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View article: Outside Back Cover: Rare Mononuclear Lithium–Carbene Complex for Atomic Layer Deposition of Lithium Containing Thin Films (Angew. Chem. Int. Ed. 47/2025)
Outside Back Cover: Rare Mononuclear Lithium–Carbene Complex for Atomic Layer Deposition of Lithium Containing Thin Films (Angew. Chem. Int. Ed. 47/2025) Open
View article: Rare Mononuclear Lithium–Carbene Complex for Atomic Layer Deposition of Lithium Containing Thin Films
Rare Mononuclear Lithium–Carbene Complex for Atomic Layer Deposition of Lithium Containing Thin Films Open
Lithium is the core material of modern battery technologies and fabricating the lithium‐containing materials with atomic layer deposition (ALD) confers significant benefits in control of film composition and thickness. In this work, a new …
View article: Ein seltener mononuklearer Lithium‐Carben‐Komplex für die Atomlagenabscheidung von lithiumhaltigen Dünnschichten
Ein seltener mononuklearer Lithium‐Carben‐Komplex für die Atomlagenabscheidung von lithiumhaltigen Dünnschichten Open
Kurzfassung Lithium ist das zentrale Element moderner Batterietechnologien, und die Herstellung von lithiumhaltigen Materialien mittels Atomlagenabscheidung (engl. Atomic Layer Deposition, ALD) bietet erhebliche Vorteile bei der Kontrolle …
View article: High Quality Crystalline VN Thin Films via MOCVD from a New Vanadium Precursor: Linking Growth Chemistry to Functional Catalytic Surfaces
High Quality Crystalline VN Thin Films via MOCVD from a New Vanadium Precursor: Linking Growth Chemistry to Functional Catalytic Surfaces Open
Vanadium nitride (VN) has been identified as a promising material for numerous applications including electrochemical nitrogen reduction reaction (eNRR). For such applications, catalyst nanoengineering will help to experimentally test its …
View article: Surface Oxidation of Transition Metal Nitrides
Surface Oxidation of Transition Metal Nitrides Open
The well-known Haber-Bosch process for NH3 production is highly inefficient, with a significant energy demand and CO2 emissions. Alternative approaches, including electrochemical ammonia synthesis from N2 a…
View article: Surface Oxidation of Transition Metal Nitrides
Surface Oxidation of Transition Metal Nitrides Open
The well-known Haber-Bosch process of NH3-production ishighly inefficient, with significant energy demand and high CO2 emissions. Alternative approaches like the electrochemical ammonia synthesis from N2 and H2 are attractive, but the slug…
View article: New measurements of the <sup>63</sup>Cu(<i>α</i>, <i>γ</i>)<sup>67</sup>Ga reaction compared with improved calculations
New measurements of the <sup>63</sup>Cu(<i>α</i>, <i>γ</i>)<sup>67</sup>Ga reaction compared with improved calculations Open
One of the challenges of nuclear astrophysics is understanding the observed abundances of the p-process nuclei. Nucleosynthesis calculations typically employ an extended reaction network involving tens of thousands of reactions and thousan…
View article: Plasma-enhanced atomic layer deposition of AlPO <sub>4</sub> /AlP <sub> <i>x</i> </sub> O <sub> <i>y</i> </sub> : comparing dual source and supercycle approaches for composition control
Plasma-enhanced atomic layer deposition of AlPO <sub>4</sub> /AlP <sub> <i>x</i> </sub> O <sub> <i>y</i> </sub> : comparing dual source and supercycle approaches for composition control Open
Two plasma-enhanced atomic layer deposition (PEALD) pathways for AlP x O y thin films are compared: a dual-source process with a new TMA-phosphine adduct yields P-doped Al 2 O 3 , and a supercycle approach using P(NMe 2 ) 3 and TMA results…
View article: Study of the 2H(3He, p0)4He nuclear reaction for deuterium depth profiling
Study of the 2H(3He, p0)4He nuclear reaction for deuterium depth profiling Open
The differential cross sections of the 2H(3He, p0)4He reaction have been determined at six detection angles (120°, 130°, 140°, 150°, 160° and 170°) in the energy range between 300 and 4000 keV, with steps of 30 to 100 keV. The measurements…
View article: TALYS calculations for α capture reactions on Cu isotopes
TALYS calculations for α capture reactions on Cu isotopes Open
Within the present work, previously measured experimental cross-sections of the 63Cu(α,γ)67Ga reaction at astrophysical energies are compared with a variety of different theoretical calculations. Utilizing the nuclear reaction code TALYS (…
View article: Wafer‐Scale Demonstration of Polycrystalline MoS<sub>2</sub> Growth on 200 mm Glass and SiO<sub>2</sub>/Si Substrates by Plasma‐Enhanced Atomic Layer Deposition
Wafer‐Scale Demonstration of Polycrystalline MoS<sub>2</sub> Growth on 200 mm Glass and SiO<sub>2</sub>/Si Substrates by Plasma‐Enhanced Atomic Layer Deposition Open
2D materials like transition metal dichalcogenides (TMDCs) have been widely studied and are a gateway to modern technologies. While research today is mostly carried out on a laboratory scale, there is an intensive need for reliable process…
View article: A sustainable CVD approach for ZrN as potential catalyst for nitrogen reduction reaction
A sustainable CVD approach for ZrN as potential catalyst for nitrogen reduction reaction Open
In pursuit of developing alternatives for the highly polluting Haber-Bosch process for ammonia synthesis, the electrocatalytic nitrogen reduction reaction (NRR) on transition metal nitrides such as zirconium mononitride (ZrN) has been iden…
View article: On the influence of annealing on the compositional and crystallographic properties of sputtered Li-Al-O thin films
On the influence of annealing on the compositional and crystallographic properties of sputtered Li-Al-O thin films Open
A Li-Al-O thin film materials library, deposited by inert magnetron sputtering and post-deposition annealing in O2 atmosphere, was used to study the effects of different annealing temperatures (300 to 850°C) and durations (1 min to 7 h) on…
View article: A sustainable CVD approach for ZrN as a potential catalyst for nitrogen reduction reaction
A sustainable CVD approach for ZrN as a potential catalyst for nitrogen reduction reaction Open
A versatile CVD process for growing facetted ZrN layers as a potential catalyst for electrochemical reduction of nitrogen to ammonia.
View article: Absolute cross section of the <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:mmultiscripts><mml:mi mathvariant="normal">C</mml:mi><mml:mprescripts/><mml:none/><mml:mn>12</mml:mn></mml:mmultiscripts><mml:mo>(</mml:mo><mml:mi>p</mml:mi><mml:mo>,</mml:mo><mml:mi>γ</mml:mi><mml:mo>)</mml:mo><mml:mmultiscripts><mml:mi mathvariant="normal">N</mml:mi><mml:mprescripts/><mml:none/><mml:mn>13</mml:mn></mml:mmultiscripts></mml:mrow></mml:math> reaction
Absolute cross section of the reaction Open
Solar neutrino measurements have recently reached a level of sensitivity such that CNO fluxes can now be experimentally determined. While these first measurements are still only sensitive to the higher energy neutrinos resulting from the <…
View article: Interplay of Precursor and Plasma for The Deposition of HfO<sub>2</sub> via PEALD: Film Growth and Dielectric Properties
Interplay of Precursor and Plasma for The Deposition of HfO<sub>2</sub> via PEALD: Film Growth and Dielectric Properties Open
HfO 2 thin films are appealing for microelectronic applications such as high‐ κ dielectric layers, memristors, and ferroelectric memory devices. To fulfill the different requirements of each application, the properties of the deposited mat…
View article: First results from the 63Cu(α,γ)67Ga reaction study for nuclear astrophysics purposes
First results from the 63Cu(α,γ)67Ga reaction study for nuclear astrophysics purposes Open
The 63Cu(α,γ)67Ga reaction cross-section was measured in the energy range between 5 and 9 MeV, which is relevant to p-process nucleosynthesis. The experiment was conducted at the Dynamitron Tandem Laboratory, of the Ruhr-University Bochum …
View article: CCDC 2144051: Experimental Crystal Structure Determination
CCDC 2144051: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2144286: Experimental Crystal Structure Determination
CCDC 2144286: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Microscopic Diffusion of Atomic Hydrogen and Water in HER Catalyst MoS<sub>2</sub> Revealed by Neutron Scattering
Microscopic Diffusion of Atomic Hydrogen and Water in HER Catalyst MoS<sub>2</sub> Revealed by Neutron Scattering Open
The design of novel and abundant catalytic materials for electrolysis is crucial for reaching carbon neutrality of the global energy system. A deliberate approach to catalyst design requires both theoretical and experimental knowledge not …
View article: CCDC 2193925: Experimental Crystal Structure Determination
CCDC 2193925: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2153885: Experimental Crystal Structure Determination
CCDC 2153885: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2153883: Experimental Crystal Structure Determination
CCDC 2153883: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2153884: Experimental Crystal Structure Determination
CCDC 2153884: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CVD Grown Tungsten Oxide for Low Temperature Hydrogen Sensing: Tuning Surface Characteristics via Materials Processing for Sensing Applications
CVD Grown Tungsten Oxide for Low Temperature Hydrogen Sensing: Tuning Surface Characteristics via Materials Processing for Sensing Applications Open
The intrinsic properties of semiconducting oxides having nanostructured morphology are highly appealing for gas sensing. In this study, the fabrication of nanostructured WO 3 thin films with promising surface characteristics for hydrogen (…
View article: Unveiling Ruthenium(II) Diazadienyls for Gas Phase Deposition Processes: Low Resistivity Ru Thin Films and Their Performance in the Acidic Oxygen Evolution Reaction
Unveiling Ruthenium(II) Diazadienyls for Gas Phase Deposition Processes: Low Resistivity Ru Thin Films and Their Performance in the Acidic Oxygen Evolution Reaction Open
Two novel ruthenium complexes belonging to the Ru(II)(DAD)(Cym) (DAD = diazadienyl) (Cym = cymene) compound family are introduced as promising precursors. Their chemical nature, potential for chemical vapor deposition (CVD), and possibly a…
View article: Silver Thin‐Film Electrodes Grown by Low‐Temperature Plasma‐Enhanced Spatial Atomic Layer Deposition at Atmospheric Pressure
Silver Thin‐Film Electrodes Grown by Low‐Temperature Plasma‐Enhanced Spatial Atomic Layer Deposition at Atmospheric Pressure Open
The unique properties of atomic layer deposition (ALD) are mainly exploited for metal oxides, while the growth of metals, such as silver, is still in its infancy. Low growth temperatures and high growth rates are essential to achieve condu…
View article: Unusual Phase Formation in Reactively Sputter‐Deposited La—Co—O Thin‐Film Libraries
Unusual Phase Formation in Reactively Sputter‐Deposited La—Co—O Thin‐Film Libraries Open
La‐based perovskites are versatile materials that are of interest for solid oxide fuel cells and electrocatalytic water splitting. During fabrication of composition spread thin‐film libraries of La—Co‐based oxide systems, an unusual phase …
View article: CCDC 2195121: Experimental Crystal Structure Determination
CCDC 2195121: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: High-performance iridium thin films for water splitting by CVD using new Ir(I) precursors
High-performance iridium thin films for water splitting by CVD using new Ir(I) precursors Open
Thin films of iridium can be utilized in a wide range of applications and are particularly interesting for catalytic transformations. For the scalable deposition of functional Ir thin films, metal-organic chemical vapor deposition (MOCVD) …