Dmitry I. Pavlov
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View article: Luminescent Properties and Cytotoxic Activity of 2-phenylbenzoxazole Fluorosulfate Derivatives
Luminescent Properties and Cytotoxic Activity of 2-phenylbenzoxazole Fluorosulfate Derivatives Open
The synthesis of 2-phenylbenzoxazole fluorosulfate derivatives was carried out using the SuFEx reaction. To study the anticancer properties of the obtained compounds, the cell lines PC-3 (obtained from prostate adenocarcinoma), BT-474, and…
View article: Zinc(II) 2D Coordination Polymer With Terephthalate and 4,6‐Bis(Imidazol‐1‐yl)‐2,1,3‐Benzoxadiazole Linkers as a Selective Luminescent Probe for Gallium(III) Cations
Zinc(II) 2D Coordination Polymer With Terephthalate and 4,6‐Bis(Imidazol‐1‐yl)‐2,1,3‐Benzoxadiazole Linkers as a Selective Luminescent Probe for Gallium(III) Cations Open
A two‐dimensional (2D) zinc(II) coordination polymer CP‐1 , [Zn(im 2 bod)(bdc)] n (im 2 bod = 4,6‐bis(imidazol‐1‐yl)‐2,1,3‐benzoxadiazole, bdc 2− = 1,4‐benzenedicarboxylate), was synthesized and fully characterized. CP‐1 crystallizes in th…
View article: Lanthanum(III) Coordination Polymer Decorated With 2,1,3‐Benzoxadiazole Units for Sensitive Luminescent Recognition of Sulfate Anion
Lanthanum(III) Coordination Polymer Decorated With 2,1,3‐Benzoxadiazole Units for Sensitive Luminescent Recognition of Sulfate Anion Open
One‐dimensional coordination polymer La‐CP , {[La(H 2 O) 2 (HL O ) (L O )]·H 2 O} n containing a new luminescent ligand 4,7‐di(4‐carboxypyrazol‐1‐yl)‐2,1,3‐benzoxadiazole (H 2 L O ) was synthesized. Upon excitation at 400 nm, the compound …
View article: Metal-Organic Frameworks of Cobalt(II) with 4,7-Di(1,2,4-triazol-1-yl)-2,1,3-benzothiadiazole and Aromatic Dicarboxylic Acids: Synthesis, Crystal Structures, and Magnetic Properties
Metal-Organic Frameworks of Cobalt(II) with 4,7-Di(1,2,4-triazol-1-yl)-2,1,3-benzothiadiazole and Aromatic Dicarboxylic Acids: Synthesis, Crystal Structures, and Magnetic Properties Open
The reactions of cobalt(II) nitrate with 4,7-di(1,2,4-triazol-1-yl)-2,1,3-benzothiadiazole (Tr2btd) and aromatic dicarboxylic acids (terephthalic (H2bdc), 2,6-naphthalenedicarboxylic (2,6-H2Ndc), and 2,5-furandicarboxylic (2,5-H2Fdc) acids…
View article: 6,8-Dibromo-11H-indeno[1,2-b]quinolin-11-one
6,8-Dibromo-11H-indeno[1,2-b]quinolin-11-one Open
We report the synthesis of the new compound 6,8-dibromo-11H-indeno[1,2-b]quinolin-11-one, which presents an important type of nitrogen-containing heterocycles and is a useful intermediate product in organic synthesis. The structure of the …
View article: Experimental and Theoretical Elucidation of the Luminescence Quenching Mechanism in Highly Efficient Hg<sup>2+</sup> and Sulfadiazine Sensing by Ln‐MOF
Experimental and Theoretical Elucidation of the Luminescence Quenching Mechanism in Highly Efficient Hg<sup>2+</sup> and Sulfadiazine Sensing by Ln‐MOF Open
Heavy metal ions and antibiotic contamination have become a major environmental concern worldwide. The development of efficient recognition strategies of these pollutants at ultra‐low concentrations in aqueous solutions as well as the eluc…
View article: Ln‐MOF‐Based Hydrogel Films with Tunable Luminescence and Afterglow Behavior for Visual Detection of Ofloxacin and Anti‐Counterfeiting Applications (Adv. Mater. 19/2024)
Ln‐MOF‐Based Hydrogel Films with Tunable Luminescence and Afterglow Behavior for Visual Detection of Ofloxacin and Anti‐Counterfeiting Applications (Adv. Mater. 19/2024) Open
Ln-MOF-Based Hydrogel Films Flexible and biocompatible hydrogel thin-film materials based on lanthanide MOFs and carrageenan demonstrate sensitive and selective luminescence quenching response to the antibiotic ofloxacin in poultry meat an…
View article: Synthesis and study of a novel supramolecular 'host–guest' complex based on cucurbit[6]uril and 1,4-bis(2-hydroxyethyl)piperazine dihydrochloride
Synthesis and study of a novel supramolecular 'host–guest' complex based on cucurbit[6]uril and 1,4-bis(2-hydroxyethyl)piperazine dihydrochloride Open
A novel supramolecular complex C44H71Cl2N26O22 (CB[6]@Pipa·2HCl) of the “host-guest” type has been synthesized. It is based on cucurbit[6]uril (CB[6]) with dihydrochloride 1,4-bis(2-hydroxyethyl)piperazine (Pipa·2HCl) localized within the …
View article: CCDC 2294214: Experimental Crystal Structure Determination
CCDC 2294214: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2294213: Experimental Crystal Structure Determination
CCDC 2294213: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Synthesis of Novel Phosphorus-Containing Derivatives of 1,3,4-Trimethylglycoluril via the Birum–Oleksyszyn Reaction
Synthesis of Novel Phosphorus-Containing Derivatives of 1,3,4-Trimethylglycoluril via the Birum–Oleksyszyn Reaction Open
This work presents the synthesis of a new compound, 1-[aryl-(diphenylphosphono)methyl]-3,4,6-trimethylglycolurils, via the interaction of benzaldehyde and its mononitro- and monohydroxyderivatives with 1,3,4-trimethylglycoluril and triphen…
View article: Laser-Assisted Design of MOF-Derivative Platforms from Nano- to Centimeter Scales for Photonic and Catalytic Applications
Laser-Assisted Design of MOF-Derivative Platforms from Nano- to Centimeter Scales for Photonic and Catalytic Applications Open
Laser conversion of metal-organic frameworks (MOFs) has recently emerged as a fast and low-energy consumptive approach to create scalable MOF derivatives for catalysis, energy, and optics. However, due to the virtually unlimited MOF struct…
View article: CCDC 2263524: Experimental Crystal Structure Determination
CCDC 2263524: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2249118: Experimental Crystal Structure Determination
CCDC 2249118: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Exfoliation of 2D Metal‐Organic Frameworks: toward Advanced Scalable Materials for Optical Sensing
Exfoliation of 2D Metal‐Organic Frameworks: toward Advanced Scalable Materials for Optical Sensing Open
Two‐dimensional metal‐organic frameworks (MOFs) occupy a special place among the large family of functional 2D materials. Even at a monolayer level, 2D MOFs exhibit unique sensing, separation, catalytic, electronic, and conductive properti…
View article: CCDC 2249116: Experimental Crystal Structure Determination
CCDC 2249116: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2249117: Experimental Crystal Structure Determination
CCDC 2249117: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Experimental and Computational Investigation of the Oxime Bond Stereochemistry in c-Jun N-terminal Kinase 3 Inhibitors 11H-Indeno[1,2-b]quinoxalin-11-one Oxime and Tryptanthrin-6-oxime
Experimental and Computational Investigation of the Oxime Bond Stereochemistry in c-Jun N-terminal Kinase 3 Inhibitors 11H-Indeno[1,2-b]quinoxalin-11-one Oxime and Tryptanthrin-6-oxime Open
11H-Indeno[1,2-b]quinoxalin-11-one oxime (IQ-1) and tryptanthrin-6-oxime are potent c-Jun N-terminal kinase 3 (JNK-3) inhibitors demonstrating neuroprotective, anti-inflammatory and anti-arthritic activity. However, the stereochemical conf…
View article: Synthesis, Crystal Structure, and Luminescent Sensing Properties of a Supramolecular 3D Zinc(II) Metal–Organic Framework with Terephthalate and Bis(imidazol-1-yl)methane Linkers
Synthesis, Crystal Structure, and Luminescent Sensing Properties of a Supramolecular 3D Zinc(II) Metal–Organic Framework with Terephthalate and Bis(imidazol-1-yl)methane Linkers Open
Supramolecular 3D Zn(II) coordination polymer {[Zn(bim)(bdc)]⋅0.8DMF⋅0.4EtOH⋅0.1H2O }n (Zn-MOF), constructed from Zn2+ ions, bis(imidazol-1-yl)methane (bim) and terephthalate (bdc2−) anions, was synthesized and structurally characterized. …
View article: Luminescent Metal-Organic Framework with 2,1,3-Benzothiadiazole Units for Highly Sensitive Gossypol Sensing
Luminescent Metal-Organic Framework with 2,1,3-Benzothiadiazole Units for Highly Sensitive Gossypol Sensing Open
A new metal–organic framework based on cadmium(II) cations, di(p-carboxyphenyl)sulphone and 4,7-di(imidazol-1-yl)-2,1,3-benzothiadiazole was prepared, and its crystal structure was determined using single-crystal XRD analysis. MOF demonstr…
View article: CCDC 2208390: Experimental Crystal Structure Determination
CCDC 2208390: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2208389: Experimental Crystal Structure Determination
CCDC 2208389: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2208391: Experimental Crystal Structure Determination
CCDC 2208391: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Variable Dimensionality of Europium(III) and Terbium(III) Coordination Compounds with a Flexible Hexacarboxylate Ligand
Variable Dimensionality of Europium(III) and Terbium(III) Coordination Compounds with a Flexible Hexacarboxylate Ligand Open
A reaction between 4,4′,4″-(benzene-1,3,5-triyltris(oxy))triphthalic acid (H6L) and lanthanide(III) nitrates (Ln = Eu3+, Tb3+) in water under the same conditions gave a molecular coordination compound [Tb(H4.5L)2(H2O)5]∙6H2O in the case of…
View article: Iridium(III) and Rhodium(III) Half-Sandwich Coordination Compounds with 11H-Indeno[1,2-b]quinoxalin-11-one Oxime: A Case of Spontaneous Resolution of Rh(III) Complex
Iridium(III) and Rhodium(III) Half-Sandwich Coordination Compounds with 11H-Indeno[1,2-b]quinoxalin-11-one Oxime: A Case of Spontaneous Resolution of Rh(III) Complex Open
Two half-sandwich iridium(III) and rhodium(III) complexes with 11H-indeno[1,2-b]quinoxalin-11-one oxime (IQ-1) ligand were prepared by the reaction of the proligand with [M(Cp*)Cl2]2 (M = Ir, Rh) dimers. The reaction between IQ-1 and [Ir(C…
View article: CCDC 2118484: Experimental Crystal Structure Determination
CCDC 2118484: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2172853: Experimental Crystal Structure Determination
CCDC 2172853: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2172854: Experimental Crystal Structure Determination
CCDC 2172854: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2074084: Experimental Crystal Structure Determination
CCDC 2074084: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …