Xian‐He Bu
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View article: Supramolecular linker directed assembly of a “trap-and-diffusion” MOF for one-step purification of polymer-grade C2H4 from C2 hydrocarbons
Supramolecular linker directed assembly of a “trap-and-diffusion” MOF for one-step purification of polymer-grade C2H4 from C2 hydrocarbons Open
Simultaneously removing ethane (C2H6) and acetylene (C2H2) from ethylene (C2H4) streams is advantageous for industrial production yet remains challenging for physisorbents. Herein, we report a microporous metal-organic framework (MOF), NKM…
View article: Multidirectional color palette of electrochromic metal–organic frameworks
Multidirectional color palette of electrochromic metal–organic frameworks Open
Electrochromic metal–organic frameworks (MOFs) combine advantages from both inorganic/organic electrochromic materials by enabling stable structures/performances as well as tunable functionalities. Their current design and synthesis, howev…
View article: A Highly Crystalline 2D Conjugated Metal–Organic Framework for Superior Sodium Storage
A Highly Crystalline 2D Conjugated Metal–Organic Framework for Superior Sodium Storage Open
Two‐dimensional conjugated metal–organic frameworks (2D c ‐MOFs) have emerged as promising electrode materials for sodium‐ion batteries (SIBs). However, developing 2D c ‐MOFs with multiple redox‐active sites and well‐defined structures to …
View article: Shaping Metal–Organic Frameworks Toward Practical Applications: From 0D to 3D
Shaping Metal–Organic Frameworks Toward Practical Applications: From 0D to 3D Open
Over the past three decades, characterized by structural diversity, large specific surface area, and ultrahigh porosity, metal–organic frameworks (MOFs) have demonstrated broad application prospects in fields such as gas adsorption and sep…
View article: CCDC 2353133: Experimental Crystal Structure Determination
CCDC 2353133: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Zirconium-Based Metal–Organic Frameworks for Photocatalytic CO<sub>2</sub> Reduction
Zirconium-Based Metal–Organic Frameworks for Photocatalytic CO<sub>2</sub> Reduction Open
Photocatalytic carbon dioxide (CO2) reduction shows great potential as an important approach to tackling global energy and environmental challenges. In recent years, zirconium-based metal-organic frameworks (Zr-MOFs), as an emerging class …
View article: Inverted Chiroptical Properties of Hybrid Metal Halides Through Reversible Chiral Induction Driven by External and Internal Chirality Transfer
Inverted Chiroptical Properties of Hybrid Metal Halides Through Reversible Chiral Induction Driven by External and Internal Chirality Transfer Open
Chiral organic‐inorganic hybrid metal halides (OIHMHs) are commonly constructed by introducing pairs of enantiomorphic chiral precursors through a single chirality transfer pathway, which may limit the regulation of chiral structural diver…
View article: Enzyme‐Photocoupled Catalytic Systems Based on Zirconium‐Metal‐Organic Frameworks
Enzyme‐Photocoupled Catalytic Systems Based on Zirconium‐Metal‐Organic Frameworks Open
Green, low‐carbon, and efficient chemical conversions are crucial for the sustainable development of modern society. Enzyme‐photocoupled catalytic systems (EPCS), which mimic natural photosynthesis, utilize solar energy to drive biochemica…
View article: Thiophene Sulfone Single Crystal as a Reversible Thermoelastic Linear Actuator with an Extended Stroke and Second-Harmonic Generation Switching
Thiophene Sulfone Single Crystal as a Reversible Thermoelastic Linear Actuator with an Extended Stroke and Second-Harmonic Generation Switching Open
Dynamic organic crystals are becoming recognized as some of the fastest materials for converting light or heat to mechanical work. The degree of deformation and the response time of any actuating material are often exclusive of each other;…
View article: Positive and Negative Exchange Bias in N-, P- and Q-Type Ferri-Magnets of Niccolite Metal Formates [CH3NH2CH3]n[CrIII1−xFeIIIxFeII(HCO2)6]n
Positive and Negative Exchange Bias in N-, P- and Q-Type Ferri-Magnets of Niccolite Metal Formates [CH3NH2CH3]n[CrIII1−xFeIIIxFeII(HCO2)6]n Open
Exchange bias (EB) materials, whose magnetization curve can shift along the field axis after field cooling, have attracted tremendous attention and play a crucial role in the development of fundamental physics as well as practical applicat…
View article: Thermoelastic twisting–assisted crystal jumping based on a self-healing molecular crystal
Thermoelastic twisting–assisted crystal jumping based on a self-healing molecular crystal Open
Adaptive crystals have attracted significant attention from solid-state chemists and crystal engineers for their promising applications in memories, capacitors, sensors, and actuators. Among them, thermosalient crystals are particularly fa…
View article: Donor-acceptor engineering of a triplet-exciton-optimized MOF photocatalyst for efficient singlet oxygen-mediated oxidation
Donor-acceptor engineering of a triplet-exciton-optimized MOF photocatalyst for efficient singlet oxygen-mediated oxidation Open
The exploration of photocatalysts (PCs) for efficient singlet oxygen (1O2)-based photocatalytic oxidation is critical and challenging. Herein, a new series of donor-acceptor metal-organic frameworks (D-A MOFs) are constructed through the e…
View article: Retrieving the Stability and Practical Performance of Activation‐Unstable Mesoporous Zr(IV)‐MOF for Highly Efficient Self‐Calibrating Acidity Sensing
Retrieving the Stability and Practical Performance of Activation‐Unstable Mesoporous Zr(IV)‐MOF for Highly Efficient Self‐Calibrating Acidity Sensing Open
The practical applications of activation‐unstable mesoporous metal‐organic frameworks (MOFs) are often constrained by their structural instability. However, enhancing their stability could unlock valuable functionalities. Herein, we stabil…
View article: Regulation of TADF by Internal and External Heavy Atom Effect in D‐A MOF for Heterocrystal based Temperature‐Compensated Photonic Device
Regulation of TADF by Internal and External Heavy Atom Effect in D‐A MOF for Heterocrystal based Temperature‐Compensated Photonic Device Open
The application of temperature‐compensated photonic device is hampered by poor accuracy and overly simplistic functions of propagation in photonic integrated circuits (PICs) field. Herein, we report a new library of donor‐acceptor metal–or…
View article: A Hydrolytically Stable Metal–Organic Framework for Simultaneous Desulfurization and Dehydration of Wet Flue Gas
A Hydrolytically Stable Metal–Organic Framework for Simultaneous Desulfurization and Dehydration of Wet Flue Gas Open
Metal–organic frameworks (MOFs) have great prospects as adsorbents for industrial gas purification, but often suffer from issues of water stability and competitive water adsorption. Herein, we present a hydrolytically stable MOF that could…
View article: Optimizing Hygroscopic Metal–Organic Frameworks via EDTA‐Mediated Structural Reinforcement and Photothermal Modification
Optimizing Hygroscopic Metal–Organic Frameworks via EDTA‐Mediated Structural Reinforcement and Photothermal Modification Open
Hygroscopic metal–organic frameworks (MOFs) are considered as superior moisture sorbents due to their highly adjustable and desired water adsorption/release performance, enabling effective atmospheric water harvesting (AWH) in arid regions…
View article: Strategic Defect Engineering Enabled Efficient Oxygen Evolution Reaction in Reconstructed Metal‐Organic Frameworks
Strategic Defect Engineering Enabled Efficient Oxygen Evolution Reaction in Reconstructed Metal‐Organic Frameworks Open
Metal‐organic frameworks (MOFs) have emerged as promising pre‐catalysts for oxygen evolution reaction (OER) due to their marvelous structural reconstruction process in strongly alkaline media. However, targeting design MOF structures to ac…
View article: Engineering Hygroscopic MOF‐Based Silk Via Bioinspired Interfacial Assembly for Fast Moisture Manipulation
Engineering Hygroscopic MOF‐Based Silk Via Bioinspired Interfacial Assembly for Fast Moisture Manipulation Open
Metal‐organic frameworks (MOFs) have emerged as exceptional moisture sorbents in low humidity conditions. However, their typical powdered form often results in agglomeration, impeding water diffusion kinetics and practical handling. To enh…
View article: CCDC 2369865: Experimental Crystal Structure Determination
CCDC 2369865: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Liquid‐Phase Exfoliation of 3D Metal–Organic Frameworks into Nanosheets
Liquid‐Phase Exfoliation of 3D Metal–Organic Frameworks into Nanosheets Open
Traditionally, the acquisition of 2D materials involved the exfoliation of layered crystals. However, the anisotropic bonding arrangements within 3D crystals indicate they are mechanically reminiscent of 2D counterparts and could also be e…
View article: Near‐Full‐Spectrum Emission Realized in a Single Lead Halide Perovskite across the Visible‐Light Region
Near‐Full‐Spectrum Emission Realized in a Single Lead Halide Perovskite across the Visible‐Light Region Open
The engineering of tunable photoluminescence (PL) in single materials with a full‐spectrum emission represents a highly coveted objective but poses a formidable challenge. In this context, the realization of near‐full‐spectrum PL emission,…
View article: Planar Chlorination Engineering: A Strategy of Completely Breaking the Geometric Symmetry of Fe‐N<sub>4</sub> Site for Boosting Oxygen Electroreduction
Planar Chlorination Engineering: A Strategy of Completely Breaking the Geometric Symmetry of Fe‐N<sub>4</sub> Site for Boosting Oxygen Electroreduction Open
Introducing asymmetric elements and breaking the geometric symmetry of traditional metal‐N 4 site for boosting oxygen reduction reaction (ORR) are meaningful and challenging. Herein, the planar chlorination engineering of Fe‐N 4 site is fi…
View article: Surface‐Grafted Single‐Atomic Pt−N<sub>x</sub> Complex with a Precisely Regulating Coordination Sphere for Efficient Electron Acceptor‐Inducing Interfacial Electron Transfer
Surface‐Grafted Single‐Atomic Pt−N<sub>x</sub> Complex with a Precisely Regulating Coordination Sphere for Efficient Electron Acceptor‐Inducing Interfacial Electron Transfer Open
Based on the electron‐withdrawing effect of the Pt(bpy)Cl 2 molecule, a simple post‐modification amide reaction was firstly used to graft it onto the surface of NH 2 ‐MIL‐125, which performed as a highly efficient electron acceptor that in…
View article: Utilizing Shear Piezoelectricity of Chiral Lead‐Free Metal Halides for Electromechanical Sensing
Utilizing Shear Piezoelectricity of Chiral Lead‐Free Metal Halides for Electromechanical Sensing Open
Chiral hybrid metal halides have emerged as a promising class of piezoelectric materials owing to their ease of synthesis, low acoustic impedance, and solution processibility. However, many known chiral halides crystalize in structures wit…
View article: Triazacoronene‐Based 2D Conductive Metal–Organic Framework for High‐Capacity Lithium Storage
Triazacoronene‐Based 2D Conductive Metal–Organic Framework for High‐Capacity Lithium Storage Open
2D conductive metal–organic frameworks (2D c ‐MOFs) have attracted increasing attention as promising electrode materials for rechargeable batteries due to their designable periodic motifs, large specific surface areas, and prominent electr…
View article: Reticular Modulation of Piezofluorochromic Behaviors in Organic Molecular Cages by Replacing Non‐Luminous Components
Reticular Modulation of Piezofluorochromic Behaviors in Organic Molecular Cages by Replacing Non‐Luminous Components Open
Organic piezochromic materials that manifest pressure‐stimuli‐responses are important in various fields such as data storage and anticounterfeiting. The manipulation of piezofluorochromic behaviors for these materials is promising but rema…
View article: Boosted Second Harmonic Generation of a Chiral Hybrid Lead Halide Resonant to Charge Transfer Exciton from Metal Halide Octahedra to Ligand
Boosted Second Harmonic Generation of a Chiral Hybrid Lead Halide Resonant to Charge Transfer Exciton from Metal Halide Octahedra to Ligand Open
Chiral hybrid organic–inorganic metal halides (HOMHs) offer an ideal platform for the advancement of second‐order nonlinear optical (NLO) materials owing to their inherent noncentrosymmetric structures. The enhancement of optical nonlinear…