Dries De Sloovere
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View article: Organic Modification of Eutectogels Enhances Electrolyte/Electrode Contact in Sodium‐Ion Batteries
Organic Modification of Eutectogels Enhances Electrolyte/Electrode Contact in Sodium‐Ion Batteries Open
Na + ion conducting deep eutectic solvents (DESs) hold promise as alternative electrolytes for future sodium‐ion batteries (SIBs) because of their higher thermal stability compared to conventional liquid electrolytes, drastically improving…
View article: Organic‐Inorganic Hybrid Solid Composite Electrolytes for High Energy Density Lithium Batteries: Combining Manufacturability, Conductivity, and Stability
Organic‐Inorganic Hybrid Solid Composite Electrolytes for High Energy Density Lithium Batteries: Combining Manufacturability, Conductivity, and Stability Open
The deployment of solid and quasi‐solid electrolytes in lithium metal batteries is envisioned to push their energy densities to even higher levels, in addition to providing enhanced safety. This article discusses a set of hybrid solid comp…
View article: Superconcentration Strategy Allows Sodium Metal Compatibility in Deep Eutectic Solvents for Sodium-Ion Batteries
Superconcentration Strategy Allows Sodium Metal Compatibility in Deep Eutectic Solvents for Sodium-Ion Batteries Open
Sodium-ion batteries (SIBs) are a more sustainable alternative to lithium-ion batteries (LIBs) considering the abundance, global distribution, and low cost of sodium. However, their economic impact remains small compared to LIBs, owing in …
View article: Phase Engineering via Aluminum Doping Enhances the Electrochemical Stability of Lithium‐Rich Cobalt‐Free Layered Oxides for Lithium‐Ion Batteries
Phase Engineering via Aluminum Doping Enhances the Electrochemical Stability of Lithium‐Rich Cobalt‐Free Layered Oxides for Lithium‐Ion Batteries Open
Lithium‐rich, cobalt‐free oxides are promising potential positive electrode materials for lithium‐ion batteries because of their high energy density, lower cost, and reduced environmental and ethical concerns. However, their commercial bre…
View article: How Polymer Influences the Electrochemical Behavior of Eutectogels for Lithium Batteries
How Polymer Influences the Electrochemical Behavior of Eutectogels for Lithium Batteries Open
Solid electrolytes are regarded as good alternatives for liquid carbonate-based electrolytes, as they show much better safety. In polymeric eutectogel (P-ETG) hybrid solid-state electrolytes, a deep eutectic solvent (DES) is enclosed withi…
View article: Polymeric Backbone Eutectogel Electrolytes for High-Energy Lithium-Ion Batteries
Polymeric Backbone Eutectogel Electrolytes for High-Energy Lithium-Ion Batteries Open
This work introduces a polymeric backbone eutectogel (P-ETG) hybrid solid-state electrolyte with an N-isopropylacrylamide (NIPAM) backbone for high-energy lithium-ion batteries (LIBs). The NIPAM-based P-ETG is (electro)chemically co…
View article: Temperature-driven chemical segregation in Co-free Li-rich layered oxides and its influence on electrochemical performance
Temperature-driven chemical segregation in Co-free Li-rich layered oxides and its influence on electrochemical performance Open
Co-free Li-rich layered oxides are gaining interest as feasible positive electrode materials in lithium-ion batteries (LIBs) in terms of energy density, cost reduction, and alleviating safety concerns. Unfortunately, their commercializatio…
View article: Solution-gel-based surface modification of LiNi<sub>0.5</sub>Mn<sub>1.5</sub>O<sub>4−<i>δ</i></sub> with amorphous Li–Ti–O coating
Solution-gel-based surface modification of LiNi<sub>0.5</sub>Mn<sub>1.5</sub>O<sub>4−<i>δ</i></sub> with amorphous Li–Ti–O coating Open
LNMO powder surface was modified with amorphous Li–Ti–O. Increase in electrochemically active surface area, as well as improved HF-scavenging enhanced its electrochemical performance.
View article: Photocatalytic Performance of Undoped and Al-Doped ZnO Nanoparticles in the Degradation of Rhodamine B under UV-Visible Light:The Role of Defects and Morphology
Photocatalytic Performance of Undoped and Al-Doped ZnO Nanoparticles in the Degradation of Rhodamine B under UV-Visible Light:The Role of Defects and Morphology Open
Quasi-spherical undoped ZnO and Al-doped ZnO nanoparticles with different aluminum content, ranging from 0.5 to 5 at% of Al with respect to Zn, were synthesized. These nanoparticles were evaluated as photocatalysts in the photodegradation …
View article: Temperature-Driven Chemical Segregation in Co-Free Li-Rich-Layered Oxides and Its Influence on Electrochemical Performance
Temperature-Driven Chemical Segregation in Co-Free Li-Rich-Layered Oxides and Its Influence on Electrochemical Performance Open
Co-free Li-rich layered oxides are gaining interest as feasible positiveelectrode materials in lithium-ion batteries (LIBs) in terms of energy density, costreduction, and alleviating safety concerns. Unfortunately, their commercialization …
View article: Deep Eutectic Solvents as Nonflammable Electrolytes for Durable Sodium‐Ion Batteries
Deep Eutectic Solvents as Nonflammable Electrolytes for Durable Sodium‐Ion Batteries Open
Radiative Cooling In article number 2100159, Dries De Sloovere, An Hardy, and co-workers, show that careful investigation and optimization of the coordination structure of deep eutectic solvents allows the preparation of a viable electroly…
View article: Deep Eutectic Solvents as Nonflammable Electrolytes for Durable Sodium‐Ion Batteries
Deep Eutectic Solvents as Nonflammable Electrolytes for Durable Sodium‐Ion Batteries Open
Sodium‐ion batteries are alternatives for lithium‐ion batteries in applications where cost‐effectiveness is of primary concern, such as stationary energy storage. The stability of sodium‐ion batteries is limited by the current generation o…
View article: Frontispiece: Precursor Design Strategies for the Low‐Temperature Synthesis of Functional Oxides: It's All in the Chemistry
Frontispiece: Precursor Design Strategies for the Low‐Temperature Synthesis of Functional Oxides: It's All in the Chemistry Open
Limiting the energetic budget during the solution processing of oxides is one of the most crucial considerations, adhering to green chemistry principles. Low-temperature strategies require thought-out adjustments at the level of the chemic…
View article: Photo-induced copper-mediated (meth)acrylate polymerization towards graphene oxide and reduced graphene oxide modification
Photo-induced copper-mediated (meth)acrylate polymerization towards graphene oxide and reduced graphene oxide modification Open
View article: CSD 1865782: Experimental Crystal Structure Determination
CSD 1865782: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: CSD 1865779: Experimental Crystal Structure Determination
CSD 1865779: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: CSD 1865780: Experimental Crystal Structure Determination
CSD 1865780: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: CSD 1865781: Experimental Crystal Structure Determination
CSD 1865781: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: Ti surface doping of LiNi<sub>0.5</sub>Mn<sub>1.5</sub>O<sub>4−δ</sub> positive electrodes for lithium ion batteries
Ti surface doping of LiNi<sub>0.5</sub>Mn<sub>1.5</sub>O<sub>4−δ</sub> positive electrodes for lithium ion batteries Open
LiNi0.5Mn1.5O4−δ surface is doped with Ti ion maintaining the spinel structure at 500 °C, higher annealing temperatures cause Ti diffusion from surface towards the core.
View article: Combustion synthesis as a low temperature route to Li<sub>4</sub>Ti<sub>5</sub>O<sub>12</sub> based powders for lithium ion battery anodes
Combustion synthesis as a low temperature route to Li<sub>4</sub>Ti<sub>5</sub>O<sub>12</sub> based powders for lithium ion battery anodes Open
An LTO based anode material was synthesized at a significantly lower temperature and shorter processing time than previously reported.
View article: The low-temperature chemical synthesis of Li4Ti5O12 powder for Li-ion battery anodes
The low-temperature chemical synthesis of Li4Ti5O12 powder for Li-ion battery anodes Open
While using Li4Ti5O12 (LTO) as the anode material in lithium ion batteries greatly enhances their operation safety and avoids the formation of a solid electrolyte interface, the synthesis of this material often comes at a high time and ene…