Dharmraj Prajapati
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View article: Formation of a low-symmetry Pd<sub>8</sub> molecular barrel employing a hetero donor tetradentate ligand, and its use in the binding and extraction of C<sub>70</sub>
Formation of a low-symmetry Pd<sub>8</sub> molecular barrel employing a hetero donor tetradentate ligand, and its use in the binding and extraction of C<sub>70</sub> Open
A tetradentate ligand with two different donor groups gave unsymmetrical molecular barrel UNMB via self-assembly. The stronger binding affinity of UNMB towards C 70 over C 60 was used to extract C 70 from a mixture of C 60 /C 70 in high pu…
View article: A water-soluble Pd<sub>4</sub> molecular tweezer for selective encapsulation of isomeric quinones and their recyclable extraction
A water-soluble Pd<sub>4</sub> molecular tweezer for selective encapsulation of isomeric quinones and their recyclable extraction Open
A molecular tweezer (MT) was obtained by reacting a tetraimidazole donor (L) with a Pd( ii ) acceptor (M). MT was used for multicycle aqueous extraction of phenanthrenequinone (PQ) in high purity from an equimolar mixture of isomeric anthr…
View article: Water-Soluble Pd<sub>6</sub>L<sub>3</sub> Molecular Bowl for Separation of Phenanthrene from a Mixture of Isomeric Aromatic Hydrocarbons
Water-Soluble Pd<sub>6</sub>L<sub>3</sub> Molecular Bowl for Separation of Phenanthrene from a Mixture of Isomeric Aromatic Hydrocarbons Open
Phenanthrene is a high-value raw material in chemical industries. Separation of phenanthrene from isomeric anthracene continues to be a big challenge in the industry due to their very similar physical properties. Herein, we report the self…
View article: Kinetic And Thermodynamic Study Of Os(Viii) Catalysed Oxidation Of Glycine By Ferrate(Vi) In Alkaline Medium
Kinetic And Thermodynamic Study Of Os(Viii) Catalysed Oxidation Of Glycine By Ferrate(Vi) In Alkaline Medium Open
Kinetic and thermodynamic investigation on Os(VIII) catalysed oxidation of glycine by ferrate(VI) has been done in basic medium and in the temperature range 30– 45 0C. Rate of oxidation increases with increase in [FeO4