Daniel Wassy
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View article: Evaluating the Polymer Backbone – Vinylene versus Styrene – of Anisyl‐substituted Phenothiazines as Battery Electrode Materials
Evaluating the Polymer Backbone – Vinylene versus Styrene – of Anisyl‐substituted Phenothiazines as Battery Electrode Materials Open
Organic electrode materials are capable candidates for next‐generation greener energy storage solutions. One advantage is that their electrochemical performance can be tuned by structural modification. We herein investigate anisyl‐substitu…
View article: CCDC 2118222: Experimental Crystal Structure Determination
CCDC 2118222: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2043704: Experimental Crystal Structure Determination
CCDC 2043704: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1483358: Experimental Crystal Structure Determination
CCDC 1483358: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Chiral Dibenzopentalene‐Based Conjugated Nanohoops through Stereoselective Synthesis
Chiral Dibenzopentalene‐Based Conjugated Nanohoops through Stereoselective Synthesis Open
Conjugated nanohoops allow to investigate the effect of radial conjugation and bending on the involved π‐systems. They can possess unexpected optoelectronic properties and their radially oriented π‐system makes them attractive for host–gue…
View article: Chiral Dibenzopentalene‐Based Conjugated Nanohoops through Stereoselective Synthesis
Chiral Dibenzopentalene‐Based Conjugated Nanohoops through Stereoselective Synthesis Open
Conjugated nanohoops allow to investigate the effect of radial conjugation and bending on the involved π‐systems. They can possess unexpected optoelectronic properties and their radially oriented π‐system makes them attractive for host–gue…
View article: Cations and Anions of Dibenzo[<i>a</i>,<i>e</i>]pentalene and Reduction of a Dibenzo[<i>a</i>,<i>e</i>]pentalenophane
Cations and Anions of Dibenzo[<i>a</i>,<i>e</i>]pentalene and Reduction of a Dibenzo[<i>a</i>,<i>e</i>]pentalenophane Open
Dibenzo[ a , e ]pentalene (DBP) is a non‐alternant conjugated hydrocarbon with antiaromatic character and ambipolar electrochemical behavior. Upon both reduction and oxidation, it becomes aromatic. We herein study the chemical oxidation an…
View article: Enantiopure nanohoops through racemic resolution of diketo[<i>n</i>]CPPs by chiral derivatization as precursors to DBP[<i>n</i>]CPPs
Enantiopure nanohoops through racemic resolution of diketo[<i>n</i>]CPPs by chiral derivatization as precursors to DBP[<i>n</i>]CPPs Open
Racemic resolution of diketone-embedded cycloparaphenylenes by derivatization with a chiral auxiliary provides scalable access to enantiopure hoops with chiroptical properties.
View article: Thiocoumarin Caged Nucleotides: Synthetic Access and Their Photophysical Properties
Thiocoumarin Caged Nucleotides: Synthetic Access and Their Photophysical Properties Open
Photocages have been successfully applied in cellular signaling studies for the controlled release of metabolites with high spatio-temporal resolution. Commonly, coumarin photocages are activated by UV light and the quantum yields of uncag…
View article: Conjugated Nanohoops Incorporating Donor, Acceptor, Hetero‐ or Polycyclic Aromatics
Conjugated Nanohoops Incorporating Donor, Acceptor, Hetero‐ or Polycyclic Aromatics Open
In the last 13 years several synthetic strategies were developed that provide access to [n]cycloparaphenylenes ([n]CPPs) and related conjugated nanohoops. A number of potential applications emerged, including optoelectronic devices, and th…