François Sidoroff
YOU?
Author Swipe
View article: An Analysis of Shear-Dependent Mechanochemical Reaction Kinetics
An Analysis of Shear-Dependent Mechanochemical Reaction Kinetics Open
The variation in the rate of a tribochemical reaction is calculated as a function of combined normal and shear stresses using Evans-Polanyi perturbation theory. The effect of perturbations such as stresses is obtained using transition-stat…
View article: Modeling mechanochemistry: pressure dependence of Diels–Alder cycloaddition reaction kinetics
Modeling mechanochemistry: pressure dependence of Diels–Alder cycloaddition reaction kinetics Open
We analyze the effect of pressure on the Diels–Alder (D–A) dimerization reactions using Evans–Polanyi (E–P) theory, a thermodynamic analysis of the way in which a perturbation, in this case a hydrostatic pressure, modifies a reaction rate.
View article: Modeling the squeezed-thin film using generalized oedometric Reynolds equations
Modeling the squeezed-thin film using generalized oedometric Reynolds equations Open
International audience
View article: Exploring mechanochemical reactions at the nanoscale: theory <i>versus</i> experiment
Exploring mechanochemical reactions at the nanoscale: theory <i>versus</i> experiment Open
Mechanochemical reaction kinetics which are calculated using the steepest-descent pathway yield results that agree well with experiment for the normal-stress-induced decomposition of methyl thiolate on Cu(100).
View article: Critical stresses in mechanochemical reactions
Critical stresses in mechanochemical reactions Open
The rates of mechanochemical reactions are generally found to increase exponentially with applied stress.