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Wavelength dependent photochemistry of an iron dinitrogen hydride complex via multiple spectroscopies - Competing ejection of axial ligands Open

Weibing Dong, Hongxin Wang, Saeed Kamali, David R. Tyler, Yisong Guo , et al. · 2025

Nitrogenase (N2ase) is a critical enzyme which catalyzes the reaction of N2 --> NH3 in nature. Studies on the spectroscopy and photochemistry of trans-[FeII(DMeOPrPE)2(N2)H][BPh4](1) and its isotopomers provide a possible first step to eva…

Wavelength dependent photochemistry of an iron dinitrogen hydride complex <i>via</i> multiple spectroscopies – competing ejection of axial ligands Open

Weibing Dong, Hongxin Wang, Saeed Kamali, David R. Tyler, Yisong Guo , et al. · 2025

For this dinitrogen hydride complex, UV photolyses lead to a competitive ejection between N 2 and H· while visible light photolyses produce N 2 alone. It is the solid first step towards the future studies on nitrogenase–N 2 and its photoly…

Synthesis and crystal structure of sodium (ethane-1,2-diyl)bis[(3-methoxypropyl)phosphinodithiolate] octahydrate Open

Bryan P. Nell, David R. Tyler, Lev N. Zakharov, Dean H. Johnston · 2024

The title compound, catena -poly[[triaquasodium]-di-μ-aqua-[triaquasodium]-μ-(ethane-1,2-diyl)bis[(3-methoxypropyl)phosphinodithiolato]], [Na 2 (C 10 H 22 O 2 P 2 S 4 )(H 2 O) 8 ] n , crystallizes in the triclinic space group P 1 . The dia…

List of contributors Open

Thomas J. Allen, Muhammad Awais, Jeremy N. Bailenson, Mitradip Bhattacharjee, Uzzal Biswas , et al. · 2021

CCDC 1895567: Experimental Crystal Structure Determination Open

Dillon J. Bryant, Lev N. Zakharov, David R. Tyler · 2019

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …

CCDC 1895568: Experimental Crystal Structure Determination Open

Dillon J. Bryant, Lev N. Zakharov, David R. Tyler · 2019

CCDC 1456706: Experimental Crystal Structure Determination Open

Alexander J. Kendall, Lev N. Zakharov, David R. Tyler · 2017

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …

CCDC 1456708: Experimental Crystal Structure Determination Open

Alexander J. Kendall, Lev N. Zakharov, David R. Tyler · 2017

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …

CCDC 1456707: Experimental Crystal Structure Determination Open

Alexander J. Kendall, Lev N. Zakharov, David R. Tyler · 2017

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …

CCDC 1456705: Experimental Crystal Structure Determination Open

Alexander J. Kendall, Lev N. Zakharov, David R. Tyler · 2017

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …

CCDC 1471247: Experimental Crystal Structure Determination Open

Alexander J. Kendall, Lev N. Zakharov, David R. Tyler · 2016

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …

CCDC 1471245: Experimental Crystal Structure Determination Open

Alexander J. Kendall, Lev N. Zakharov, David R. Tyler · 2016

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …

CCDC 1471246: Experimental Crystal Structure Determination Open

Alexander J. Kendall, Lev N. Zakharov, David R. Tyler · 2016

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …

CCDC 1455849: Experimental Crystal Structure Determination Open

Bryan P. Nell, Charles D. Swor, E. Adrian Henle, Lev N. Zakharov, N. Ian Rinehart , et al. · 2016

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …

CCDC 1471243: Experimental Crystal Structure Determination Open

Alexander J. Kendall, Lev N. Zakharov, David R. Tyler · 2016

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …

CCDC 1471244: Experimental Crystal Structure Determination Open

Alexander J. Kendall, Lev N. Zakharov, David R. Tyler · 2016

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …

Crystal structure of<i>trans</i>-dihydridobis[tris(dimethylamino)phosphane-κ<i>P</i>]platinum(II) Open

Emma L. Downs, Lev N. Zakharov, David R. Tyler · 2015

The molecule of the title compound, [PtH 2 (C 6 H 18 N 3 P) 2 ], has a centrosymmetric square-planar structure in which the Pt II atom is bonded to two H and two P atoms in a mutually trans configuration. The Pt II atom sits on an inversio…

CCDC 1038736: Experimental Crystal Structure Determination Open

Bryan P. Nell, Charles D. Swor, Lev N. Zakharov, David R. Tyler · 2015

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …

CCDC 1051841: Experimental Crystal Structure Determination Open

Emma L. Downs, L.N. Zakharov, David R. Tyler · 2015

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …

CCDC 1038735: Experimental Crystal Structure Determination Open

Bryan P. Nell, Charles D. Swor, Lev N. Zakharov, David R. Tyler · 2015

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …

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