Helena Randel
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View article: Controlling hydrogen transfer dynamics in adaptive semihydrogenation of alkynes: Unveiling and directing outer- vs. inner-sphere mechanisms
Controlling hydrogen transfer dynamics in adaptive semihydrogenation of alkynes: Unveiling and directing outer- vs. inner-sphere mechanisms Open
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View article: Inside Cover: A Cooperative Rhodium/Secondary Phosphine Oxide [Rh/P(O)<i>n</i>Bu<sub>2</sub>] Template for Catalytic Hydrodefluorination of Perfluoroarenes (Angew. Chem. Int. Ed. 23/2023)
Inside Cover: A Cooperative Rhodium/Secondary Phosphine Oxide [Rh/P(O)<i>n</i>Bu<sub>2</sub>] Template for Catalytic Hydrodefluorination of Perfluoroarenes (Angew. Chem. Int. Ed. 23/2023) Open
Two cooperative robotic arms [Rh/P(O)nBu2] are in the process of activating and breaking C−F bonds to create C−H bonds. In their Research Article (e202219127), Christophe Werlé and co-workers developed a molecular template based on these d…
View article: CCDC 2220405: Experimental Crystal Structure Determination
CCDC 2220405: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2117074: Experimental Crystal Structure Determination
CCDC 2117074: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2117073: Experimental Crystal Structure Determination
CCDC 2117073: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2181638: Experimental Crystal Structure Determination
CCDC 2181638: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2181637: Experimental Crystal Structure Determination
CCDC 2181637: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2110200: Experimental Crystal Structure Determination
CCDC 2110200: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: A Cooperative Rhodium/Secondary Phosphine Oxide [Rh/P(O)<i>n</i>Bu<sub>2</sub>] Template for Catalytic Hydrodefluorination of Perfluoroarenes
A Cooperative Rhodium/Secondary Phosphine Oxide [Rh/P(O)<i>n</i>Bu<sub>2</sub>] Template for Catalytic Hydrodefluorination of Perfluoroarenes Open
The selective activation of C−F bonds under mild reaction conditions remains an ongoing challenge of bond activation. Here, we present a cooperative [Rh/P(O) n Bu 2 ] template for catalytic hydrodefluorination (HDF) of perfluoroarenes. In …
View article: An Adaptive Rhodium Catalyst to Control the Hydrogenation Network of Nitroarenes
An Adaptive Rhodium Catalyst to Control the Hydrogenation Network of Nitroarenes Open
An adaptive catalytic system that provides control over the nitroarene hydrogenation network to prepare a wide range of aniline and hydroxylamine derivatives is presented. This system takes advantage of a delicate interplay between a rhodi…