Edson Leonardo Scarpa de Souza
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View article: General and Anti‐Markovnikov Selective Ni‐Catalyzed Alkylation of Arenes and Heteroarenes with Non‐Activated Olefins
General and Anti‐Markovnikov Selective Ni‐Catalyzed Alkylation of Arenes and Heteroarenes with Non‐Activated Olefins Open
The majority of C–C coupling reactions between arenes and olefins result in the formation of branched isomer products, exhibiting what is known as Markovnikov selectivity. However, alternative catalytic strategies are required to modulate …
View article: Development of highly efficient and selective palladium catalysts for telomerization of 1,3-butadiene with alcohols
Development of highly efficient and selective palladium catalysts for telomerization of 1,3-butadiene with alcohols Open
Novel phosphine ligands based on (benzo)furylphosphines, enable the efficient palladium-catalyzed telomerization of 1,3-butadiene with methanol.
View article: Intramolecular Heck-Matsuda Reaction for the Asymmetric Synthesis of a Spiro-Benzofuran Using Chiral N,N-Ligands: Experimental and Theoretical Insights into the Catalytic Cycle and Enantioselectivity
Intramolecular Heck-Matsuda Reaction for the Asymmetric Synthesis of a Spiro-Benzofuran Using Chiral N,N-Ligands: Experimental and Theoretical Insights into the Catalytic Cycle and Enantioselectivity Open
View article: Combination of the structural components of amino acids with fatty acids: access to an unknown class of “fatty” α-amino acids by palladium-catalyzed amidocarbonylation
Combination of the structural components of amino acids with fatty acids: access to an unknown class of “fatty” α-amino acids by palladium-catalyzed amidocarbonylation Open
A new class of fatty amino acids, integrating fatty acids motifs, is synthesized in one step via palladium-catalyzed amidocarbonylation.
View article: Proposing Oxalic Acid as Chemical Storage of Carbon Dioxide to Achieve Carbon Neutrality
Proposing Oxalic Acid as Chemical Storage of Carbon Dioxide to Achieve Carbon Neutrality Open
Increasing emissions of carbon dioxide into the atmosphere due to the use of fossil fuels and ongoing deforestation are affecting the global climate. To reach the Paris climate agreement, in the coming decades low emission technologies mus…
View article: In Tandem Enantioselective Intramolecular Heck-Matsuda Reactions directly from anilines
In Tandem Enantioselective Intramolecular Heck-Matsuda Reactions directly from anilines Open
A new enantioselective intramolecular strategy for the synthesis of enantioenriched bridged benzoxacines, unsaturated spirobenzofurans, methyl-2,3-dihydrobenzofuran acetates, and methyl-2,3-indoline acetate scaffolds in a tandem-like diazo…
View article: Arilações radicalares regiosseletivas de olefinas ricas em elétrons catalisadas por ferro
Arilações radicalares regiosseletivas de olefinas ricas em elétrons catalisadas por ferro Open
Uma vez que anéis aromáticos estão presentes em fármacos
View article: Iron-Catalyzed Meerwein Carbooxygenation of Electron-Rich Olefins: Studies with Styrenes, Vinyl Pyrrolidinone, and Vinyl Oxazolidinone
Iron-Catalyzed Meerwein Carbooxygenation of Electron-Rich Olefins: Studies with Styrenes, Vinyl Pyrrolidinone, and Vinyl Oxazolidinone Open
The arylative oxygenation of the electron-rich olefins styrene, α-methylstyrene, vinyl pyrrolidinone, and vinyl oxazolidinone was accomplished using arenediazonium salts and catalytic amounts of FeSO4 in an effective single elec…