Eaindra Lwin
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View article: Rotational, vibrational, conformational and diastereomeric dimer cooling of aminoalcohols in soft supersonic expansions and the monohydrate of dimethylaminoethanol
Rotational, vibrational, conformational and diastereomeric dimer cooling of aminoalcohols in soft supersonic expansions and the monohydrate of dimethylaminoethanol Open
Supersonic jet expansions allow to cool molecules and to form molecular complexes over a wide range of expansion conditions, ranging from nearly effusive expansions of the pure vapour to colder expansions in carrier gases. The resulting mo…
View article: The universal vibrational dynamics of water bound to tertiary amines: more than just Fermi resonance
The universal vibrational dynamics of water bound to tertiary amines: more than just Fermi resonance Open
Infrared spectra of jet-cooled microhydrated amines with fishy odours reveal anharmonic water vibrational dynamics.
View article: Rotational, vibrational, conformational and diastereomeric dimer cooling of aminoalcohols in soft supersonic expansions and the monohydrate of dimethylaminoethanol
Rotational, vibrational, conformational and diastereomeric dimer cooling of aminoalcohols in soft supersonic expansions and the monohydrate of dimethylaminoethanol Open
Non-equilibrium thermal excitation of different degrees of freedom in hydrogen-bonded systems is explored using vibrational gas phase spectroscopy for the benefit of future computational modelling.
View article: OH-stretching dynamics in trimethylamine monohydrate: what can we learn from three different direct absorption spectra?
OH-stretching dynamics in trimethylamine monohydrate: what can we learn from three different direct absorption spectra? Open
The anharmonic resonances of strongly hydrogen-bonded water are systematically tuned by thermal excitation and matrix isolation.
View article: Microhydration of Tertiary Amines: Robust Resonances in Red-Shifted Water
Microhydration of Tertiary Amines: Robust Resonances in Red-Shifted Water Open
[Image: see text] Tertiary amines are strong hydrogen bond acceptors. When a water molecule donates one of the OH groups, its in-phase stretching vibration wavenumber is decreased to such an extent that it comes close to the water bending …