Erik Misselwitz
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View article: On-Surface Synthesis of Nonbenzenoid PAHs Using Intermolecular π-Radical C–C Coupling
On-Surface Synthesis of Nonbenzenoid PAHs Using Intermolecular π-Radical C–C Coupling Open
On-surface synthesis has emerged as a new research field, ideal for designing low-dimensional carbon-based nanomaterials. One of the central problems with this synthetic approach is the understanding of reaction mechanisms, which is a key …
View article: Fluoranthene-Containing Distorted Nanographenes Exhibiting Two-Photon Absorption Response
Fluoranthene-Containing Distorted Nanographenes Exhibiting Two-Photon Absorption Response Open
Two distorted nanographenes combining helicenes and a fluoranthene unit within their polycyclic scaffolds were synthesized. Their structural and electronic properties were elucidated by various spectroscopic methods, and the experimental d…
View article: Cyclopentannulated Decacyclenes as Carbon‐Based Multistage Electron Acceptors
Cyclopentannulated Decacyclenes as Carbon‐Based Multistage Electron Acceptors Open
We report a series of cyclopentannulated decacyclenes that act as remarkable multistage electron acceptors. The compounds were synthesized in a modular approach via Yamamoto cyclotrimerization of brominated pyracylene precursors, allowing …
View article: Octacyano-substituted tridecacyclene: a non-benzenoid cyanocarbon with low-lying LUMO and multistage redox properties
Octacyano-substituted tridecacyclene: a non-benzenoid cyanocarbon with low-lying LUMO and multistage redox properties Open
Octacyanation of tridecacyclene affords a saddle-shaped multistage electron acceptor with a low-lying LUMO and a unique solid-state packing mediated by hydrogen bonding.
View article: Cover Feature: Indenoannulated Tridecacyclene: An All‐Carbon Seven‐Stage Redox‐Amphoter (Chem. Eur. J. 34/2024)
Cover Feature: Indenoannulated Tridecacyclene: An All‐Carbon Seven‐Stage Redox‐Amphoter (Chem. Eur. J. 34/2024) Open
Charge it up: Indenoannulation of tridecacyclene afforded a saddle-shaped nanocarbon with one octagonal and multiple pentagonal rings. The compound can undergo seven reversible redox events (highlighted as electron flashes), facilitated by…
View article: Indenoannulated Tridecacyclene: An All‐Carbon Seven‐Stage Redox‐Amphoter
Indenoannulated Tridecacyclene: An All‐Carbon Seven‐Stage Redox‐Amphoter Open
We disclose an indenoannulated tridecacyclene comprising a central cyclooctatetraene moiety with multiple adjacent pentagonal rings which is accessible in a concise synthetic sequence. The saddle‐shaped geometry of the non‐benzenoid polycy…
View article: CCDC 2212011: Experimental Crystal Structure Determination
CCDC 2212011: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2212012: Experimental Crystal Structure Determination
CCDC 2212012: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: TIPS‐Ethynylated Naphthodiquinoline and Naphthodiacridine: Novel Diazabisacenes
TIPS‐Ethynylated Naphthodiquinoline and Naphthodiacridine: Novel Diazabisacenes Open
The synthesis of two diazabisacenes is reported. A bisboronated naphthalene was Suzuki‐coupled to substituted ethyl nicotinates, then cyclized by intramolecular Friedel‐Crafts acylation. The resulting diketones were alkynylated and reduced…