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View article: [Rh<sub>2</sub>(phesp)<sub>2</sub>]: a Bulkier [Rh<sub>2</sub>(esp)<sub>2</sub>] Analog to Tune the Site‐Selectivity in Carbene C─H Insertion Reactions
[Rh<sub>2</sub>(phesp)<sub>2</sub>]: a Bulkier [Rh<sub>2</sub>(esp)<sub>2</sub>] Analog to Tune the Site‐Selectivity in Carbene C─H Insertion Reactions Open
[Rh 2 (phesp) 2 ], a new dirhodium(II) complex bearing a bulky bidentate bis‐carboxylate ligand, has been prepared in two steps from commercially available compounds. Its X‐ray structure revealed distinctive features with a strong distorti…
View article: Synthesis and characterization of new highly fluorinated phosphoramidates bearing different alkylamino groups
Synthesis and characterization of new highly fluorinated phosphoramidates bearing different alkylamino groups Open
Seventeen new highly fluorinated phosphoramidates containing alkylamino moieties of the type (RFO)2P(O)NHR (R = CH2CH2CH3, (CH2)3CH3, (CH2)4-CH3, CH(CH3)2, C6H11, CH2CH2-C6H5, CH2-C6H5 or C6H5; RF = CH2CF3, CH2C2F5 or CH2CH2C6F13) were syn…
View article: Polymeric nanoreactors for catalytic applications
Polymeric nanoreactors for catalytic applications Open
Mimicking Nature is one drive for chemists to design efficient architectures matching the activity and selectivity of natural catalytic systems, such as enzymes. To this extent, the developed architectures need to have a selective and acti…
View article: One‐Pot Synthesis of Rh Nanoparticles in Polycationic‐Shell, Triphenylphosphine Oxide‐Functionalized Core‐Crosslinked Micelles for Aqueous Biphasic Hydrogenation
One‐Pot Synthesis of Rh Nanoparticles in Polycationic‐Shell, Triphenylphosphine Oxide‐Functionalized Core‐Crosslinked Micelles for Aqueous Biphasic Hydrogenation Open
Cationic‐shell core‐crosslinked micelles (CCM−C) with rhodium nanoparticles (RhNPs) anchored to core‐linked triphenylphosphine oxide (TPPO) ligands were synthesized by a facile one‐pot approach by the reduction of [Rh(COD)(μ‐Cl)] 2 /toluen…
View article: Hafnium coordination vitrimer based on carboxylate exchange: synthesis, properties, and mechanistic investigations on the [Hf<sub>6</sub>O<sub>4</sub>(OH)<sub>4</sub>(O<sub>2</sub>CMe)<sub>12</sub>]<sub>2</sub> model compound
Hafnium coordination vitrimer based on carboxylate exchange: synthesis, properties, and mechanistic investigations on the [Hf<sub>6</sub>O<sub>4</sub>(OH)<sub>4</sub>(O<sub>2</sub>CMe)<sub>12</sub>]<sub>2</sub> model compound Open
A hafnium‐based coordination vitrimer (Hf−CooAN‐10) has been prepared by carboxylate ligand exchange from [Hf 6 O 4 (OH) 4 (O 2 CMe) 12 ] 2 and poly‐((ethylhexyl methacylate)‐ co ‐(carboxyethyl acrylate)) (M n = 14.4 kg mol −1 , Đ = 2.2, 9…
View article: Understanding ketone hydrogenation catalysis with anionic iridium(<scp>iii</scp>) complexes: the crucial role of counterion and solvation
Understanding ketone hydrogenation catalysis with anionic iridium(<span>iii</span>) complexes: the crucial role of counterion and solvation Open
A highly unusual mechanism for asymmetric hydrogenation catalysed by an anionic Ir III hydride system, including a strong counterion dependence on catalyst activity, is explored and rationalised.
View article: CCDC 2286862: Experimental Crystal Structure Determination
CCDC 2286862: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2286864: Experimental Crystal Structure Determination
CCDC 2286864: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2286865: Experimental Crystal Structure Determination
CCDC 2286865: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2286866: Experimental Crystal Structure Determination
CCDC 2286866: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2286863: Experimental Crystal Structure Determination
CCDC 2286863: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Coordination Adaptable Networks: Introducing Vitrimer Properties Using Dynamic Coordination Bonds
Coordination Adaptable Networks: Introducing Vitrimer Properties Using Dynamic Coordination Bonds Open
Coordination adaptable networks (CooANs) may be obtained by combination of ligand‐functionalized polymers and metal ions or clusters when the crosslink migration by ligand exchange with available free ligands in the polymer matrix is facil…
View article: New Protocol for the Synthesis of S‐Thioesters from Benzylic, Allylic and Tertiary Alcohols with Thioacetic Acid
New Protocol for the Synthesis of S‐Thioesters from Benzylic, Allylic and Tertiary Alcohols with Thioacetic Acid Open
A new one‐pot solvent‐less reaction to convert benzylic, allylic, ferrocenyl or tertiary alcohols into S‐thioesters, bench‐stable and less odorous precursors of the corresponding thiols, which is based on reactions in neat thioacetic acid …
View article: CCDC 2253409: Experimental Crystal Structure Determination
CCDC 2253409: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2226722: Experimental Crystal Structure Determination
CCDC 2226722: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2226723: Experimental Crystal Structure Determination
CCDC 2226723: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Synthesis of Tris[2‐(dimethylamino)ethyl]amine with Regiospecific Deuterium Labels
Synthesis of Tris[2‐(dimethylamino)ethyl]amine with Regiospecific Deuterium Labels Open
Simple synthetic routes to regioselectively deuterated tris[2-(dimethylamino)ethyl]amine (Me6TREN) variants are described. Imine formation with formaldehyde-d2 from tris(2-aminoethyl)amine (TREN) and subsequent reductions with NaBD4 afford…
View article: Synthesis of Tris[2‐(dimethylamino)ethyl]amine with Regiospecific Deuterium Labels
Synthesis of Tris[2‐(dimethylamino)ethyl]amine with Regiospecific Deuterium Labels Open
Simple synthetic routes to regioselectively deuterated tris[2‐(dimethylamino)ethyl]amine (Me 6 TREN) variants are described. Imine formation with formaldehyde‐ d 2 from tris(2‐aminoethyl)amine (TREN) and subsequent reductions with NaBD 4 a…
View article: Synthesis of Tris[2‐(dimethylamino)ethyl]amine with Regiospecific Deuterium Labels
Synthesis of Tris[2‐(dimethylamino)ethyl]amine with Regiospecific Deuterium Labels Open
Simple synthetic routes to regioselectively deuterated tris[2-(dimethylamino)ethyl]amine (Me6TREN) variants are described. Imine formation with formaldehyde-d2 from tris(2-aminoethyl)amine (TREN) and subsequent reductions with NaBD4 afford…
View article: Catalyst‐Free Thia‐Michael Addition to α‐Trifluoromethylacrylates for 3D Network Synthesis
Catalyst‐Free Thia‐Michael Addition to α‐Trifluoromethylacrylates for 3D Network Synthesis Open
Thia‐Michael additions (1,4‐additions of a thiol to a Michael acceptor) are generally catalyzed by an external Brønsted or Lewis base. A spontaneous (uncatalyzed) Michael addition of thiols to α‐trifluoromethyl acrylates is described, as w…
View article: Redox-responsive catalysis: fine tuning of chemoselectivity in the intramolecular reaction of diazo compounds catalysed by ferrocene-functionalised dirhodium(<scp>ii</scp>) complexes
Redox-responsive catalysis: fine tuning of chemoselectivity in the intramolecular reaction of diazo compounds catalysed by ferrocene-functionalised dirhodium(<span>ii</span>) complexes Open
In redox-responsive carbene transfer catalysis using neutral or oxidised forms of ferrocene-containing dirhodium( ii ) species, the weakly interacting SbF 6 − anion allows a greater chemoselectivity change toward the aromatic C–H insertion…
View article: Ir<sup>I</sup>(η<sup>4</sup>-diene) precatalyst activation by strong bases: formation of an anionic Ir<sup>III</sup> tetrahydride
Ir<sup>I</sup>(η<sup>4</sup>-diene) precatalyst activation by strong bases: formation of an anionic Ir<sup>III</sup> tetrahydride Open
Complex [IrCl(COD)(dppe)] yields [IrH 4 (dppe)] − at 80 °C (or at room T under H 2 ) in the presence of strong base and isopropanol, hinting to the nature the active species in Ir-catalysed hydrogenations and transfer hydrogenations.
View article: Acetate exchange mechanism on a Zr <sub>12</sub> oxo hydroxo cluster: relevance for reshaping Zr–carboxylate coordination adaptable networks
Acetate exchange mechanism on a Zr <sub>12</sub> oxo hydroxo cluster: relevance for reshaping Zr–carboxylate coordination adaptable networks Open
The acetate ligand exchange with free acetic acid in [Zr 6 O 4 (OH) 4 (O 2 CCH 3 ) 12 ] 2 , used as a model of crosslink migration in [Zr 6 O 4 (OH) 4 ]-based coordination vitrimers, has been thoroughly investigated by dynamic 1 H NMR and …
View article: Acetate ion addition to and exchange in (1,5-cyclooctadiene)rhodium(<scp>i</scp>) acetate: relevance for the coagulation of carboxylic acid-functionalized shells of core-crosslinked micelle latexes
Acetate ion addition to and exchange in (1,5-cyclooctadiene)rhodium(<span>i</span>) acetate: relevance for the coagulation of carboxylic acid-functionalized shells of core-crosslinked micelle latexes Open
[Rh(COD)(μ-OAc)] 2 reacts with acetate in dichloromethane to produce equilibrium amounts of [Rh(COD)(OAc) 2 ] − and exchanges the acetate ligands with polymer-linked methacrylic acid, rationalizing the coagulation of core-crosslinked micel…
View article: Phosphine-Functionalized Core-Crosslinked Micelles and Nanogels with an Anionic Poly(styrenesulfonate) Shell: Synthesis, Rhodium(I) Coordination and Aqueous Biphasic Hydrogenation Catalysis
Phosphine-Functionalized Core-Crosslinked Micelles and Nanogels with an Anionic Poly(styrenesulfonate) Shell: Synthesis, Rhodium(I) Coordination and Aqueous Biphasic Hydrogenation Catalysis Open
Stable latexes containing unimolecular amphiphilic core-shell star-block polymers with a triphenylphosphine(TPP)-functionalized hydrophobic core and an outer hydrophilic shell based on anionic styrenesulfonate monomers have been synthesize…
View article: Coordination Adaptable Networks: Zirconium(IV) Carboxylates
Coordination Adaptable Networks: Zirconium(IV) Carboxylates Open
Vitrimers are 3D “covalent adaptable networks” (CANs) with flow properties thanks to thermally activated associative exchange reactions. This contribution introduces coordination adaptable networks, or CooANs, that are topologically relate…
View article: CCDC 2159223: Experimental Crystal Structure Determination
CCDC 2159223: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …