F. Marchetti
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View article: Correction to “Half-Sandwich Ruthenium and Osmium Complexes with Hydrazinocurcuminoid-like Ligands”
Correction to “Half-Sandwich Ruthenium and Osmium Complexes with Hydrazinocurcuminoid-like Ligands” Open
[This corrects the article DOI: 10.1021/acs.organomet.5c00082.].
View article: Half-Sandwich Ruthenium and Osmium Complexes with Hydrazinocurcuminoid-like Ligands
Half-Sandwich Ruthenium and Osmium Complexes with Hydrazinocurcuminoid-like Ligands Open
Ruthenium and osmium half-sandwich complexes with hydrazinocurcuminoid ligands, 4,4'-((1E,1'E)-(1-(pyridin-2-yl)-1H-pyrazole-3,5-diyl)-bis-(ethene-2,1-diyl))-bis-(2-methoxyphenol) (HZPcurc) and 4,4'-((1E,1'E)-(1-(pyridin-2-yl)-1H-pyrazole-…
View article: Ruthenium(<scp>ii</scp>)-bisdemethoxycurcumin conjugate complexes as potent antitumour agents through simultaneous inhibition of 20S proteasome and HMG-CoA reductase
Ruthenium(<span>ii</span>)-bisdemethoxycurcumin conjugate complexes as potent antitumour agents through simultaneous inhibition of 20S proteasome and HMG-CoA reductase Open
The synthesis of new conjugated bisdemethoxycurcumin ligands, each incorporating a distinct acyl substituent—cyclic, aliphatic, heteroaromatic, or branched—in place of the native hydroxyl groups, has been reported.
View article: Ru(II)-Arene Complexes of Curcumin and Bisdesmethoxycurcumin Metabolites
Ru(II)-Arene Complexes of Curcumin and Bisdesmethoxycurcumin Metabolites Open
Curcuminoids and their complexes continue to attract attention in medicinal chemistry, but little attention has been given to their metabolic derivatives. Here, the first examples of (arene)Ru(II) complexes with curcuminoid metabolites, te…
View article: Quality of Life and Its Psychosocial Predictors among Patients with Disorders of Gut–Brain Interaction: A Comparison with Age- and Sex-Matched Controls
Quality of Life and Its Psychosocial Predictors among Patients with Disorders of Gut–Brain Interaction: A Comparison with Age- and Sex-Matched Controls Open
The disorders of gut–brain interaction (DGBIs) are a heterogeneous group of chronic conditions that greatly reduce patients’ quality of life (QoL). To date, biopsychosocial factors (such as gastrointestinal symptoms, alexithymia, and inter…
View article: NRF2 activation in BON‑1 neuroendocrine cancer cells reduces the cytotoxic effects of a novel Ruthenium(II)‑curcumin compound: A pilot study
NRF2 activation in BON‑1 neuroendocrine cancer cells reduces the cytotoxic effects of a novel Ruthenium(II)‑curcumin compound: A pilot study Open
Gastroenteropancreatic neuroendocrine neoplasms (GEP‑NEN) are a group of rare tumors whose specific pathogenetic mechanisms of resistance to therapies have not been completely revealed yet. Chemotherapy is the main therapeutic approach in …
View article: Bioactive Ag(<scp>i</scp>) coordination complexes as dopants for castor oil plasticized ethylcellulose films
Bioactive Ag(<span>i</span>) coordination complexes as dopants for castor oil plasticized ethylcellulose films Open
New ethylcellulose films doped with bioactive Ag( i ) complexes and a natural plasticizer are prepared and characterized. Their antibacterial activity makes them potential active food packaging materials.
