Darko P. Ašanin
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View article: Dinuclear Gallium(III) Complex With 1,3‐Propanediamine‐<i>N,N′</i>‐Diacetate: Structural Characterization, Antimicrobial Activity, and DNA/BSA Interactions
Dinuclear Gallium(III) Complex With 1,3‐Propanediamine‐<i>N,N′</i>‐Diacetate: Structural Characterization, Antimicrobial Activity, and DNA/BSA Interactions Open
In this study, a tetradentate 1,3‐propanediamine‐ N,N′- diacetate (1,3‐pdda 2− ) was utilized for the synthesis of a dinuclear gallium(III) complex, uns‐ cis ‐[Ga(1,3‐pdda)( µ ‐OH)] 2 . 2H 2 O ( 1 ). Complex 1 was characterized using IR an…
View article: Copper(II) and Zinc(II) Complexes with Bacterial Prodigiosin Are Targeting Site III of Bovine Serum Albumin and Acting as DNA Minor Groove Binders
Copper(II) and Zinc(II) Complexes with Bacterial Prodigiosin Are Targeting Site III of Bovine Serum Albumin and Acting as DNA Minor Groove Binders Open
The negative environmental and social impacts of food waste accumulation can be mitigated by utilizing bio-refineries’ approach where food waste is revalorized into high-value products, such as prodigiosin (PG), using microbial bioprocesse…
View article: Gallium(III) complexes with 1,3-pdta-type of ligands: The influence of an alkyl substituent in 1,3-propanediamine chain and the metal counter cation on the structural properties of the complex
Gallium(III) complexes with 1,3-pdta-type of ligands: The influence of an alkyl substituent in 1,3-propanediamine chain and the metal counter cation on the structural properties of the complex Open
View article: Modes of Interactions with DNA/HSA Biomolecules and Comparative Cytotoxic Studies of Newly Synthesized Mononuclear Zinc(II) and Heteronuclear Platinum(II)/Zinc(II) Complexes toward Colorectal Cancer Cells
Modes of Interactions with DNA/HSA Biomolecules and Comparative Cytotoxic Studies of Newly Synthesized Mononuclear Zinc(II) and Heteronuclear Platinum(II)/Zinc(II) Complexes toward Colorectal Cancer Cells Open
A series of mono- and heteronuclear platinum(II) and zinc(II) complexes with 4,4′,4″-tri-tert-butyl-2,2′:6′,2″-terpyridine ligand were synthesized and characterized. The DNA and protein binding properties of [ZnCl2(terpytBu)] (C1), [{cis-P…
View article: CCDC 2158468: Experimental Crystal Structure Determination
CCDC 2158468: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2158469: Experimental Crystal Structure Determination
CCDC 2158469: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Kinetic investigation of reactions of a 3-arylidene-2-thiohydantoin derivative with palladium (II) salts
Kinetic investigation of reactions of a 3-arylidene-2-thiohydantoin derivative with palladium (II) salts Open
1H-NMR spectroscopy was used to monitor the reactions of an arylidene 2-thiohydantoin derivative, 3-((phenylmethylene)amino)-2-thioxo-4-imidazolidinone (3), with PdCl2, cis-[PdCl2(dmso-S)2] and K2[PdCl4] in DMSO-d6 in order to elucidate th…
View article: CCDC 2266664: Experimental Crystal Structure Determination
CCDC 2266664: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Comparative study of antimicrobial potential and DNA/BSA binding affinity of silver(I) and gold(III) coordination compounds with 1,6-naphthyridine
Comparative study of antimicrobial potential and DNA/BSA binding affinity of silver(I) and gold(III) coordination compounds with 1,6-naphthyridine Open
View article: Metal complexes with valuable biomolecules produced by <i>Pseudomonas aeruginosa</i>: a review of the coordination properties of pyocyanin, pyochelin and pyoverdines
Metal complexes with valuable biomolecules produced by <i>Pseudomonas aeruginosa</i>: a review of the coordination properties of pyocyanin, pyochelin and pyoverdines Open
A survey of the results achieved in the field of metal complexes with the natural products derived from Pseudomonas aeruginosa , namely pyocyanin, pyochelin, and pyoverdines, has been presented.
View article: Structure and DNA/BSA binding study of zinc(II) complex with 4-ethynyl-2,2’-bipyridine
Structure and DNA/BSA binding study of zinc(II) complex with 4-ethynyl-2,2’-bipyridine Open
In the present study, a zinc(II) complex with 4-ethynyl-2,2?-bipyridine (ebpy), [Zn(ebpy)Cl2], was synthesized and characterized by spectroscopic (1H-NMR, IR and UV?Vis) methods and molar conductivity measurement. The crystal structure of …
View article: Dinuclear silver(I) complexes with phthalazine: DNA/BSA binding and in vivo toxicity study
Dinuclear silver(I) complexes with phthalazine: DNA/BSA binding and in vivo toxicity study Open
The present study reports the synthesis and spectroscopic characterization of dinuclear silver(I) complexes, {[Ag(X-O)(phtz-N)]2(µ-phtz-N,N')2} (X = NO3 - (Ag1) and CF3SO3 - (Ag2), and phtz is phthalazine). The interaction of these two com…
View article: Zinc(II) complex with 4-ethynyl-2,2’-bipyridine: synthesis, characterization and DNA/BSA interactions
Zinc(II) complex with 4-ethynyl-2,2’-bipyridine: synthesis, characterization and DNA/BSA interactions Open
View article: CCDC 2065519: Experimental Crystal Structure Determination
CCDC 2065519: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2065521: Experimental Crystal Structure Determination
CCDC 2065521: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2065520: Experimental Crystal Structure Determination
CCDC 2065520: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2170843: Experimental Crystal Structure Determination
CCDC 2170843: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2170842: Experimental Crystal Structure Determination
CCDC 2170842: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Cobalt(II) and magnesium(II) complexes with 1,3-pdta-type of ligands: influence of an alkyl substituent at 1,3-propanediamine chain on the structural and antimicrobial properties of the complex
Cobalt(II) and magnesium(II) complexes with 1,3-pdta-type of ligands: influence of an alkyl substituent at 1,3-propanediamine chain on the structural and antimicrobial properties of the complex Open
To investigate how modification in the structure of 1,3-propanediamine chain of 1,3-pdta (1,3-propanediamine-N,N,N′,N′-tetraacetate) ligand affects the structural and biological properties of the corresponding metal complexes, two n…
View article: Synthesis of series of different imidazolidine-2,4-dione derivatives and evaluation of their antimicrobial potential
Synthesis of series of different imidazolidine-2,4-dione derivatives and evaluation of their antimicrobial potential Open
A series of twenty two different imidazolidine-2,4-dione derivatives, divided according to their structure into five groups, including alkyl, alkenyl or aryl 5,5disubstituted hydantoins, spirohydantoins, and fused bicyclic and tricyclic hy…
View article: Cobalt(II) and magnesium(II) complexes with 1,3-pdta-type of ligands: influence of an alkyl substituent at 1,3-propanediamine chain on the structural and antimicrobial properties of the complex
Cobalt(II) and magnesium(II) complexes with 1,3-pdta-type of ligands: influence of an alkyl substituent at 1,3-propanediamine chain on the structural and antimicrobial properties of the complex Open
To investigate how modification in the structure of 1,3-propanediamine chain of 1,3-pdta (1,3-propanediamine-N,N,N′,N′-tetraacetate) ligand affects the structural and biological properties of the corresponding metal complexes, two n…
View article: Structural Characterization, Antimicrobial Activity and BSA/DNA Binding Affinity of New Silver(I) Complexes with Thianthrene and 1,8-Naphthyridine
Structural Characterization, Antimicrobial Activity and BSA/DNA Binding Affinity of New Silver(I) Complexes with Thianthrene and 1,8-Naphthyridine Open
Three new silver(I) complexes [Ag(NO3)(tia)(H2O)]n (Ag1), [Ag(CF3SO3)(1,8-naph)]n (Ag2) and [Ag2(1,8-naph)2(H2O)1.2](PF6)2 (Ag3), where tia is thianthrene and 1,8-naph is 1,8-naphthyridine, were synthesized and structurally characterized b…
View article: Influence of electrochemical conditions on the regio- and stereoselectivity of selenocyclization of alkenyl hydantoins
