Emilio Pardo
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View article: Efficient Capture of Short‐ and Long‐Chain PFAS from Water by a Metal–Organic Framework
Efficient Capture of Short‐ and Long‐Chain PFAS from Water by a Metal–Organic Framework Open
Per‐ and polyfluoroalkyl substances (PFAS), known as “forever chemicals,” present major environmental and health risks due to their extreme stability and dual hydrophobic–hydrophilic character, which complicates remediation. Conventional a…
View article: Efficient removal of drugs of abuse from drinking water using metal–organic frameworks
Efficient removal of drugs of abuse from drinking water using metal–organic frameworks Open
Efficient removal of drugs of abuse: a family of oxamifato-based metal–organic frameworks with outstanding reusability and removal efficiency for drugs of abuse is reported in this work.
View article: Decoding host–guest interactions: tuning pore functionality in MOFs for efficient capture of short- and long-chain PFAS
Decoding host–guest interactions: tuning pore functionality in MOFs for efficient capture of short- and long-chain PFAS Open
A family of bio-derived MOFs was synthesised for efficient PFAS removal. Hydrophobic pore tailoring boosted adsorption of short-chain PFAS, with structural and theoretical analyses confirming the preeminent role of hydrophobic interactions.
View article: Controlled Zn(II) to Co(II) Transmetalation in a Metal–Organic Framework Inducing Single-Ion Magnet Behavior
Controlled Zn(II) to Co(II) Transmetalation in a Metal–Organic Framework Inducing Single-Ion Magnet Behavior Open
The intrinsic characteristic features of metal–organic frameworks offer unique, great opportunities to develop novel materials with applications in very diverse fields. Aiming to take advantage of these, the application of post-synthetic m…
View article: BioMOF@PAN Mixed Matrix Membranes as Fast and Efficient Adsorbing Materials for Multiple Heavy Metals’ Removal
BioMOF@PAN Mixed Matrix Membranes as Fast and Efficient Adsorbing Materials for Multiple Heavy Metals’ Removal Open
Heavy metal ions are a common source of water pollution. In this study, two novel membranes with biobased metal-organic frameworks (BioMOFs) embedded in a polyacrylonitrile matrix with tailored porosity were prepared via nonsolvent induced…
View article: Environmental Health Assessment by Local Environmental Justice Experts for Evidence‐Based Decision‐Making in an Agricultural Community of Northern California
Environmental Health Assessment by Local Environmental Justice Experts for Evidence‐Based Decision‐Making in an Agricultural Community of Northern California Open
Environmental justice research driven by academics and policymakers often overlooks the valuable insights and leadership of the communities most impacted by environmental hazards. When institution‐led research approaches are employed, inad…
View article: Efficient nickel and cobalt recovery by metal–organic framework based mixed matrix membranes (MMM-MOFs)
Efficient nickel and cobalt recovery by metal–organic framework based mixed matrix membranes (MMM-MOFs) Open
Green energy transition\nhas supposed to give a huge boost\nto the\nelectric vehicle rechargeable battery market. This has generated a\ncompelling demand for raw materials, such as cobalt and nickel, which\nare key common constituents in l…
View article: Efficient Nickel and Cobalt Recovery by Metal–Organic Framework-Based Mixed Matrix Membranes (MMM-MOFs)
Efficient Nickel and Cobalt Recovery by Metal–Organic Framework-Based Mixed Matrix Membranes (MMM-MOFs) Open
Green energy transition has supposed to give a huge boost to the electric vehicle rechargeable battery market. This has generated a compelling demand for raw materials, such as cobalt and nickel, which are key common constituents in lithiu…
View article: Design of Multivariate Biological Metal–Organic Frameworks: Toward Mimicking Active Sites of Enzymes
Design of Multivariate Biological Metal–Organic Frameworks: Toward Mimicking Active Sites of Enzymes Open
Mimicking enzymatic processes carried out by natural enzymes, which are highly efficient biocatalysts with key roles in living organisms, attracts much interest but constitutes a synthetic challenge. Biological metal-organic frameworks (bi…
View article: Bioinspired metal–organic frameworks for aqueous environment decontamination: from laboratory scale to real-world technologies
Bioinspired metal–organic frameworks for aqueous environment decontamination: from laboratory scale to real-world technologies Open
Oxamidato-based MOFs in water remediation: the most remarkable examples of the application of oxamidato-based bioMOFs for the selective and efficient removal of emerging pollutants are highlighted in this feature article.
