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View article: Organic–Inorganic Hybrid Materials from Vegetable Oils
Organic–Inorganic Hybrid Materials from Vegetable Oils Open
The production of materials based on fossil resources is yielding more sustainable and ecologically beneficial methods. Vegetable oils (VO) are one example of base materials whose derivatives rival the properties of their petro‐based count…
View article: Rheological and mechanical comparison of di-and tri-block copolymer imine vitrimers
Rheological and mechanical comparison of di-and tri-block copolymer imine vitrimers Open
View article: Rheological and Mechanical Comparison of Di and Tri-Block Copolymer Vitrimers Using Dynamic Imine Exchange
Rheological and Mechanical Comparison of Di and Tri-Block Copolymer Vitrimers Using Dynamic Imine Exchange Open
View article: Uncovering and mitigating bias in large, automated MRI analyses of brain development
Uncovering and mitigating bias in large, automated MRI analyses of brain development Open
Large, population-based MRI studies of adolescents promise transformational insights into neurodevelopment and mental illness risk 1, 2 . However, MRI studies of youth are especially susceptible to motion and other artifacts 3, 4 . These a…
View article: Integrated Process for Structuring and Functionalizing Ordered Mesoporous Silica to Achieve Superprotonic Conductivity
Integrated Process for Structuring and Functionalizing Ordered Mesoporous Silica to Achieve Superprotonic Conductivity Open
International audience
View article: Synthetic Polymers with Finely Regulated Monomer Sequences: Properties and Emerging Applications
Synthetic Polymers with Finely Regulated Monomer Sequences: Properties and Emerging Applications Open
The design of synthetic polymers with controlled monomer sequences is an important emerging trend in polymer science. This new field of research is bio‐inspired by sequence‐defined biopolymers such as proteins and nucleic acids. The chemic…
View article: Storing the portrait of Antoine de Lavoisier in a single macromolecule
Storing the portrait of Antoine de Lavoisier in a single macromolecule Open
A pixelated portrait of Antoine de Lavoisier was stored in a digitally-encoded poly(phosphodiester). The storage capacity attained in this work (440 bits/chain) is the highest ever reported for a synthetic informational polymer. To reach t…
View article: Synthesis and sequencing of informational poly(amino phosphodiester)s
Synthesis and sequencing of informational poly(amino phosphodiester)s Open
The inclusion of main-chain tertiary amines in digital poly(phosphodiester)s allows synthesis of molecularly-defined achiral polymers and simplifies tandem mass spectrometry sequencing.
View article: Synthèse et optimisation de séquences de poly(phosphodiester)s à haute capacité de stockage d’information et à lecture facilitée
Synthèse et optimisation de séquences de poly(phosphodiester)s à haute capacité de stockage d’information et à lecture facilitée Open
This thesis focused on the synthesis of digital poly(phosphodiester)s. These non-natural polymers are built thanks to a monomeric alphabet which enables to write a binary message at the molecular level. These polymers are read by a pseudo-…
View article: Precise Alkoxyamine Design to Enable Automated Tandem Mass Spectrometry Sequencing of Digital Poly(phosphodiester)s
Precise Alkoxyamine Design to Enable Automated Tandem Mass Spectrometry Sequencing of Digital Poly(phosphodiester)s Open
A major step towards reliable reading of information coded in the sequence of long poly(phosphodiester)s was previously achieved by introducing an alkoxyamine spacer between information sub‐segments. However, MS/MS decoding had to be perfo…
View article: High-Capacity Digital Polymers: Storing Images in Single Molecules
High-Capacity Digital Polymers: Storing Images in Single Molecules Open
International audience
View article: Particle Flux Effects on Physicochemical Polymer Degradations
Particle Flux Effects on Physicochemical Polymer Degradations Open
Particle flux effects on polymer physicochemical degradations were investigated. Different polymers were studied depending on application: silicone, fluoropolymer, acrylic, epoxy, polyimide, polyurethane, etc. Polymers with surface functio…