Influence of electrochemical conditions on the regio- and stereoselectivity of selenocyclization of alkenyl hydantoins Open
5-Alkenyl hydantoins and alkenyl spirohydantoins are converted into bicyclic and tricyclic hydantoins, under indirect electrochemical conditions, generating the phenylselenyl cation in situ. The reactions proceeded in good to exelent yield…
View article: Polynuclear Silver(I) Complex with Thianthrene: Structural Characterization, Antimicrobial Activity and Interaction with Biomolecules
Polynuclear Silver(I) Complex with Thianthrene: Structural Characterization, Antimicrobial Activity and Interaction with Biomolecules Open
New silver(I) complex with thianthrene (tia), [Ag(NO3)(tia)(H2O)]n, was synthesized by the reaction of AgNO3 with an equimolar amount of tia in ethanol/dichloromethane (v/v 1:1) at room temperature, and characterized by NMR, IR and UV-Vis …
View article: DNA/BSA binding affinities and &lt;em&gt;in vivo&lt;/em&gt; toxicity of dinuclear silver(I) complexes with phthalazine
DNA/BSA binding affinities and <em>in vivo</em> toxicity of dinuclear silver(I) complexes with phthalazine Open
Silver(I) complexes with aromatic nitrogen-containing heterocycles have shown an effective and wide-spectrum of antimicrobial activity. The possible mechanism of their antimicrobial activity can be attributed to interactions of these compl…
View article: Improvement of antifungal activity and therapeutic profile of fluconazole by its complexation with copper(II) and zinc(II) ions. Complex characterization and antimicrobial activity studies
Improvement of antifungal activity and therapeutic profile of fluconazole by its complexation with copper(II) and zinc(II) ions. Complex characterization and antimicrobial activity studies Open
Over the last few decades, invasive fungal infections represent a serious problem for modern-day healthcare. Aspergillus, Candida and Cryptococcus species are the most common pathogens causing life-threatening infections. Therapeutic optio…
View article: Antimicrobial activity and DNA/BSA binding study of new silver(I) complexes with 1,8-naphthyridine
Antimicrobial activity and DNA/BSA binding study of new silver(I) complexes with 1,8-naphthyridine Open
Silver(I) compounds are well known for their pharmacological applications as antibiotics and have been also evaluated as potential anticancer agents. The use of simple silver(I) salts, such as AgNO3, as an antimicrobial agent, has been lim…
View article: Synthesis and spectroscopic characterization of new solid solution containing Mg(II) and Cu(II) complexes with hexadentate 1,3-propanediaminen, N,N’,N’-tetraacetate (1,3-pdta) ligand: In vitro antifungal activity of 1,3-pdta-Cu(II) complexes
Synthesis and spectroscopic characterization of new solid solution containing Mg(II) and Cu(II) complexes with hexadentate 1,3-propanediaminen, N,N’,N’-tetraacetate (1,3-pdta) ligand: In vitro antifungal activity of 1,3-pdta-Cu(II) complexes Open
New solid solution containing Mg(II) and Cu(II) complexes with hexadentate 1,3-propanediamine-N,N,N?,N?-tetraacetate ligand (1,3-pdta), [Mg(H2O)6] [Mg0.5Cu0.5(1,3-pdta)].2H2O was synthesized and structurally characterized by elemental micr…
View article: <em> </em> Interactions of zinc(II) complexes with<em> N</em>-donor ligands with 5’-GMP and their cytotoxic activity
<em> </em> Interactions of zinc(II) complexes with<em> N</em>-donor ligands with 5’-GMP and their cytotoxic activity Open
Design of novel non-platinum DNA and protein targeting metal-based anticancer agents with potential in vitro toxicity have gained importance in recent years (Bertini, I. et al, Biological Inorganic Chemistry. Structure and Reactivity. Univ…
View article: <strong>Antimicrobial Activity of Various Hydantoin Derivatives </strong>
<strong>Antimicrobial Activity of Various Hydantoin Derivatives </strong> Open
A series of 22 synthetic drug-like hydantoin derivatives, including aryl or alkenyl 5,5-disubstituted hydantoins, spirohydantoins and annulated bicyclic and tricyclic hydantoins, was assayed for in vitro antibacterial and antifungal activi…