Denis Testemale
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View article: Kinetic study of the effect of Mg2+ and Ca2+ on the hydrolysis of ATP up to 120 °C
Kinetic study of the effect of Mg2+ and Ca2+ on the hydrolysis of ATP up to 120 °C Open
View article: The role of hydrogen sulfide and trisulfur radical ion in molybdenum transport by hydrothermal fluids: implications for porphyry-epithermal Cu-Au-Mo deposits
The role of hydrogen sulfide and trisulfur radical ion in molybdenum transport by hydrothermal fluids: implications for porphyry-epithermal Cu-Au-Mo deposits Open
View article: A transparent IHPV for the in-situ geochemical characterization of magmatic volatile phases and melts
A transparent IHPV for the in-situ geochemical characterization of magmatic volatile phases and melts Open
View article: Tungsten solubility and speciation in hydrothermal solutions revealed by in situ X-ray absorption spectroscopy
Tungsten solubility and speciation in hydrothermal solutions revealed by in situ X-ray absorption spectroscopy Open
Tungsten (W) concentrations in fluids in equilibrium with crystalline tungsten oxide are used to determine thermodynamic parameters for W solubility and W species in hydrothermal fluids. The solubility data were measured in situ at high pr…
View article: ‘A Transparent Ihpv for the In-Situ Geochemical Characterization of Magmatic Volatile Phases and Melts ‘
‘A Transparent Ihpv for the In-Situ Geochemical Characterization of Magmatic Volatile Phases and Melts ‘ Open
View article: Quantifying the transfers of metals and sulfur by geological fluids using in-situ spectroscopy
Quantifying the transfers of metals and sulfur by geological fluids using in-situ spectroscopy Open
International audience
View article: First low-temperature synthesis of Cr4+ -doped YAG powders by the Pechini process: unveiling the role of Cr⁶⁺
First low-temperature synthesis of Cr4+ -doped YAG powders by the Pechini process: unveiling the role of Cr⁶⁺ Open
Cr 4+ -doped Y3Al5O12 (YAG:Cr 4+ ) is widely employed in photonic devices as a saturable absorber and has recently attracted attention as an infrared gain medium. However, its synthesis typically requires annealing at high temperature (>13…
View article: Tantalum in hydrothermal fluids
Tantalum in hydrothermal fluids Open
View article: Stable isotopes analysis combined with X-ray absorption spectroscopy reveal the fate of organic waste-borne copper and zinc in amended soils
Stable isotopes analysis combined with X-ray absorption spectroscopy reveal the fate of organic waste-borne copper and zinc in amended soils Open
View article: <i>In situ</i> X-ray absorption spectroscopy using the FAME autoclave: a window into fluid-mineral-melt interactions in the Earth’s crust
<i>In situ</i> X-ray absorption spectroscopy using the FAME autoclave: a window into fluid-mineral-melt interactions in the Earth’s crust Open
International audience
View article: Hydrolysis rate constants of ATP up to 120 °C and 1.6 GPa: Implications for life at extreme conditions
Hydrolysis rate constants of ATP up to 120 °C and 1.6 GPa: Implications for life at extreme conditions Open
View article: Novel high-pressure/high-temperature reactor cell for <i>in situ</i> and <i>operando</i> x-ray absorption spectroscopy studies of heterogeneous catalysts at synchrotron facilities
Novel high-pressure/high-temperature reactor cell for <i>in situ</i> and <i>operando</i> x-ray absorption spectroscopy studies of heterogeneous catalysts at synchrotron facilities Open
This paper presents the development of a novel high-pressure/high-temperature reactor cell dedicated to the characterization of catalysts using synchrotron x-ray absorption spectroscopy under operando conditions. The design of the vitreous…
View article: Nature and coordination geometry of geologically relevant aqueous Uranium(VI) complexes up to 400 ºC: A review and new data
Nature and coordination geometry of geologically relevant aqueous Uranium(VI) complexes up to 400 ºC: A review and new data Open
The structure of the uranyl aqua ion (UO22+) and a number of its inorganic complexes (specifically, UO2Cl+, UO2Cl20, UO2SO40, [Fo…
View article: In-situ monitoring of ATP hydrolysis at high pressure and temperature: exploring the limits of life
In-situ monitoring of ATP hydrolysis at high pressure and temperature: exploring the limits of life Open
View article: Oxygen breath of subduction zones revealed by arsenic in serpentinite
Oxygen breath of subduction zones revealed by arsenic in serpentinite Open
View article: The role of S<sub>3</sub><sup>•-</sup> in molybdenum transport by hydrothermal fluids revealed by in situ X-ray absorption spectroscopy
The role of S<sub>3</sub><sup>•-</sup> in molybdenum transport by hydrothermal fluids revealed by in situ X-ray absorption spectroscopy Open
View article: Characterisation of uranium redox state in organic-rich marine sediments of the Cretaceous Toolebuc Formation, Australia
Characterisation of uranium redox state in organic-rich marine sediments of the Cretaceous Toolebuc Formation, Australia Open
View article: Redox dynamics of subduction revealed by arsenic in serpentinite
Redox dynamics of subduction revealed by arsenic in serpentinite Open
International audience
View article: In situ spectroscopy of hydrothermal fluids: What can we learn with autoclaves and photons?
In situ spectroscopy of hydrothermal fluids: What can we learn with autoclaves and photons? Open
View article: Carbonate complexation enhances hydrothermal transport of rare earth elements in alkaline fluids
Carbonate complexation enhances hydrothermal transport of rare earth elements in alkaline fluids Open
View article: Yttrium speciation in sulfate-rich hydrothermal ore-forming fluids
Yttrium speciation in sulfate-rich hydrothermal ore-forming fluids Open
International audience
View article: Speciation and thermodynamic properties of La(III)-Cl complexes in hydrothermal fluids: A combined molecular dynamics and in situ X-ray absorption spectroscopy study
Speciation and thermodynamic properties of La(III)-Cl complexes in hydrothermal fluids: A combined molecular dynamics and in situ X-ray absorption spectroscopy study Open
International audience
View article: Tin transport in ore fluids - in-situ insight from cassiterite dissolution experiments
Tin transport in ore fluids - in-situ insight from cassiterite dissolution experiments Open
View article: Drastic Ce3+ Insertion Enhancement in YAG Garnet Nanocrystals Through a Solvothermal Route
Drastic Ce3+ Insertion Enhancement in YAG Garnet Nanocrystals Through a Solvothermal Route Open
Y 3 Al 5 O 12 (YAG) nanocrystals have been synthesized by a modified solvothermal method (300°C) allowing the incorporation of cerium ions in much larger proportion (up to 30 mol.% with respect to yttrium ions) than ever published. The rea…
View article: The trisulfur radical ion S <sub>3</sub> <sup>•−</sup> controls platinum transport by hydrothermal fluids
The trisulfur radical ion S <sub>3</sub> <sup>•−</sup> controls platinum transport by hydrothermal fluids Open
Significance Platinum group elements (PGE) are highly valued by many industrial applications, serve as important geochemical tracers of planetary processes, and are among eagerly sought natural resources of critical trace metals. We show h…
View article: Gold speciation in hydrothermal fluids revealed by in situ high energy resolution X-ray absorption spectroscopy
Gold speciation in hydrothermal fluids revealed by in situ high energy resolution X-ray absorption spectroscopy Open
Gold mobilization, transfer, and concentration in the Earth’s crust are controlled by hydrothermal sulfur- and chloride-bearing fluids. Yet the exact chemical identity, structure, and stability of Au-bearing species and, in particular, the…
View article: A hydrothermal apparatus for x-ray absorption spectroscopy of hydrothermal fluids at DESY
A hydrothermal apparatus for x-ray absorption spectroscopy of hydrothermal fluids at DESY Open
We present a new autoclave that enables in situ characterization of hydrothermal fluids at high pressures and high temperatures at synchrotron x-ray radiation sources. The autoclave has been specifically designed to enable x-ray absorption…
View article: An arsenic-driven pump for invisible gold in hydrothermal systems
An arsenic-driven pump for invisible gold in hydrothermal systems Open
International audience
View article: “Critical” trace elements in major minerals: old questions, new approaches and geochemical applications
“Critical” trace elements in major minerals: old questions, new approaches and geochemical applications Open
View article: A synchrotron XAS study of molybdenum speciation in sulfur-bearing hydrothermal fluids
A synchrotron XAS study of molybdenum speciation in sulfur-bearing hydrothermal fluids Open
Knowledge of the identity and thermodynamic properties of aqueous molybdenum (Mo) species at elevated temperatures and pressures is important for understanding the extraction of Mo from source rocks and the formation of hydrothermal deposi…