View article: CCDC 2261945: Experimental Crystal Structure Determination
CCDC 2261945: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Copper and Zinc Metal–Organic Frameworks with Bipyrazole Linkers Display Strong Antibacterial Activity against Both Gram+ and Gram− Bacterial Strains
Copper and Zinc Metal–Organic Frameworks with Bipyrazole Linkers Display Strong Antibacterial Activity against Both Gram+ and Gram− Bacterial Strains Open
Here, we report a new synthetic protocol based on microwave-assisted synthesis (MAS) for the preparation of higher yields of zinc and copper in MOFs based on different bis(pyrazolyl)-tagged ligands ([M(BPZ)]n where M = Zn(II), Cu(II), H2BP…
View article: Copper and Zinc MOFs With Bipyrazole Linkers Display Strong Antibacterial Activity Against Both Gram+ and Gram- Bacterial Strains
Copper and Zinc MOFs With Bipyrazole Linkers Display Strong Antibacterial Activity Against Both Gram+ and Gram- Bacterial Strains Open
Here we report a new synthetic protocol based on Microwave- Assisted Synthesis (MAS) for the preparation in higher yields of zinc and copper MOFs based on different bis(pyrazolyl)-tagged ligands ([M(BPZ)]n where M = Zn(II), Cu(II), H2BPZ =…
View article: Steric and Electronic Effects Responsible for <i>N</i>,<i>O</i>- or <i>N</i>,<i>N</i>-Chelating Coordination of Pyrazolones Containing a Pyridine Ring in Ruthenium Arene Systems
Steric and Electronic Effects Responsible for <i>N</i>,<i>O</i>- or <i>N</i>,<i>N</i>-Chelating Coordination of Pyrazolones Containing a Pyridine Ring in Ruthenium Arene Systems Open
Structural and electronic factors are crucial to rationalizethedifferent N,O or N,N chelating coordination of pyrazolones containinga pyridine ring. The reactivity of proligand 3-phenyl-1-(pyridin-2-yl)-5-pyrazolone(HLpy,ph) with the (aren…
View article: CCDC 2225698: Experimental Crystal Structure Determination
CCDC 2225698: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2190681: Experimental Crystal Structure Determination
CCDC 2190681: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2190070: Experimental Crystal Structure Determination
CCDC 2190070: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2190069: Experimental Crystal Structure Determination
CCDC 2190069: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Multitarget-Directed Gallium(III) Tris(acyl-pyrazolonate) Complexes Induce Ferroptosis in Cancer Cells via Dysregulation of Cell Redox Homeostasis and Inhibition of the Mevalonate Pathway
Multitarget-Directed Gallium(III) Tris(acyl-pyrazolonate) Complexes Induce Ferroptosis in Cancer Cells via Dysregulation of Cell Redox Homeostasis and Inhibition of the Mevalonate Pathway Open
A series of Ga(Qn)3 coordination compounds have been synthesized, where HQn is 1-phenyl-3-methyl-4-RC(═O)-pyrazolo-5-one. The complexes have been characterized through analytical data, NMR and IR spectroscopy, ESI mass spectrometry, elemen…
View article: NRF2 and Bip Interconnection Mediates Resistance to the Organometallic Ruthenium-Cymene Bisdemethoxycurcumin Complex Cytotoxicity in Colon Cancer Cells
NRF2 and Bip Interconnection Mediates Resistance to the Organometallic Ruthenium-Cymene Bisdemethoxycurcumin Complex Cytotoxicity in Colon Cancer Cells Open
Organometallic ruthenium (Ru)(II)-cymene complexes display promising pharmacological properties and might represent alternative therapeutic agents in medical applications. Polyphenols, such as curcumin and curcuminoids, display beneficial …
View article: Self-Assembly of a Two-Dimensional Coordination Polymer Based on Silver and Lanthanide Tetrakis-Acylpyrazolonates: An Efficient New Strategy for Suppressing Ligand-to-Metal Charge Transfer Quenching of Europium Luminescence
Self-Assembly of a Two-Dimensional Coordination Polymer Based on Silver and Lanthanide Tetrakis-Acylpyrazolonates: An Efficient New Strategy for Suppressing Ligand-to-Metal Charge Transfer Quenching of Europium Luminescence Open
A new strategy for the easy polymerization of anionic [Ln(Qcy)4]− (HQcy-4-(cyclohexanecarbonyl)-5-methyl-2-phenyl-2,4-dihydro-3H-pyrazol-3-one) into two-dimensional layers of [AgLn(Qcy)4]n (Ln = Sm, Eu, Gd, Tb and Dy) is proposed by bindin…
View article: CCDC 2215453: Experimental Crystal Structure Determination
CCDC 2215453: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2215455: Experimental Crystal Structure Determination
CCDC 2215455: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2215462: Experimental Crystal Structure Determination
CCDC 2215462: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2159059: Experimental Crystal Structure Determination
CCDC 2159059: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2159060: Experimental Crystal Structure Determination
CCDC 2159060: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2086825: Experimental Crystal Structure Determination
CCDC 2086825: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Antibacterial activity of copper pyrazolate coordination polymers
Antibacterial activity of copper pyrazolate coordination polymers Open
Cu( ii ) pyrazolate coordination polymers display antibacterial activity through a “contact kill” mechanism.
View article: CCDC 2193265: Experimental Crystal Structure Determination
CCDC 2193265: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2193266: Experimental Crystal Structure Determination
CCDC 2193266: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …