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View article: Multiorbital Interactions and Spin Polarization in Single Rare-Earth Adatoms
Multiorbital Interactions and Spin Polarization in Single Rare-Earth Adatoms Open
Surface-adsorbed rare-earth nanostructures are ideal platforms to investigate the interplay between intra-atomic interactions and multiorbital spin configurations. However, addressing these properties has posed severe experimental and theo…
View article: Germanene-Based Two-Dimensional Magnet with Tunable Properties
Germanene-Based Two-Dimensional Magnet with Tunable Properties Open
Magnetic order engineering in two-dimensional Dirac systems is of great interest for theoretical and technological exploration. Up to now, the experimental advances in this field mostly concerned graphene monolayers. Here, we report a comp…
View article: Non-Pinned, Reversible Spin Crossover in Self-Assembled Monolayers of a Functionalized Fe(II) Scorpionate Complex
Non-Pinned, Reversible Spin Crossover in Self-Assembled Monolayers of a Functionalized Fe(II) Scorpionate Complex Open
The spin crossover (SCO) behaviour of molecules in (sub)monolayers is typically significantly altered from that of the bulk: in particular, the SCO can be quenched by direct contact between the SCO molecules and the substrate, known as pin…
View article: Non-Pinned, Reversible Spin Crossover in Self-Assembled Monolayers of a Functionalized Fe(II) Scorpionate Complex
Non-Pinned, Reversible Spin Crossover in Self-Assembled Monolayers of a Functionalized Fe(II) Scorpionate Complex Open
Spin crossover (SCO) in (sub)monolayers is typically altered from that in the bulk: in particular, the SCO can be quenched by direct contact between the SCO molecules and the substrate, causing problems for potential device applications. H…
View article: Multi-Orbital Interactions and Spin Polarization in Single Rare-Earth Adatoms
Multi-Orbital Interactions and Spin Polarization in Single Rare-Earth Adatoms Open
Surface-adsorbed rare-earth nanostructures are ideal platforms to investigate the interplay between intra-atomic interactions and multi-orbital spin configurations. However, addressing these properties has posed severe experimental and the…
View article: Temperature Induced Reversible Switching of the Magnetic Anisotropy in a Neodymium Complex Adsorbed on Graphite
Temperature Induced Reversible Switching of the Magnetic Anisotropy in a Neodymium Complex Adsorbed on Graphite Open
Controlling the magnetic anisotropy of molecular layers assembled on a surface is one of the challenges that needs to be addressed to create the next‐generation spintronic devices. Recently, metal complexes that show a reversible solid‐sta…
View article: Finite size effects on the metamagnetic phase transition in a B2 FeRh nanocluster thick film
Finite size effects on the metamagnetic phase transition in a B2 FeRh nanocluster thick film Open
FeRh alloys in the CsCl-type (B2) chemically ordered phase present an antiferromagnetic to ferromagnetic order transition around 370 K observed in bulk and continuous films but absent in nanoclusters. In this study, we investigate the ther…
View article: Electronic and Magnetic Properties of a Monolayer of VOTPP Molecules Sublimated on Ag(100)
Electronic and Magnetic Properties of a Monolayer of VOTPP Molecules Sublimated on Ag(100) Open
Vanadyl(IV) 5,10,15,20‐tetraphenylporphyrin (VOTPP) is an S = 1/2 molecular system with remarkable spin qubit properties. Its structure offers a higher chemical tunability with respect to archetypal molecular qubits, such as vanadyl(IV)Pht…
View article: Room-temperature-persistent magnetic interaction between coordination complexes and nanoparticles in maghemite-based nanohybrids
Room-temperature-persistent magnetic interaction between coordination complexes and nanoparticles in maghemite-based nanohybrids Open
Magnetic coordination complexes interact strongly with maghemite nanoparticles, increasing their magnetic anisotropy and remaining coupled up to room temperature.
View article: Investigation of the spin crossover behaviour of a sublimable Fe(<scp>ii</scp>)-qsal complex: from the bulk to a submonolayer on graphene/SiO<sub>2</sub>
Investigation of the spin crossover behaviour of a sublimable Fe(<span>ii</span>)-qsal complex: from the bulk to a submonolayer on graphene/SiO<sub>2</sub> Open
Spin crossover Fe( ii ) molecules deposited on graphene/SiO 2 as a submonolayer present a switching behavior within the whole temperature range from 350 to 4 K.
View article: Assembling Fe<sub>4</sub> single-molecule magnets on a TiO<sub>2</sub> monolayer
Assembling Fe<sub>4</sub> single-molecule magnets on a TiO<sub>2</sub> monolayer Open
A monolayer of tetrairon( iii ) (Fe 4 ) molecules, featuring single-molecule magnet (SMM) behavior, is used to decorate a TiO 2 film. We evaluated the modifications occurring at the interface, a crucial issue for future applications of SMM…
View article: Finite size effects on the metamagnetic phase transition in a thick B2 FeRh nanocluster film
Finite size effects on the metamagnetic phase transition in a thick B2 FeRh nanocluster film Open
An inhomogeneous grain coarsening distribution to explain the metamagnetic transition in a thick film of assembled B2 FeRh nanoclusters.
View article: Hybrid Heterostructures of a Spin Crossover Coordination Polymer on MoS<sub>2</sub>: Elucidating the Role of the 2D Substrate (Small 50/2023)
Hybrid Heterostructures of a Spin Crossover Coordination Polymer on MoS<sub>2</sub>: Elucidating the Role of the 2D Substrate (Small 50/2023) Open
status: Published
View article: Orbital Magnetic Moment and Single-Ion Magnetic Anisotropy of the <i>S</i> = 1/2 K<sub>3</sub>[Fe(CN)<sub>6</sub>] Compound: A Case Where the Orbital Magnetic Moment Dominates the Spin Magnetic Moment
Orbital Magnetic Moment and Single-Ion Magnetic Anisotropy of the <i>S</i> = 1/2 K<sub>3</sub>[Fe(CN)<sub>6</sub>] Compound: A Case Where the Orbital Magnetic Moment Dominates the Spin Magnetic Moment Open
The potassium hexacyanoferrate(III), K3[FeIII(CN)6], is known for its exceptional magnetic anisotropy among the 3d transition metal series. The Fe(III) ions are in the S = 1/2 low spin state imposed by the strong crystal field of the cyani…
View article: Hybrid Heterostructures of a Spin Crossover Coordination Polymer on MoS<sub>2</sub>: Elucidating the Role of the 2D Substrate
Hybrid Heterostructures of a Spin Crossover Coordination Polymer on MoS<sub>2</sub>: Elucidating the Role of the 2D Substrate Open
Controlling the deposition of spin‐crossover (SCO) materials constitutes a crucial step for the integration of these bistable molecular systems in electronic devices. Moreover, the influence of functional surfaces, such as 2D materials, ca…
View article: Impact of Embedded Co Nanoparticles on Local Magnetic Properties of <b> <i>L</i> </b>1<sub>0</sub>-FePt Films
Impact of Embedded Co Nanoparticles on Local Magnetic Properties of <b> <i>L</i> </b>1<sub>0</sub>-FePt Films Open
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View article: Interface versus Bulk Light-Induced Switching in Spin-Crossover Molecular Ultrathin Films Adsorbed on a Metallic Surface
Interface versus Bulk Light-Induced Switching in Spin-Crossover Molecular Ultrathin Films Adsorbed on a Metallic Surface Open
Spin-crossover molecules present the unique property of having two spin states that can be controlled by light excitation at low temperature. Here, we report on the photoexcitation of [FeII((3, 5-(CH3)2Pz)3BH)2] (Pz = pyrazolyl) ultrathin …
View article: Investigation of a Tetrathiafulvalene-Based Fe2+ Thermal Spin Crossover Assembled on Gold Surface
Investigation of a Tetrathiafulvalene-Based Fe2+ Thermal Spin Crossover Assembled on Gold Surface Open
A thick film and a monolayer of tetrathiafulvalene-based Fe2+ spin-crossover complex have been deposited by solution on a Au (111) substrate, attempting both self-assembling monolayer protocol and a simpler drop-casting procedure. The ther…
View article: Magnetic molecules as sensors of topological hysteresis of superconductors
Magnetic molecules as sensors of topological hysteresis of superconductors Open
Superconductors and magnetic materials, including molecules, are key ingredients for quantum and advanced spintronic applications. However, only a little is known about how these materials are mutually influenced at their interface in hybr…
View article: Magnetic Ordering in Ultrasmall Potassium Ferrite Nanoparticles Grown on Graphene Nanoflakes
Magnetic Ordering in Ultrasmall Potassium Ferrite Nanoparticles Grown on Graphene Nanoflakes Open
Magnetic nanoparticles are central to the development of efficient hyperthermia treatments, magnetic drug carriers, and multimodal contrast agents. While the magnetic properties of small crystalline iron oxide nanoparticles are well unders…
View article: CCDC 2083928: Experimental Crystal Structure Determination
CCDC 2083928: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2083926: Experimental Crystal Structure Determination
CCDC 2083926: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2083932: Experimental Crystal Structure Determination
CCDC 2083932: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2083929: Experimental Crystal Structure Determination
CCDC 2083929: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2083930: Experimental Crystal Structure Determination
CCDC 2083930: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2083927: Experimental Crystal Structure Determination
CCDC 2083927: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2083931: Experimental Crystal Structure Determination
CCDC 2083931: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Engineering Chemisorption of Fe<sub>4</sub> Single‐Molecule Magnets on Gold
Engineering Chemisorption of Fe<sub>4</sub> Single‐Molecule Magnets on Gold Open
Gaining control over the grafting geometry is critically important for any application of surface‐supported single‐molecule magnets (SMMs) in data storage, spintronics, and quantum information science. Here, tetrairon(III) SMMs with a prop…