View article: Single–atom Cu catalysts for the oxidative coupling of styrenes with aryl sulfones: from salts and zeolites to MOFs
Single–atom Cu catalysts for the oxidative coupling of styrenes with aryl sulfones: from salts and zeolites to MOFs Open
Oxidative couplings in organic synthesis are typically performed with unrecoverable precious metal catalysts in solution. Here we show that CuCO3, Cu-supported zeolites and Cu-metal organic frameworks (MOFs) can replace AgNO3 as a catalyst…
View article: Application of metal-organic frameworks for sensing of VOCs and other volatile biomarkers
Application of metal-organic frameworks for sensing of VOCs and other volatile biomarkers Open
Volatile organic compounds (VOCs) are present in the mixture of gases found in the exhaled human breath. Since their occurrence in the breath may indicate the presence of a disease, some VOCs are referred to as 'biomarkers.' One of the mos…
View article: CCDC 2265848: Experimental Crystal Structure Determination
CCDC 2265848: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Degradation of Penicillinic Antibiotics and β‐Lactamase Enzymatic Catalysis in a Biomimetic Zn‐Based Metal–Organic Framework
Degradation of Penicillinic Antibiotics and β‐Lactamase Enzymatic Catalysis in a Biomimetic Zn‐Based Metal–Organic Framework Open
Invited for the cover of this issue are Jesús Ferrando‐Soria, Donatella Armentano, Antonio Leyva‐Pérez, Emilio Pardo and co‐workers at University of Valencia, Technical University of Valencia and University of Calabria. The image depicts t…
View article: Front Cover: Degradation of Penicillinic Antibiotics and β‐Lactamase Enzymatic Catalysis in a Biomimetic Zn‐Based Metal–Organic Framework (Chem. Eur. J. 51/2023)
Front Cover: Degradation of Penicillinic Antibiotics and β‐Lactamase Enzymatic Catalysis in a Biomimetic Zn‐Based Metal–Organic Framework (Chem. Eur. J. 51/2023) Open
A novel ZnII biological metal–organic framework mimics β-lactamase enzymes. The crystal structure of a novel Zn-based biological MOF occupies the central position to reflect the crucial role that its porous functional channels play in the …
View article: Ag2(0) dimers within a thioether-functionalized MOF catalyze the CO2 to CH4 hydrogenation reaction
Ag2(0) dimers within a thioether-functionalized MOF catalyze the CO2 to CH4 hydrogenation reaction Open
Ultrasmall silver clusters in reduced state are difficult to synthesize since silver atoms tend to rapidly aggregate into bigger entities. Here, we show that dimers of reduced silver (Ag 2 ) are formed within the framework of a metal–organ…
View article: CCDC 2258088: Experimental Crystal Structure Determination
CCDC 2258088: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2258089: Experimental Crystal Structure Determination
CCDC 2258089: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Degradation of Penicillinic Antibiotics and β‐Lactamase Enzymatic Catalysis in a Biomimetic Zn‐Based Metal–Organic Framework
Degradation of Penicillinic Antibiotics and β‐Lactamase Enzymatic Catalysis in a Biomimetic Zn‐Based Metal–Organic Framework Open
β‐Lactam antibiotics are one of the most commonly prescribed drugs to treat bacterial infections. However, their use has been somehow limited given the emergence of bacteria with resistance mechanisms, such as β‐lactamases, which inactivat…
View article: CCDC 2157534: Experimental Crystal Structure Determination
CCDC 2157534: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2241172: Experimental Crystal Structure Determination
CCDC 2241172: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: MOF-Triggered Synthesis of Subnanometer Ag<sup>0</sup><sub>2</sub> Clusters and Fe<sup>3+</sup> Single Atoms: Heterogenization Led to Efficient and Synergetic One-Pot Catalytic Reactions
MOF-Triggered Synthesis of Subnanometer Ag<sup>0</sup><sub>2</sub> Clusters and Fe<sup>3+</sup> Single Atoms: Heterogenization Led to Efficient and Synergetic One-Pot Catalytic Reactions Open
The combination of well-defined Fe3+ isolated single-metal atoms and Ag2 subnanometer metal clusters within the channels of a metal-organic framework (MOF) is reported and characterized by single-crystal X-ray diffraction for the first tim…
View article: Exploring the Role of Amino Acid-Derived Multivariate Metal–Organic Frameworks as Catalysts in Hemiketalization Reactions
Exploring the Role of Amino Acid-Derived Multivariate Metal–Organic Frameworks as Catalysts in Hemiketalization Reactions Open
Understanding the host-guest chemistry in MOFs represents a research field with outstanding potential to develop in a rational manner novel porous materials with improved performances in fields such as heterogeneous catalysis. Herein, we r…
View article: Controlled Supramolecular Self‐assembly in<scp>MOF</scp>Confined Spaces
Controlled Supramolecular Self‐assembly in<span>MOF</span>Confined Spaces Open
The chapter is focused on our recent advances in the construction of well-defined metal organic framework (MOF)-driven self-assembly of supramolecular species. The experimental developments, which reside at the connection between supramole…
View article: KOH-Based Hydrothermal Synthesis of Iron-Rich Titanate Nanosheets Assembled into 3D Hierarchical Architectures from Natural Ilmenite Mineral Sands
KOH-Based Hydrothermal Synthesis of Iron-Rich Titanate Nanosheets Assembled into 3D Hierarchical Architectures from Natural Ilmenite Mineral Sands Open
The synthesis of titanate nanostructures from low-cost mineral precursors is a topic of continuous interest, considering not only their fundamental aspects but also the benefits of incorporating such nanomaterials in a wide variety of appl…
View article: CCDC 2215543: Experimental Crystal Structure Determination
CCDC 2215543: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …