Bing‐Feng Shi
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Modification of [2.2]Paracyclophanes via Cobalt/Salox‐Catalyzed Enantioselective Electrooxidative or Photoredox C─H Acyloxylation and Alkoxylation Open
Chiral [2.2]paracyclophanes (PCPs) have widespread application in asymmetric catalysis and materials science. However, enantioselective C─H activation of PCPs remains elusive and challenging due to steric hindrance, which differs significa…
View article: Antigen Presentation by Graft Myofibroblasts Leads to Murine Heart Transplantation Rejection through the Autophagy Signaling Pathway
Antigen Presentation by Graft Myofibroblasts Leads to Murine Heart Transplantation Rejection through the Autophagy Signaling Pathway Open
Background Fibrobalst plays a critical role in heart physiology and pathology, yet their immunological role in transplanted heart grafts remains unclear, particularly the mechanisms involved. Methods Heart transplantation was performed in …
View article: Nickel(II)/Salox-Catalyzed Enantioselective C–H Functionalization
Nickel(II)/Salox-Catalyzed Enantioselective C–H Functionalization Open
Recently, nickel catalysts have garnered considerable attention for their efficacy and versatility in asymmetric catalysis, attributed to their distinctive properties. However, the use of cost-effective and sustainable divalent nickel cata…
Recent progress towards catalytic asymmetric construction of inherently chiral scaffolds Open
This tutorial review generalizes the booming and remarkable advancements in asymmetric synthesis of inherently chiral calix[ n ]arenes, pillar[ n ]arenes, saddle-shaped scaffolds, mechanically interlocked molecules, and prism-like cages.
<i>Lactobacillus rhamnosus</i> HN001 facilitates the efficacy of dual PI3K/mTOR inhibition prolonging cardiac transplant survival and enhancing antitumor effect Open
Solid organ transplantation is a crucial treatment for patients who have reached the end stage of heart, lung, kidney, or liver failure. However, the likelihood of developing cancer post-transplantation increases. Additionally, primary mal…
Cobalt-Catalyzed Domino Transformations via Enantioselective C–H Activation/Nucleophilic [3+2] Annulation Towards Chiral Bridged Bicycles Open
Selective synthesis of chiral bridged (hetero)bicyclic scaffolds via asymmetric C–H activation constitutes substantial chal-lenges, due to the multiple reactivities of strained bicyclic structures. Herein, we develop the domino transformat…
Construction of Planar Chiral Ferrocenes by Cobalt-Catalyzed Enantioselective C–H Acyloxylation Enabled by Dual Ligands Open
Open AccessCCS ChemistryRESEARCH ARTICLES22 Mar 2024Construction of Planar Chiral Ferrocenes by Cobalt-Catalyzed Enantioselective C–H Acyloxylation Enabled by Dual Ligands Fan-Rui Huang, Peng Zhang, Qi-Jun Yao and Bing-Feng Shi Fan-Rui Hua…
Pd(<span>ii</span>)-catalyzed enantioselective C–H olefination and photoregulation of sterically hindered diarylethenes Open
We have for the first time directly constructed intrinsic chiral diarylethenes through an enantioselective C–H olefination strategy.
Pd(<span>ii</span>)-Catalyzed enantioselective C–H olefination toward the synthesis of <i>P</i>-stereogenic phosphinamides Open
A Pd( ii )-catalyzed enantioselective C–H olefination toward the synthesis of P -stereogenic phosphines is reported.
Copper/BINOL-Catalyzed Enantioselective C-H Functionalization towards Planar Chiral Ferrocenes Under Mild Conditions Open
Copper-catalyzed enantioselective C–H activation proceeds through inner-sphere mechanism remains a huge challenge. Herein, a copper-catalyzed enantioselective C−H alkynylation with terminal alkynes assisted by 8-aminoquinoline using readil…
Half-Sandwich d6-Metal (CoIII, RhIII, IrIII, RuII)-Catalyzed Enantioselective C–H Activation Open
Transition-metal-catalyzed enantioselective C–H activation provides a straightforward strategy to synthesize chiral molecules from readily available sources. In this graphical review, we summarize the progress on half-sandwich d6-metal (Co…
Synthesis of C—N Axial Chirality <span><i>N</i>‐Arylindoles</span> via Pd(<span>II</span>)‐Catalyzed Free <span>Amine‐Directed</span> Atroposelective C—H Olefination<sup>†</sup> Open
Comprehensive Summary Axially chiral N ‐arylindoles bearing a stereogenic C—N axis are unique important scaffolds in natural products, advance materials, pharmaceuticals and privileged chiral ligands or catalysts. Herein, we report the dir…
View article: CCDC 2219856: Experimental Crystal Structure Determination
CCDC 2219856: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2225542: Experimental Crystal Structure Determination
CCDC 2225542: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
Functionalization of Pyridines, Quinolines, and Isoquinolines Open
Transition metal-catalyzed C–H functionalization of pyridines, quinolines and isoquinolines has been well investigated over the past few decades. In this chapter, we aim at providing a comprehensive overview of this topic. For clarity, thi…
Palladium(II)-Catalyzed Enantioselective Functionalization of C(sp<sup>3</sup>)—H Bonds<sup>★</sup> Open
Chiral molecules are ubiquitous in nature and play an important role in natural products, pharmaceuticals, agriculture, advanced materials, as well as living organisms.Therefore, the development of efficient strategies to enable the facile…
CCDC 2033977: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2132393: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2132395: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2132394: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2132392: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
Regio‐ and Stereoselective 1,2‐Oxyhalogenation of Non‐Conjugated Alkynes via Directed Nucleopalladation: Catalytic Access to Tetrasubstituted Alkenes** Open
A catalytic 1,2‐oxyhalogenation method that converts non‐conjugated internal alkynes into tetrasubstituted alkenes with high regio‐ and stereoselectivity is described. Mechanistically, the reaction involves a Pd II /Pd IV catalytic cycle t…
Regio‐ and Stereoselective 1,2‐Oxyhalogenation of Non‐Conjugated Alkynes via Directed Nucleopalladation: Catalytic Access to Tetrasubstituted Alkenes** Open
A catalytic 1,2‐oxyhalogenation method that converts non‐conjugated internal alkynes into tetrasubstituted alkenes with high regio‐ and stereoselectivity is described. Mechanistically, the reaction involves a Pd II /Pd IV catalytic cycle t…