David M. King
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View article: Reactivity of a triamidoamine terminal uranium(<scp>vi</scp>)-nitride with 3d-transition metal metallocenes
Reactivity of a triamidoamine terminal uranium(<span>vi</span>)-nitride with 3d-transition metal metallocenes Open
The reactions of a uranium( vi )-nitride with 3d-transition metal metallocenes have been examined.
View article: CCDC 2115881: Experimental Crystal Structure Determination
CCDC 2115881: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2115882: Experimental Crystal Structure Determination
CCDC 2115882: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Uranium–nitride chemistry: uranium–uranium electronic communication mediated by nitride bridges
Uranium–nitride chemistry: uranium–uranium electronic communication mediated by nitride bridges Open
Sequential reduction of a uranium-azide through all the nitride steps is revealed. Experimentally determined U–U coupling in the diuranium( iv )–dinitride is shown by ab initio calculations to stem from the nitride bridges, not U–U bonding.
View article: Dipnictogen f-Element Chemistry: A Diphosphorus Uranium Complex
Dipnictogen f-Element Chemistry: A Diphosphorus Uranium Complex Open
The first isolation and structural characterization of an f-element dinitrogen complex was reported in 1988, but an f-element complex with the first heavier group 15 homologue diphosphorus has to date remained unknown. Here, we report the …
View article: Thorium- and uranium-azide reductions: a transient dithorium-nitride <i>versus</i> isolable diuranium-nitrides
Thorium- and uranium-azide reductions: a transient dithorium-nitride <i>versus</i> isolable diuranium-nitrides Open
Evidence for a transient, highly reactive ThNTh nitride is presented, in contrast to uranium analogues that are stable and isolable. Surprisingly, computational studies reveal a σ > π energy ordering for all these bridging nitride bonds, a…
View article: CCDC 1547175: Experimental Crystal Structure Determination
CCDC 1547175: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1547176: Experimental Crystal Structure Determination
CCDC 1547176: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1486686: Experimental Crystal Structure Determination
CCDC 1486686: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1486679: Experimental Crystal Structure Determination
CCDC 1486679: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1487596: Experimental Crystal Structure Determination
CCDC 1487596: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1486685: Experimental Crystal Structure Determination
CCDC 1486685: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1487597: Experimental Crystal Structure Determination
CCDC 1487597: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1486688: Experimental Crystal Structure Determination
CCDC 1486688: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1486680: Experimental Crystal Structure Determination
CCDC 1486680: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1487598: Experimental Crystal Structure Determination
CCDC 1487598: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1486683: Experimental Crystal Structure Determination
CCDC 1486683: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1486684: Experimental Crystal Structure Determination
CCDC 1486684: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1486681: Experimental Crystal Structure Determination
CCDC 1486681: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1486689: Experimental Crystal Structure Determination
CCDC 1486689: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1486682: Experimental Crystal Structure Determination
CCDC 1486682: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1547177: Experimental Crystal Structure Determination
CCDC 1547177: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1486687: Experimental Crystal Structure Determination
CCDC 1486687: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Assessing crystal field and magnetic interactions in diuranium-μ-chalcogenide triamidoamine complexes with U<sup>IV</sup>–E–U<sup>IV</sup> cores (E = S, Se, Te): implications for determining the presence or absence of actinide–actinide magnetic exchange
Assessing crystal field and magnetic interactions in diuranium-μ-chalcogenide triamidoamine complexes with U<sup>IV</sup>–E–U<sup>IV</sup> cores (E = S, Se, Te): implications for determining the presence or absence of actinide–actinide magnetic exchange Open
Analysis of UIV–E–UIV (E = S, Se, Te) complexes reveals their behaviour is due to crystal field effects and not exchange coupling.
View article: CCDC 1547174: Experimental Crystal Structure Determination
CCDC 1547174: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1547173: Experimental Crystal Structure Determination
CCDC 1547173: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1487599: Experimental Crystal Structure Determination
CCDC 1487599: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Uranium halide complexes stabilized by a new sterically demanding tripodal <i>tris</i>(<i>N</i>-adamantylamidodimethylsilyl)methane ligand
Uranium halide complexes stabilized by a new sterically demanding tripodal <i>tris</i>(<i>N</i>-adamantylamidodimethylsilyl)methane ligand Open
The new tris(N-adamantylamine-dimethylsilyl)methane HC{SiMe2N(H)Ad}3 (TsAdH3, 1) and its trilithium salt [HC{SiMe2N(Li)Ad}3] (TsAdLi3, 2) were synthesized and characterized by multinuclear NMR and IR spectroscopy, elemental microanalysis, …