Ethan Gerhardt
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View article: Electroreductive Iron Catalysis Enabled by a Redox Mediator: Alkyne Semi-Hydrogenation as a Model System
Electroreductive Iron Catalysis Enabled by a Redox Mediator: Alkyne Semi-Hydrogenation as a Model System Open
The development of electroreductive Fe-catalyzed processes for organic synthesis has remained scarce compared to other earth abundant metals despite inherent advantages in cost, low-toxicity, and accessible redox. Through stability of the …
View article: A Voltage-Controlled Redox Mediator Strategy Enables Electrocatalytic Z-Selective Semi-Hydrogenation
A Voltage-Controlled Redox Mediator Strategy Enables Electrocatalytic Z-Selective Semi-Hydrogenation Open
Selective semi-hydrogenation to generate alkenes from alkynes is an invaluable method to access olefins for materials, pharmaceuticals, and nat-ural products. Electrochemical transition-metal-catalyzed hydrogenation is an attractive altern…