George Hutchinson
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View article: Response to Letter to the Editor
Response to Letter to the Editor Open
View article: Predicting late renal toxicity using a two-component repair model among pediatric patients receiving total body irradiation for stem cell transplant
Predicting late renal toxicity using a two-component repair model among pediatric patients receiving total body irradiation for stem cell transplant Open
View article: Computing High-Degree Polynomial Gradients in Memory
Computing High-Degree Polynomial Gradients in Memory Open
Specialized function gradient computing hardware could greatly improve the performance of state-of-the-art optimization algorithms, e.g., based on gradient descent or conjugate gradient methods that are at the core of control, machine lear…
View article: Mechanistic interpretation of orders in catalyst greater than one
Mechanistic interpretation of orders in catalyst greater than one Open
View article: CCDC 1972758: Experimental Crystal Structure Determination
CCDC 1972758: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1972760: Experimental Crystal Structure Determination
CCDC 1972760: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1972759: Experimental Crystal Structure Determination
CCDC 1972759: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Organocatalytic Enantioselective α-Bromination of Aldehydes with <i>N</i>-Bromosuccinimide
Organocatalytic Enantioselective α-Bromination of Aldehydes with <i>N</i>-Bromosuccinimide Open
Despite the wealth of existing organocatalytic, enantioselective transformations, the α-bromination of aldehydes remains a challenging reaction. The four examples reported to date require expensive, inconvenient brominating agents to achie…
View article: Mechanistically Guided Design of an Efficient and Enantioselective Aminocatalytic α-Chlorination of Aldehydes
Mechanistically Guided Design of an Efficient and Enantioselective Aminocatalytic α-Chlorination of Aldehydes Open
The enantioselective aminocatalytic α-chlorination of aldehydes is a challenging reaction because of its tendency to proceed through neutral intermediates in unselective pathways. Herein we report the rational shift to a highly selective r…
View article: Chirality-Induced Catalyst Aggregation: Insights into Catalyst Speciation and Activity Using Chiral Aluminum Catalysts in Cyclic Ester Ring-Opening Polymerization
Chirality-Induced Catalyst Aggregation: Insights into Catalyst Speciation and Activity Using Chiral Aluminum Catalysts in Cyclic Ester Ring-Opening Polymerization Open
A series of chiral-at-metal aluminum complexes have been synthesized using chiral catam ligands. Reactivity studies demonstrate the importance of alkoxide bulkiness and complex chirality in inducing catalyst aggregation. This has been expl…
View article: Use of Standard Addition to Quantify In Situ FTIR Reaction Data
Use of Standard Addition to Quantify In Situ FTIR Reaction Data Open
FTIR spectroscopy is a common in situ reaction monitoring technique used in modern academic and industrial environments. The FTIR signals collected during the course of a reaction are proportional to the concentration of the reaction compo…