically investigate the stability of aerosol-g…
View article: CCDC 1961137: Experimental Crystal Structure Determination
CCDC 1961137: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …