Dominik Fehn
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View article: A titanium redox-switch enables reversible C–C bond forming and splitting reactions
A titanium redox-switch enables reversible C–C bond forming and splitting reactions Open
A dinuclear titanium complex remains in a trivalent valence state, during redox-driven formation and breakage of a C–C σ-bond.
View article: Electronic Structure of <i>trans‐</i>[V<sup>II</sup>Cl<sub>2</sub>(E(CH<sub>3</sub>)<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>E(CH<sub>3</sub>)<sub>2</sub>)<sub>2</sub>], E=N, P
Electronic Structure of <i>trans‐</i>[V<sup>II</sup>Cl<sub>2</sub>(E(CH<sub>3</sub>)<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>E(CH<sub>3</sub>)<sub>2</sub>)<sub>2</sub>], E=N, P Open
Coordination complexes of general formula trans ‐[MX 2 (R 2 ECH 2 CH 2 ER 2 ) 2 ] (M II =Ti, V, Cr, Mn; E=N or P; R=alkyl or aryl) are a cornerstone of coordination and organometallic chemistry. We investigate the electronic properties of …
View article: Correction to “Enhanced Photostability of Lead Halide Perovskite Nanocrystals with Mn<sup>3+</sup> Incorporation”
Correction to “Enhanced Photostability of Lead Halide Perovskite Nanocrystals with Mn<sup>3+</sup> Incorporation” Open
ADVERTISEMENT RETURN TO ARTICLES ASAPPREVAddition/CorrectionNEXTORIGINAL ARTICLEThis notice is a correctionCorrection to "Enhanced Photostability of Lead Halide Perovskite Nanocrystals with Mn3+ Incorporation"Huiying Hu*Huiying HuMaterials…
View article: Divalent Titanium <i>via</i> Reductive N−C Coupling of a Ti<sup>IV</sup> Nitrido with <i>π</i>‐Acids
Divalent Titanium <i>via</i> Reductive N−C Coupling of a Ti<sup>IV</sup> Nitrido with <i>π</i>‐Acids Open
The nitrido‐ate complex [(PN) 2 Ti(N){μ 2 ‐K(OEt 2 )}] 2 ( 1 ) (PN − =(N‐(2‐P i Pr 2 ‐4‐methylphenyl)‐2,4,6‐Me 3 C 6 H 2 ) reductively couples CO and isocyanides in the presence of DME or cryptand (Kryptofix222), to form rare, five‐coordin…
View article: Divalent Titanium <i>via</i> Reductive N−C Coupling of a Ti<sup>IV</sup> Nitrido with <i>π</i>‐Acids
Divalent Titanium <i>via</i> Reductive N−C Coupling of a Ti<sup>IV</sup> Nitrido with <i>π</i>‐Acids Open
The nitrido‐ate complex [(PN) 2 Ti(N){μ 2 ‐K(OEt 2 )}] 2 ( 1 ) (PN − =(N‐(2‐P i Pr 2 ‐4‐methylphenyl)‐2,4,6‐Me 3 C 6 H 2 ) reductively couples CO and isocyanides in the presence of DME or cryptand (Kryptofix222), to form rare, five‐coordin…
View article: An electrically conducting 3D coronene-based metal–organic framework
An electrically conducting 3D coronene-based metal–organic framework Open
A novel electrically conducting cubic mesoporous metal–organic framework (MOF), consisting of hexahydroxy- cata -hexabenzocoronene ( c -HBC) and Fe III ions is presented.
View article: CCDC 2239593: Experimental Crystal Structure Determination
CCDC 2239593: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2239591: Experimental Crystal Structure Determination
CCDC 2239591: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2239594: Experimental Crystal Structure Determination
CCDC 2239594: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2239595: Experimental Crystal Structure Determination
CCDC 2239595: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2239592: Experimental Crystal Structure Determination
CCDC 2239592: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2131813: Experimental Crystal Structure Determination
CCDC 2131813: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2166115: Experimental Crystal Structure Determination
CCDC 2166115: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2131816: Experimental Crystal Structure Determination
CCDC 2131816: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2131815: Experimental Crystal Structure Determination
CCDC 2131815: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2131812: Experimental Crystal Structure Determination
CCDC 2131812: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2131814: Experimental Crystal Structure Determination
CCDC 2131814: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2125932: Experimental Crystal Structure Determination
CCDC 2125932: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2125931: Experimental Crystal Structure Determination
CCDC 2125931: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2125929: Experimental Crystal Structure Determination
CCDC 2125929: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2125930: Experimental Crystal Structure Determination
CCDC 2125930: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Uranium-Mediated Peroxide Activation and a Precursor toward an Elusive Uranium <i>cis</i>-Dioxo Fleeting Intermediate
Uranium-Mediated Peroxide Activation and a Precursor toward an Elusive Uranium <i>cis</i>-Dioxo Fleeting Intermediate Open
The activation of chalcogen–chalcogen bonds using organometallic uranium complexes has been well documented for S–S, Se–Se, and Te–Te bonds. In stark contrast, reports concerning the ability of a uranium complex to activate the O–O bond of…
View article: CCDC 1970341: Experimental Crystal Structure Determination
CCDC 1970341: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1966403: Experimental Crystal Structure Determination
CCDC 1966403: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2159697: Experimental Crystal Structure Determination
CCDC 2159697: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1966404: Experimental Crystal Structure Determination
CCDC 1966404: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Critical factors for photoelectrochemical and photocatalytic H<sub>2</sub> evolution from gray anatase (001) nanosheets
Critical factors for photoelectrochemical and photocatalytic H<sub>2</sub> evolution from gray anatase (001) nanosheets Open
In recent years, the defect engineering of titania via reduction treatments has shown a high potential for enabling efficient and co-catalyst-free photocatalytic H 2 generation from methanol/water solutions. However, defect engineering sim…
View article: Oxidative Cyclodehydrogenation of Trinaphthylamine: Selective Formation of a Nitrogen‐Centered Polycyclic π‐System Comprising 5‐ and 7‐Membered Rings
Oxidative Cyclodehydrogenation of Trinaphthylamine: Selective Formation of a Nitrogen‐Centered Polycyclic π‐System Comprising 5‐ and 7‐Membered Rings Open
We describe a new type of nitrogen‐centered polycyclic scaffold comprising a unique combination of 5‐, 6‐, and 7‐membered rings. The compound is accessible through an intramolecular oxidative cyclodehydrogenation of tri(1‐naphthyl)amine. T…
View article: Oxidative Cyclodehydrogenation of Trinaphthylamine: Selective Formation of a Nitrogen‐Centered Polycyclic π‐System Comprising 5‐ and 7‐Membered Rings
Oxidative Cyclodehydrogenation of Trinaphthylamine: Selective Formation of a Nitrogen‐Centered Polycyclic π‐System Comprising 5‐ and 7‐Membered Rings Open
We describe a new type of nitrogen‐centered polycyclic scaffold comprising a unique combination of 5‐, 6‐, and 7‐membered rings. The compound is accessible through an intramolecular oxidative cyclodehydrogenation of tri(1‐naphthyl)amine. T…
View article: Umpolung in einem Paar endständiger Cobalt(III)‐Imido/Imidylkomplexe
Umpolung in einem Paar endständiger Cobalt(III)‐Imido/Imidylkomplexe Open
Die Umsetzung des Co I ‐Komplexes [(TIMMN mes )Co I ](PF 6 ) ( 1 ) (TIMMN mes = t ris ‐[2‐(3‐Mesityl‐ im idazolin‐2‐yliden)‐ m ethyl]ami n ) mit Mesitylazid ergibt das Co III ‐Imid [(TIMMN mes )Co III (NMes)](PF 6 ) ( 2 ). Folgende Oxidati…