Devon Facchinato
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View article: Base metal chemistry and catalysis
Base metal chemistry and catalysis Open
This perspective provides an entry-level conversation concerning base metal catalysis as a green and sustainable solution in industrial and academic contexts. We establish a definition of “base metal,” challenging readers to consider the e…
View article: On the Realties of Base Metal Catalysis: An Overview
On the Realties of Base Metal Catalysis: An Overview Open
This perspective invites conversation concerning base metal catalysis as a green and sustainable solution in industrial and academic contexts. We explore what it means to be ‘sustainable’ and provide information on current efforts in synth…
View article: Rhodium Disulfur and Dioxygen Complexes: Examination of Boron Secondary Coordination Sphere Effects
Rhodium Disulfur and Dioxygen Complexes: Examination of Boron Secondary Coordination Sphere Effects Open
A series of diphosphine-ligated rhodium(III) h2-peroxo and -persulfido compounds are targeted with one subset containing a boron-rich secondary coordination sphere (SCS). A systematic investigation using both experimental and theoretical m…